La-modified nanocrystalline Cu4(NO3)2(OH)6 for highly selective CO2 reduction into CH4 under near-infrared light illumination

Jia Wang; Yue Liu; Yuancheng Peng; Peng Xie; Pengjun Wu; Lihai Zhou; Binbing Tang; Mingpeng Zhuo; Xinyu Ding; Xiaolei Yuan; Weifan Chen

doi:10.1039/D6CC00549G

La-modified nanocrystalline Cu₄(NO₃)₂(OH)₆ for highly selective CO₂ reduction into CH₄ under near-infrared light illumination

Jia Wang,^a Yue Liu,*^ab Yuancheng Peng,^a Peng Xie,^a Pengjun Wu,^a Lihai Zhou,^a Binbing Tang,^c Mingpeng Zhuo,

*^d Xinyu Ding,^f Xiaolei Yuan

^f and Weifan Chen*^abe

Author affiliations

* Corresponding authors

^a School of Physics and Materials Science, Nanchang University, Nanchang, Jiangxi 330031, P. R. China

^b Institute of Rare Earths, Nanchang University, Nanchang, Jiangxi 330031, P. R. China
E-mail: yueliu@ncu.edu.cn, chenweifan@ncu.edu.cn

^c Institute for Advanced Study, Nanchang University, Nanchang, Jiangxi 330031, P. R. China

^d National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215123, P. R. China
E-mail: mpzhuo@suda.edu.cn

^e Jiangxi Sun-Nano Advanced Materials Technology Co. Ltd, Ganzhou, Jiangxi 341000, P. R. China

^f School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China

Abstract

Under NIR irradiation, La-modified nanocrystalline Cu₄(NO₃)₂(OH)₆ (La/CuNH) reaches a methane product selectivity of 100% through a fully gas–solid reaction.

Chemical Communications

La-modified nanocrystalline Cu₄(NO₃)₂(OH)₆ for highly selective CO₂ reduction into CH₄ under near-infrared light illumination

Abstract

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La-modified nanocrystalline Cu₄(NO₃)₂(OH)₆ for highly selective CO₂ reduction into CH₄ under near-infrared light illumination

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