The circular dichroism of a series of derivatives of camphor and fenchone is reported. The appearance of two maxima of opposite sign in the curves from the latter, e.g., 5-oxofenchol, in polar solvents is attributed to complexing with the solvent, the complex absorbing at shorter wavelengths than the free ketone, and having opposite rotatory power.
D. E. Bays, G. W. Cannon and R. C. Cookson, J. Chem. Soc. B, 1966, 885 DOI: 10.1039/J29660000885
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