Herein, we report a photoinduced catalyst-free amine-mediated hydrodifluoroalkylation of 3-methyleneisoindolin-1-ones. Preliminary studies indicate key role of halogen bonding, reductant upconversion and proton shuttling in the reaction mechanism.
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V. Kumar, A. Kumar, A. Panuganti and V. R. Yatham, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D6CC01170E
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