Integrated dual-confinement effects of quantum dots and spatial CO2 activation for enhanced photoreduction performance
Abstract
A novel dual-confinement photocatalyst based on Co3S4 quantum dots and NiAl-LDH enables efficient CO2 photoreduction by coupling charge separation with surface activation. An interfacial electric field drives electron accumulation at hydroxyl-rich confined sites, lowers the COOH* formation barrier, and affords a CO evolution rate 17.8-fold higher than that of pristine NiAl-LDH.
- This article is part of the themed collection: CO2 capture and utilisation

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