Synthesis of hybrid nickel boron–oxo clusters for photocatalytic CO2 reduction
Abstract
A series of organic ligand-stabilized nickel boron–oxo clusters were synthesized, demonstrating in situ evolution from simple organoboronic acids to complex structural motifs. Among them, the quinoline–pyrazole-protected boron–oxygen cluster Ni(II)2[B3O3(OH)2Qi(Pz)2]2 (BOC-22) exhibits excellent performance in the photocatalytic CO2 reduction reaction with CO and CH4 as the main carbonaceous products.
- This article is part of the themed collection: 2026 Pioneering Investigator Collection
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