A plasmon-enhanced fluorescent nanoprobe for ultrasensitive and selective detection of nitroaniline derivatives†
Abstract
A water-soluble, plasmon-enhanced fluorescent nanoprobe is engineered through Zn2+-directed assembly of HQS-capped silver nanoparticles and zinc quinolate complexes. Plasmonic coupling amplifies emission, enabling selective ppb-level detection of 4-nitroaniline and 2,4-dinitroaniline via NH2 → Zn2+ coordination-induced static quenching, delivering excellent sensitivity in real water matrices with high selectivity, sensitivity, and environmental applicability.

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