N/O-functionalized MOFs with nonpolar channels for efficient natural gas purification and carbon capture
Abstract
A porous PyC–Zn-MOF, which possesses a rectangular pore structure and abundant nitrogen/oxygen bifunctional sites, is reported. It demonstrated effective separation of CH4/C2H6/C3H8 and CO2/N2, achieving a CH4 purity of >99.9% with a yield of 7.88 L kg−1 in a single adsorption–desorption cycle, underscoring its outstanding potential for industrial application.

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