The γ-radiolysis of carbon suboxide has been investigated. The products are a polymer, with a structure similar to that of thermal suboxide polymers, and carbon monoxide. It is suggested that the polymer is formed by an ionic chain mechanism.
A. R. Blake and K. E. Hodgson, J. Chem. Soc. A, 1966, 533 DOI: 10.1039/J19660000533
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