Open Access Article
Baolin Zhang†
a,
Xiaojian Xu†b,
Guangwei Suna,
Cheng Yanga,
Ge Zhangc,
Haichao Cui
*b,
Mingjian Wang*a,
Guofeng Xina,
Xia Houa and
Weibiao Chena
aAerospace Laser Technology and System Department, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, PR China. E-mail: haichaocui@sjtu.edu.cn
bShanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China. E-mail: wmjian@siom.ac.cn
cPrecision Optical Manufacturing and Testing Center, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201815, PR China
First published on 30th March 2026
Cu/Nd:YAG joints present a critical challenge for packaging advanced Nd:YAG-based laser components. Owing to the significant mismatch in the thermal expansion coefficients and the poor metallurgical compatibility between the ceramic and metal, the resulting high thermal stress and serious void defects deteriorate beam quality and structural lifetime. In this work, Cu and Nd:YAG were subjected to braze welding at a lower temperature of 190 °C, with reduced thermal stress and sound. It was obtained by designing a Ti–Pt–Au film as the transition layer and employing a vacuum-deposited indium film as the welding layer. Based on this approach, herein, practical sandwiched Cu/Nd:YAG/Cu laser components were fabricated for space-grade applications. Under extreme service conditions of satellite-borne laser systems, including large diurnal temperature variations and complex cyclic loads, the tested beam morphology and simulated thermal stress of the prepared laser component during operation satisfied the application requirements. These findings not only provide an efficient packaging solution for Nd:YAG-based laser components but also enrich the theoretical foundation for achieving low thermal stress and high-strength interface in ceramic/metal dissimilar joints.
The brazing welding of Cu and Nd:YAG presents a typical metal/ceramic joining challenge.8–10 The large difference in the thermal expansion coefficient (CTE) of Cu (16.5 × 10−6 K−1) and Nd:YAG (7.8 × 10−6 K−1) induces significant stress concentration (300–500 MPa) at the dissimilar interface during welding thermal cycling, which significantly weakens the mechanical properties of the joint.11–13 To address this issue, it is necessary to optimize the brazing parameters, mainly reducing the brazing temperature.14,15 It serves as the direct but efficient pathway to mitigate thermal stress by reducing heat input while proposing the higher requirement for solder selection and transition layer design.16
The traditional Ag–Cu–Ti solder, known for its excellent wettability and bonding strength, has been widely adopted in joining ceramics with metals. However, the melting point of this solder system is relatively high, more than 800 °C, which causes serious thermal damage to temperature-sensitive crystal materials such as Nd:YAG. The large heat input triggers higher stress and microcracks, lowering the component damage threshold.17 Recently, the low-temperature In-based solder system has received significant attention in the welding process during packaging Nd:YAG-based solid-state laser components. The core advantage of the low-temperature indium-based solder systems lies in their extremely low void fraction and excellent ductility, which can effectively solve stress problems in large-sized packaging, especially suitable for laser component packaging with high reliability requirements. Specifically, the high ductility of the indium-based solder accommodates thermally induced deformation without crack initiation, while the minimized void fraction after process optimization ensures stable interfacial contact, resulting in enhanced reliability and reduced thermal resistance of the packaging interface. The In solder is commonly used, together with the Au-coated crystal surface.18–20 The reaction characteristics of low-temperature chemical combination (∼150 °C for Au and In) and high-temperature service (melting points of AuIn2 at ∼541 °C and AuIn at ∼480 °C) endowed a large potential for preparing space laser components suffering severe diurnal temperature difference. The In solder is usually provided in a commercial In97Ag3 piece but it faced a high interface failure risk. Koo et al.21 considered that compared with Au atoms with slower diffusion rates, the migration of In atoms with faster rates induced vacancy aggregation and formed large-sized Kirkendall pores at the In-side of the dissimilar interface, thereby weakening the interface bond strength and worsening the laser output quality. Xiong et al.22 further found that as the eutectic reaction layer thickened, In atoms may even penetrate into the interior of the crystal substrate, significantly reducing structural reliability. Wen et al.23 found that when the thickness of the reaction layer exceeded the critical value of 2 µm and pore defects significantly worsened, despite moderate reaction-layer growth, which helped improve the bonding strength. Therefore, how to ensure the bonding strength but avoid void formation was crucial for further broadening the In/Au reaction system application in dissimilar welding of Cu/Nd:YAG. Regarding the transition layer design, mainstream methods include two aspects, including placing an additional metal layer and improving the crystal itself, such as modification by ion implanting AuNPs24 and designing transition layers. The study focuses on the former, a well-designed transition layer should simultaneously achieve the functions including stress regulation, element diffusion barrier and reductable surface modification, but few studies have been conducted in Cu/Nd:YAG dissimilar joints.25,26
Herein, low-temperature brazing of Cu/Nd:YAG was successfully achieved at 190 °C. The proposed vacuum-deposited pure In film was compared with a commercial In97Ag3 alloy foil in terms of weld formation and interfacial strength. By employing the deposited In coating as a welding layer and designing a Ti–Pt–Au transition layer, a practical sandwiched Cu/Nd:YAG/Cu space laser component was fabricated. To verify the application feasibility of the process into the extreme service conditions of satellite-borne laser systems, including large diurnal temperature fluctuations and complex cyclic loads, the beam morphology and thermal stress of the prepared laser component were experimentally evaluated and numerically simulated, respectively. This study not only provides an efficient packaging solution for the Nd:YAG-based laser components but also enriches the theoretical foundation for achieving low thermal stress and high-strength interface in other crystal/metal dissimilar joints.
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| Fig. 1 Schematic of the pre-brazing setup for the (a) experiment group and (b) practical application. | ||
Furthermore, the vacuum deposited In/vacuum deposited In double-sided brazing process developed in this study adopts an innovative symmetrical indium plating structure design under the same welding conditions (Fig. 1(b)). By adopting the Ti–Pt–Au composite transition layer design and precise control of Au layer thickness and plasma surface activation technology, the bonding rate between the gold plating heat sink and the laser crystal Nd:YAG was significantly improved. The Nd:YAG crystal (wavelength 1064 nm) treated with metallization forms a “sandwich” structure with a gold-plated heat sink. This assembly process achieves efficient soldering at low temperatures (below 200 °C) through a Ti–Pt–Au transition layer, meeting the high reliability requirements of space-level lasers for component packaging. This technology breaks through the thermal stress limitations of traditional packaging and provides innovative solutions for space applications of high-power lasers.
The key concerned properties were tested on the as-welded laser component specimens. To evaluate the interface strength of the Cu/YAG brazing weld, shear tests were performed on a microcomputer-controlled electronic universal material testing machine (DAGA4000, US). The loading rate was set at 0.5 mm min−1.
Considering that the structural thermal stress of a component in operation is difficult to measure directly, the finite element simulation was carried out. It was modeled and calculated using the Structure module of Simcenter Nastran and thermal module of Simcenter 3D Space System, respectively. The reliability of the simulation results was verified by comparing the data collected. A series of optical spot quality experiments were conducted. When the seed light was incident on this Nd laser component and the LD pump light was simultaneously activated, the laser output was triggered. And the spot pattern was captured by the CCD via the measured infrared imaging instrument (FOTRIC 240M, CN).
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| Fig. 2 Effective brazing rate analysis of the Cu/Nd:YAG interface: (a) imaging process and (b) In-F weld and In-D weld visualization results. | ||
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| Fig. 3 Weld microstructure analysis including the SEM images with EDS elemental mapping: (a) upper weld filling In97Ag3 alloy foil and (b) lower weld filling vacuum-deposited In. | ||
In comparison, as shown in Fig. 3(b), the lower In-D weld was dense with none obvious defects. The weld was relatively thin with a thickness of 25.3 µm. As displayed in the EDS mapping for the In element, the brazing filler metal was uniformly spread at the Cu/YAG interface. IMC layer thicknesses on the Cu- and YAG-sides were calculated at ∼6–8 µm and ∼3–5 µm, respectively. A thicker reaction layer indicated a more complete mixing and reaction of elements (Fig. 3(b)).
TEM with SAED analysis was performed on the FIB specimens extracted in the reaction layer for confirming the formed compound type. As shown in Fig. 4 and 5, at 190 °C, the In-F and In-D welds confirmed the FCC-structured AuIn2 formation according to the following reaction: 2
In
(l) + Au(s) → Au
In
2(s). It was worth noting that AuIn2 compounds were formed at a lower temperature (190 °C) and could withstand higher temperature (200–600 °C), exhibiting good adaptability for the studied laser component for space applications with a large diurnal temperature difference. Simultaneously, Ag in the In97Ag3 alloy foil accelerated the formation of some t-staged AgIn2 particles according to the reaction 2
In
(l) + Ag(s) → Ag
In
2(s), as shown in Fig. 4(c and d).
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| Fig. 4 TEM with SAED analysis of the compounds within the weld filling In97Ag3 alloy foil: (a and b) AuIn2, (c and d) AgIn2. | ||
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| Fig. 5 TEM with SAED analysis of the compounds within the weld filling vacuum-deposited In: (a and b) AuIn2. | ||
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| Fig. 6 Shear test analysis: (a) experimental setup and (b) stress–displacement curves of the weld filling In97Ag3 alloy foil and weld filling vacuum-deposited In. | ||
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| Fig. 7 SEM images with EDS fracture analysis of the weld filling In97Ag3 alloy foil: (a and b) Cu-side surface, (c and d) YAG-side surface. | ||
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| Fig. 8 SEM images with EDS fracture analysis of the weld filling vacuum-deposited In: (a and b) Cu-side surface, (c and d) YAG-side surface. | ||
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| Fig. 9 Schematic of the weld formation and failure behaviour under different solder forms: (a), (c) and (e) In-F weld, (b), (d) and (f) In-D weld. | ||
In contrast, when employing the vacuum-deposited indium layer, the welding surface achieves dense metallurgical bonding with a high welding efficiency of 99.7%. In this case, a thicker AuIn2 layer is formed, indicating a more complete interfacial reaction. The mitigation of the Kirkendall effect may be associated with the reduced overall weld thickness (i.e., shorter diffusion distance), which limits vacancy accumulation and thus suppresses void formation. Ultimately, compared with commercial In97Ag3 solder foil, the trade-off between strength and void suppression in the thick IMC-layer condition is overcome by adopting vacuum-deposited indium. The optimal joint exhibited a 35.3% improvement in joint strength and a fully ductile fracture mode at the In/In interface.
As shown in Fig. 10(a), (d) and (g), the temperature of Nd:YAG laser components was monitored in real-time. These test conditions were designed to simulate extreme operating scenarios that may be encountered in practical applications, which is critical for assessing the thermal stability of thin-strip Nd:YAG laser crystals. Even at the highest power-on current of 7.5 A, the experimental result shows that the temperature of the thin-strip laser crystal Nd:YAG component remains stable at 88.30 °C ± 2 °C, demonstrating reliable thermal performance under high-power excitation. A pronounced positive correlation was observed between the maximum crystal temperature and the fraction of LD pump power converted into absorbed power.
When the pump current reaches its rated working current of 7.5 A, the simulated temperature rise of the Nd:YAG thin-strip laser crystal is 93.96 °C, which is in agreement with the experimental result. The close consistency between the experimental and simulated temperature fields confirms the accuracy and reliability of the established thermal model (Fig. 10b, e, and h). Based on this, subsequent thermal stresses were calculated through thermal-mechanical coupling.
Fig. 10(c), (f) and (i) provide thermal stress calculation results of power-on laser components. It is clearly observed that the maximum principal stress mainly occurs in the central region of the Nd:YAG crystal after welding. This stress localization is primarily associated with welding-induced residual stress and the mismatch in thermal expansion behavior between the Nd:YAG crystal and the Cu substrate. Specifically, residual stress in the welded structure primarily originates from the non-uniform thermal expansion and contraction induced by the highly heterogeneous temperature field during welding, under the constraint of both ends of the crystal (shown in red). During practical operation, the difference in thermal expansion coefficients between Nd:YAG and Cu further intensifies stress accumulation during repeated heating and cooling cycles, thereby contributing to the observed stress concentration in the central region. When the maximum absorbed power reaches 200.4 W at 7.5 A, the maximum principal stress value is 79.26 MPa, as shown in Fig. 10(i), far below the fracture threshold of 206 MPa.30 It indicates that the crystal structure has a relatively high safety margin and verifies industrial feasibility of the proposed low-temperature brazing welding process. Chen et al.31 reported that the crystal temperature of Nd:YAG and other laser crystal devices increased to 638.43 K under an operating pump power of 80 W. In contrast, the Nd:YAG laser crystal brazed-sealing structure developed in this work exhibits a much lower steady-state temperature of 361.45 K experimentally and 367.11 K numerically, even under a significantly higher service power of approximately 576 W.
| Condition | Value |
|---|---|
| Pressure (atm) | 1 |
| Maximum temperature (°C) | +40 |
| Minimum temperature (°C) | −10 |
| Cycle times | 12.5 |
| Rate of temperature change (°C min−1) | 5 |
| Storage time (h) | 2 |
| Condition | Value |
|---|---|
| Frequency range (Hz) | 10–80; 80–350; and 350–2000 |
| Power spectral density (dB oct−1; g2 Hz−1; and dB oct−1) | +3; 0.04; and −3 |
| Total root mean square value | 6 |
| Loading direction | X, Y, and Z |
| Test duration (min) in each direction | 5 |
These results demonstrate that excessive porosity associated with the In-D/In-F welding schemes can induce system instability, trigger cascading amplification of welding defects, deteriorate heat-dissipation capability, and promote local stress concentration during operation.
The double-sided indium coating (In-D/In-D) configuration was adopted as the optimized group. After a series of laser-quality tests, it was confirmed that the components exhibited no cracking. Fig. 12 shows the static laser spot of the component under power-off conditions, as well as the dynamic spot profiles at different operating currents of 5.5 A, 6.5 A, and 7.5 A. Regardless of the power state, the emitted laser spots were tightly Gaussian focused and symmetric, with no observable trailing or distortion, i.e., the center of mass offset was small. That is to say, in the In-D/In-D welding scheme testing, due to low optical path loss and scattering, good wavefront integrity, weak mechanical vibration and airflow disturbance, and insignificant interference effects, the total energy is stable and close to the theoretical value, the diameter is close to the diffraction limit, the center of mass offset is small, and the peak intensity shows a single peak Gaussian distribution.
To further quantify the improvement in laser spot quality, the spot circularity was evaluated using the ImageJ software, defined as circularity = 4πS C−2, where S is the spot area and C is the spot perimeter. A circularity closer to 1 indicates a shape approaching an ideal circle. As shown in Fig. 13, the optimized laser spots exhibit circularity generally higher than 0.90, and consistently exceed those of the unoptimized samples under the same operating conditions. It demonstrates that the proposed optimization strategy significantly improves beam symmetry and focusing quality.
The reasons for the fluctuation of the laser spot in laser components with In-D and In-F welds could be concluded as: (1) thermal conduction imbalance: dense voids on the upper welding surface significantly reduce the thermal conductivity, hinder the transfer of heat to the heat sink and form a local high-temperature zone. Also, the lower welding surface has no voids to achieve efficient heat dissipation. This asymmetric thermal distribution leads to uneven refractive index gradients within the crystal, resulting in wavefront distortion when the beam passes through. (2) Asymmetric mechanical support: cavities weaken the stability of the rigid connection on the upper welding surface, resulting in micro-nano level displacement under temperature cycling or mechanical vibration; the dense structure of the lower welding surface maintains firm support. This unilateral constraint results in a slight tilt of the Nd:YAG optical axis of the crystal, amplifying the position shift and deformation of the emitted light spot. (3) Residual stress concentration: a stress concentration zone is formed around the cavity, and laser-induced microcracks propagate inside the Nd:YAG crystal, further disrupting optical uniformity. While matching the coefficient of thermal expansion (CTE) effectively controls macroscopic deformation, localized microscopic defects can generate high-frequency spot fluctuations through thermal-mechanical coupling. This occurs via a sequential process, in which localized temperature elevation initiates thermal stress accumulation, which subsequently causes micro-scale structural deformation, ultimately leading to optical path segregation or disruption.
It is concluded that In-F/In-D welds in the laser system preparation process, the large void defect should be prevented in the welded structure, which destroys the beam quality consistency through asymmetric heat conduction and mechanical instability. In other words, this triple coupling mechanism of “structural defects-thermodynamic imbalance-optical distortion” will ultimately manifest as an increase in total energy loss, deterioration of wavefront RMS error, and loss of positioning accuracy due to the rise of beam quality factor M2, which will affect the quality of the light spot. The symmetric and well-rounded laser spot observed in In-D/In-D welded components arises from enhanced metallurgical bonding facilitated by symmetrical heat distribution and improved mechanical stability at the dissimilar interfaces.
(1) Reliable joints between Cu and Nd:YAG were successfully achieved at a low temperature of 190 °C. In contrast to the weld with a relatively low effective brazing rate of 52.9% filling conventional In97Ag3 alloy foil, the one using vacuum-deposited In filler significantly improved the weld filling ratio to 99.7%, resulting in a dense welding layer and effective metallurgical bonding.
(2) A high-strength Cu/Nd:YAG interface was obtained. The optimal joint by adopting vacuum-deposited In as the welding layer exhibited a 35.3% improvement in interface strength compared with one filling In97Ag3 alloy foil. The fracture surface displayed ductile shear failure within the In solder zone.
(3) Finite element simulations were employed to visualize the thermal stress conditions. Under maximum operating current of 7.5 A, the optimized laser component still sustained a principal stress of 79.26 MPa, which remained far below the fracture threshold of Nd:YAG (206 MPa), verifying its structural safety and possessing the reliability of space applications.
(4) The laser beam spot quality of the manufactured laser component was evaluated under actual space application conditions. Void defects can induce thermodynamic instability at the dissimilar interface, thereby leading to spot distortion. By adopting the optimized vacuum-deposited indium coating as filler, the resulting laser component exhibited space-grade beam quality, characterized by a tightly focused and highly-concentrated-energy laser spot.
Footnote |
| † These authors contributed equally to this work. |
| This journal is © The Royal Society of Chemistry 2026 |