Compounds of the type Fe phen2X2 and [Fe phen3]X2 have been made and studied by Mössbauer spectroscopy supplemented by infrared spectroscopy and reflectance spectra in the visible region. The results are in accordance with a cis structure for the bisphenanthroline compounds. The interactions between the phenanthroline molecules, the anionic ligands, and the iron atoms are discussed.
J. F. Duncan and K. F. Mok, J. Chem. Soc. A, 1966, 1493 DOI: 10.1039/J19660001493
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