Control of higher-order supramolecular aggregation driven by crowding effects in a PDMS/oligomer system

Shogo Amemori; Motohiro Mizuno

doi:10.1039/D6CC02056A

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Control of higher-order supramolecular aggregation driven by crowding effects in a PDMS/oligomer system

Shogo Amemori

*^abc and Motohiro Mizuno

*^abc

Author affiliations

* Corresponding authors

^a NanoMaterials Research Institute, Kanazawa University, Kanazawa 920-1192, Japan
E-mail: amemori@staff.kanazawa-u.ac.jp, mizuno@se.kanazawa-u.ac.jp

^b Graduate School of Natural Science and Technology, Kanazawa University, Kanazawa 920-1192, Japan

^c Institute for Frontier Science Initiative, Kanazawa University, Kanazawa 920-1192, Japan

Abstract

Polydimethylsiloxane and its oligomer were employed as a crowding agent and solvent, respectively, to investigate macromolecular crowding effects without altering solvation. This system selectively induced higher-order aggregation of one-dimensional supramolecular polymers without perturbing monomer–monomer interactions.

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Article information

DOI: https://doi.org/10.1039/D6CC02056A
Article type: Communication
Submitted: 02 Apr 2026
Accepted: 14 May 2026
First published: 28 May 2026

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Chem. Commun., 2026, Advance Article

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Control of higher-order supramolecular aggregation driven by crowding effects in a PDMS/oligomer system

S. Amemori and M. Mizuno, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D6CC02056A

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Control of higher-order supramolecular aggregation driven by crowding effects in a PDMS/oligomer system

Abstract

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Control of higher-order supramolecular aggregation driven by crowding effects in a PDMS/oligomer system

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