Open Access Article
Li-Fang Wang,
Chang-Xin Shi,
Ming-Jie Xu,
Zhe Qi,
Tian-Chen Wang,
Xian-Hua Pan and
Lei Guo*
School of Perfume and Aroma Technology, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai, 201418, China. E-mail: guolei@sit.edu.cn; panxh@sit.edu.cn
First published on 7th May 2026
Correction for ‘syn-Selective carboacylation of terminal alkynes via organic photoredox and nickel catalysis’ by Li-Fang Wang et al., Org. Chem. Front., 2026, 13, 417–422, https://doi.org/10.1039/D5QO01295C.
| Entryb | Variations from standard conditions | Yield (%) | Z/E |
|---|---|---|---|
| a Reaction conditions: PC-1 (3 mol%), Ni(bpy)Br2 (20 mol%), alkyne 1 (0.1 mmol), acyl chloride 2 (2.0 equiv.), alkyltrifluoroborates 3 (2.0 equiv.), ethyl acetate [0.05 M], 29–34 °C, 15 h, 90 W blue LED. All yields are isolated yields and the ratio of the two isomers was determined by HPLC analysis of the crude reaction mixture.b Additional bpy included (20 mol%). | |||
| 1 | None | 76 | 90 : 10 |
| 2 | PC-2 | 74 | 91 : 19 |
| 3 | PC-3 | 63 | 76 : 24 |
| 4 | PC-4 | 60 | 64 : 36 |
| 5 | PC-5 | 54 | 69 : 31 |
| 6 | L2 | 64 | 64 : 36 |
| 7 | L3 | 72 | 67 : 33 |
| 8a | NiBr2 | 71 | 82 : 18 |
| 9a | NiCl2 | 62 | 78 : 22 |
| 10 | THF | 81 | 47 : 53 |
| 11 | DMF | Trace | — |
| 12 | No PC-1 | 0 | — |
| 13 | No Ni(bpy)Br2 | 0 | — |
| 14 | No light | 0 | — |
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