From the journal:

Chemical Communications

Synthesis and characterization of a π-extended nonbenzenoid perylene

Laiyun Zhou,†a   Yanru Bai,†ab   Yangyang Zhao,b   Guanghua Liu,c   Bin Rao, ORCID logo b   Zhicheng Zhang ORCID logo *b  and  Qing Wang ORCID logo *b  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, P. R. China

b School of Chemistry, Xi' an Jiaotong University, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi' an, Shaanxi, P. R. China
E-mail: wangqing0114@xjtu.edu.cn

c Institute of Agricultural and Livestock Product Quality, Inner Mongolia Academy of Agricultural and Animal Husbandry Sciences, Hohhot, P. R. China

Abstract

A π-extended nonbenzenoid perylene (Pery-56) was constructed via a ring-fusion strategy at both its bay and peri positions. As a result, it features a moderately lower bandgap, broad visible-NIR absorption (525–950 nm) with λmax around 700 nm and reversible redox behavior; the corresponding cationic and anionic radical species were thoroughly studied.

Graphical abstract: Synthesis and characterization of a π-extended nonbenzenoid perylene

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Article information

DOI
https://doi.org/10.1039/D6CC02382G
Article type
Communication
Submitted
18 Apr 2026
Accepted
14 Jun 2026
First published
15 Jun 2026

Chem. Commun., 2026, Advance Article

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Synthesis and characterization of a π-extended nonbenzenoid perylene

L. Zhou, Y. Bai, Y. Zhao, G. Liu, B. Rao, Z. Zhang and Q. Wang, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D6CC02382G

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