The ordered organization of hydrogen-bonded organic macrocycles into a permanently porous framework

Abstract

A hydrogen-bonded organic framework (HOF) was obtained via the formation of a cyclic dimer hydrogen-bonded organic macrocycle (HOM) through rational molecular design. The ordered arrangement of HOMs formed permanently porous 1D channels in the HOF. These channels exhibited the selective adsorption of naphthalene.

Graphical abstract: The ordered organization of hydrogen-bonded organic macrocycles into a permanently porous framework

Supplementary files

Article information

Article type
Communication
Submitted
30 Mar 2026
Accepted
10 Jun 2026
First published
10 Jun 2026

CrystEngComm, 2026, Advance Article

The ordered organization of hydrogen-bonded organic macrocycles into a permanently porous framework

P. Cui, C. Chen, K. Mo, H. Zhang and Q. Zhu, CrystEngComm, 2026, Advance Article , DOI: 10.1039/D6CE00249H

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