Asymmetric light transmission via Sb2S3-enhanced nonreciprocal gratings on a glass substrate

Abstract

We propose and demonstrate a compact, high-performance optical isolator utilizing nonreciprocal gratings enhanced by antimony trisulfide (Sb2S3) deposited on a glass substrate. The vertical asymmetry created by layered materials and the amorphous silicon (a-Si) grating enables direction-dependent optical transmission behavior in the near-infrared spectral range. Rigorous coupled-wave analysis (RCWA) simulations reveal that the introduction of Sb2S3 significantly boosts nonreciprocal transmission contrast, enabling an isolation ratio of 22.28 dB for an a-Si surface grating with a period p of 1 μm, a fill factor f of 0.5, and a groove depth h of 0.36 μm on a Sb2S3/glass stack. Breaking mirror symmetry yields polarization-selective optical isolation, supporting both transverse-electric (TE) and transverse-magnetic (TM) polarizations. Calculated and measured transmittance spectra match closely for both TE and TM at normal incidence, confirming the grating model and fabrication fidelity. Transitioning Sb2S3 to the crystalline phase substantially elevates asymmetric transmission for both polarizations, as captured by the model. This work provides a promising route toward scalable, efficient, and broadband nonreciprocal photonic devices based on cost-effective and versatile material platforms.

Graphical abstract: Asymmetric light transmission via Sb2S3-enhanced nonreciprocal gratings on a glass substrate

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Article information

Article type
Paper
Submitted
31 Jul 2025
Accepted
01 Sep 2025
First published
05 Sep 2025

J. Mater. Chem. C, 2025, Advance Article

Asymmetric light transmission via Sb2S3-enhanced nonreciprocal gratings on a glass substrate

X. Cui, Q. Fang, J. Ye, F. Xian and G. Zheng, J. Mater. Chem. C, 2025, Advance Article , DOI: 10.1039/D5TC02889B

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