Total synthesis of (+)-xiamycin G via acetanilide-assisted two-fold Csp2–H functionalization

Rhituparna Nandi; Souvik Biswas; Sreyashi Sadhukhan; Apurba Das; Alakesh Bisai

doi:10.1039/D6CC00441E

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Total synthesis of (+)-xiamycin G via acetanilide-assisted two-fold Csp²–H functionalization

Rhituparna Nandi,

†^a Souvik Biswas,

†^b Sreyashi Sadhukhan,

^b Apurba Das

^b and Alakesh Bisai

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhauri, Bhopal – 462 066, Madya Pradesh, India

^b Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur Campus, Kalyani, Nadia – 741 246, West Bengal, India
E-mail: alakesh@iiserkol.ac.in

Abstract

The first asymmetric total synthesis of xiamycin G (1b), a structurally unique naturally occurring indolosesquiterpene alkaloid, has been accomplished via a two-fold Csp²–H functionalization.

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DOI: https://doi.org/10.1039/D6CC00441E
Article type: Communication
Submitted: 22 Jan 2026
Accepted: 23 Apr 2026
First published: 23 Apr 2026

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Chem. Commun., 2026, Advance Article

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Total synthesis of (+)-xiamycin G via acetanilide-assisted two-fold Csp²–H functionalization

R. Nandi, S. Biswas, S. Sadhukhan, A. Das and A. Bisai, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D6CC00441E

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Total synthesis of (+)-xiamycin G via acetanilide-assisted two-fold Csp²–H functionalization

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Total synthesis of (+)-xiamycin G via acetanilide-assisted two-fold Csp²–H functionalization

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