Filippa
Wentz
ab,
Mohsen
Mohammadi
ab,
Klas
Tybrandt
abc,
Magnus
Berggren
abc,
Rickard
Arvidsson
*d and
Aiman
Rahmanudin
*ab
aLaboratory of Organic Electronics, Department of Science and Technology, Linköping University, 601 74 Norrköping, Sweden. E-mail: aiman.rahmanudin@liu.se
bWallenberg Wood Science Centre, Department of Science and Technology, Linköping University, 601 74 Norrköping, Sweden
cWallenberg Initiative Materials Science for Sustainability, Department of Science and Technology, Linköping University, 601 74 Norrköping, Sweden
dEnvironmental Systems Analysis, Department of Technology Management and Economics, Chalmers University of Technology, SE-41296 Gothenburg, Sweden. E-mail: rickard.arvidsson@chalmers.se
First published on 22nd September 2025
This perspective explores the intersection between technology research and environmental assessment during the early-stage development of next-generation wearable electronics, encompassing flexible, stretchable, soft, transient, printed, and hybrid electronics. While significant advancements have been made in the development of high-performance materials, fabrication processes, and device engineering for wearables, their environmental performance is often overlooked. Even when environmental claims for new materials or processes are stated, they are often made without any quantifiable justification. This perspective critically analyses current approaches at assessing environmental performance during the early research stage and recommends how and when to integrate an environmental assessment to ensure both high device functionality and environmental performance. The timeliness of this perspective arises from the urgent need to address environmental concerns in the rapidly expanding wearable electronics research field and commercial use, which is projected to grow exponentially in the coming decade. Research in wearable electronics is multidisciplinary, involving material science, chemistry, physics, biology, electrical engineering, medicine and neuroscience. This perspective recommends timely integration of relevant environmental assessment efforts, including life cycle assessment, into this multidisciplinary mix, thereby ensuring that next-generation wearable electronics are aligned with sustainable development policies and regulatory systems.
A critical dilemma facing researchers performing early-stage innovation of wearable technology is: when and how should environmental assessments be integrated into the research process? (Fig. 1c). Early-stage material and device research for wearables often prioritize performance, functionality and scalability over environmental sustainability. When sustainability claims for new materials or processes are stated, they are often made without any quantifiable justification.12–18 Despite an increasing trend in the number of publications in wearable electronics with a sustainability focus over the decades, the assessment of their environmental impact is lagging behind (Fig. 1d).
This is problematic considering the environmental and resource challenges observed for conventional electronics in the past, such as the massive generation of non-recycled electronic waste (e-waste),19 the use of scarce metal resources (such as silver, tin, and tantalum),20 and the use of toxic materials such as lead,21 polychlorinated biphenyls,22 and perfluoroalkyl substances (PFAS).23 Furthermore, petroleum-based polymers used as encapsulation materials for wearables, such as silicone, polyurethane (PU) and styrene-based elastomers are persistent and non-renewable.24 These lessons point to a need for considering environmental and resource aspects when developing next-generation wearables electronics which are shifting towards environmentally friendly and circularity-driven innovations.25 Addressing this requires deeper collaboration between experimental technology researchers with environmental experts, particularly those skilled in life cycle assessment (LCA) methodologies and systems-level sustainability thinking.
In addition, implementation of wearable electronics in our society fundamentally presumes widespread deployments of the technology following successful industrial upscaling. Regardless of whether this is achieved through spinout efforts or conducted in existing industry, companies are required to identify and manage risks associated with human health and the environment. In the European Union (EU), this is partly handled through several key regulatory systems, such as Critical Raw Materials Act,26 REACH (Registration, Evaluation, Authorisation, and Restriction of Chemicals),27 CSRD (Company Sustainability Reporting Directive)28 and the EU Taxonomy.29 Similar regulatory systems in the United States such as the Critical Minerals & Materials Strategy,30 Japan's green growth strategy to support their 2050 carbon neutral goal,31 and China's Green Development plan,32 signifies the importance of assessing the environmental impact of emerging technologies.
Environmental assessment efforts, including LCA, is crucial for complying with these regulatory systems as it provides quantitative data needed to assess and report on the environmental impacts of products and processes throughout their entire lifecycle, from raw material extraction to end-of-life (EoL). Environmental assessment tools should be incorporated throughout the entire research pathway, i.e. from the formulation of the idea and hypothesis to publication of results and commercialisation (Fig. 1c). This will encourage researchers in wearable electronics to align their work to be relevant for, and significantly contribute to, sustainability and avoid conducting their research toward scientific sustainability ‘dead ends’. Furthermore, making the scene even more complicated, regulatory systems have been developed in the past, and will certainly continue in the future. Researchers should be aware of regulatory frameworks and how they continuously advance over time and what impact they have on e.g. LCA.
In this perspective, we first outline some important considerations when striving for high environmental performance (including also resource performance) in the research processes for wearable electronics. We then review previous attempts at integrating environmental aspects in the development of wearable electronics. Finally, based on the critical considerations and prior work, we recommend an approach for how environmental aspects can be successfully included at the early-stage research processes for wearable electronics.
When performing an LCA, a so-called functional unit needs to be defined (ISO 14040:2006).36 It is a quantitative measure of the product's function, to which all upstream and downstream flows are related, and using the same functional unit is important in LCAs involving comparative assertions. Common functional units in LCA are 1 device, 1 kg, or some performance measure, like 1 person-km for vehicles. LCAs of conventional electronics often apply 1 device as a functional unit,37 which is convenient and allows for analyses of environmental and resource hotspots but does not reflect the performance of devices. Identifying relevant performance-based functional units for wearable electronics is thus important to ensure useful comparisons between different technologies.
The selection of environmental impact categories is another important methodological choice in LCA. It is generally advisable to include multiple environmental impact categories in LCA to enable analyses of trade-offs,38 thus going beyond single-indicator metrics like the carbon footprint. Broader lists of impact categories are available in “packages” of impact assessment methods, such as ReCiPe.39 Particularly important impact categories for conventional electronics include global warming, energy requirement, mineral resource scarcity, (eco)toxicity, pollution and generation of e-waste. Depending on the wearable electronic designs, these impact categories might be particularly relevant for wearable electronics as well.
Conventional electronics is an established – albeit rabidly changing – product category. Commercial wearables such as earphones, hearing aids, smart watches, or fitness trackers, do exist, but next-generation versions are characterized by radical novelty, fast growth, high uncertainty, and potentially high societal impact.40 For emerging technologies at a currently immature state (e.g., developed at laboratory scale), researchers and developers have high possibilities to change the design to improve the environmental performance. Therefore, performing LCA to guide the design of wearable electronics should preferably be done at such an early stage of development, since it enables researchers and developers to make informed decisions that align innovation with environmental performance. Without such early guidance, much effort can be spent on materials and device architectures that will later be revealed to have poor environmental performance.18,41
However, at this early stage, assessments of the technology as-is might be of limited relevance considering the notable changes it will likely undergo before reaching production volumes of environmental significance. Therefore, it is recommendable to apply a prospective perspective, which for the LCA modelling means that the product system is modelled “at a future point in time relative to the time at which the study is conducted”.42 For an emerging technology, a particularly relevant future time is when it has reached maturity, commercialization, and large-scale production, since it is at this point the environmental impacts of the technology will matter the most.
Unfortunately, the early stage of development is also when there is the least information about the technology, both in its current immature and future mature states, which can be referred to as the process design paradox (Fig. 2). The opportunity to influence a technology's environmental footprint is highest in the early design and material selection phases, when fundamental choices about materials, processing conditions, device architecture, and manufacturing routes are being decided. This is also when detailed knowledge of a design's environmental performance is least available, so traditional LCAs typically come only after a product is largely defined.41 By then, making substantive changes for environmental performance may be technically or economically infeasible. This paradox makes it difficult to align environmental objectives with rapid innovation, since environmental guidance often arrives only after key decisions have been locked in. Thus, finding relevant data representing production, use and EoL in the future can be challenging. However, there are attempts at developing accurate upscaling approaches and thereby easing the design paradox. Examples of such upscaling approaches include chemical process simulations, process calculations, stoichiometric calculations, and using relevant large-scale processes as proxies.43 Applying such upscaling approaches is particularly important to ensure fair comparisons with currently mature technologies.44
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Fig. 2 An illustration of the process design paradox or the Collingridge dilemma in early-stage innovation of wearable electronics technology and its prospective environmental impact. |
In addition, other technologies that are part of the wearable electronic product's life cycle might change before the time of commercialisation. For example, electricity generation is undergoing a rapid transition world-wide, with increasing shares of solar and wind power. Any product using significant amounts of electricity during its production or use will thus likely see altered environmental performance over time. Approaches to consider such changes in prospective LCA are under development. For example, the Premise tool can generate future versions of the LCA database Ecoinvent that follow scenarios from the Intergovernmental Panel on Climate Change,45 meaning that, e.g., electricity production at the future point in time (e.g., 2040 or 2050) is changed according to those scenarios.
Consequently, important environmental considerations for early-stage wearable electronics research are to (i) apply a life-cycle perspective and LCA, (ii) assess environmental performance using relevant functional units, (iii) include several impact categories to analyse trade-offs, and (iv) have a prospective perspective to reveal the potential environmental performance of the wearable electronic product at commercialisation.
Proof of concept | Innovation | Key materials | Mechanical properties | Quantitative environmental assessment approach | System boundaries | Functional unit | Impact categories | Ref. |
---|---|---|---|---|---|---|---|---|
PTFE = poly(tetrafluoroethylene), PDA = polydopamine, CMC = carboxymethyl cellulose, pEP(QH2)E = poly(3,4-ethylenedioxythiophene 3,4-propylenedioxythiophene hydroquinone 3,4-ethylenedioxythiophene), pEP(NQ)E = poly(3,4-ethylenedioxythiophene 3,4-propylenedioxythiophene naphthoquinone 3,4-ethylenedioxythiophene), P3HT:PCBM = poly(3hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester, PLA = poly(lactic acid), LED = light emitting diode. | ||||||||
Device-level | ||||||||
OECT & OPD | Leaf skeleton reinforced electronics | Leaf skeleton, ethyl cellulose, chitosan, Ag, PEDOT:PSS | Flexible | Lab-scale LCA | Cradle to gate | 1 m2 substrate | Climate change | 76 |
Impact categories: climate change | ||||||||
E-textile | New eco-friendly e-skin with integrated sensor | Tencel™/Lyocell fabrics PEDOT:PSS, graphite, graphene | Flexible | Lab-scale LCA | Cradle to gate | 10 cm × 1 cm surface | 18 (all from the ReCiPe 2016 package) | 77 |
Paper based circuit board | Processing technique for paper-based circuit boards | Paper, PU, Ag flakes, methyl acrylate | Flexible | Lab-scale LCA | Cradle to gate plus end of life | 10![]() |
9 (from the CML package) | 78 |
Energy storage and power source component-level | ||||||||
Tribo-electric nanogenerator | Comparison between high & low efficiency modules and other energy harvesters | PTFE, acrylic sheet, Cu, Ti, Pb, ethanol & acetone | Flexible | Lab-scale LCA | Cradle to gate | 1 m2 module | 11 plus weighted single-score | 73 |
Battery | A transient Zn-ion battery with high cyclic stability | Zn, PDA, CMC, agarose, glutaraldehyde, ZnSO4, dopamine, piperidine, activated charcoal, carbon black, carbon cloth, glycerol | Flexible | Lab-scale LCA | Cradle to gate | 1 kWh energy storage capacity | 18 (all from the ReCiPe 2016 package) | 71 |
Battery | First LCA of all-organic battery | Graphite, pEP(QH2)E, glass microfiber, pEP(NQ)E, biopolymer plastic & sulfuric acid | Flexible | Lab-scale LCA | Cradle to gate | 3 cm × 3 cm cell and 1 kWh energy storage capacity | 16 (from the ILCD package) plus weighted single-score | 79 |
OPV & LED | Printed OPV made from recycled and biobased polymers | LiF, Ag, ITO, ZnO, histidine,biochar, P3HT:PCBM, PEDOT:PSS, PET, rPET & PLA | Flexible | Lab-scale LCA | Cradle to gate | 1 m2 solar cell area and 1 kWh produced | Climate change and cumulative energy demand | 72 |
Function | Research concept | Key materials | Mechanical properties | Environmental assessment | Ref. |
---|---|---|---|---|---|
SIS = styrene isoprene styrene, PVA = poly(vinyl alcohol), PI = poly(imide), PMMA = poly(methylmethacrylate), PCL = poly(caprolactone), SWCNT = single-walled carbon nanotube, TEMPO = tetramethylpiperidine-1-oxy, PDMS = poly(dimethylsiloxane), PDY-132 = polymer emitter super yellow, PLGA = poly(lactic-co-glycolic acid), BTP = bioresorbable thermoplastic polymer, CNC = cellulose nanocrystals, CNT = carbon nanotube, NW = nanowire, PLCL = poly(L-lactide-co-ε-caprolactone), P14(TFSI) = N-methyl-N-butylpyrrolidinium bis(trifluoromethanesulfonyl) imide, p(DPP-PPD) = poly(diketopyrrolopyrrole p-phenyldiamine), SDS = sodium n-dodecyl sulfate, PIDTBT = poly(indacenodithiophene-benzothiadiazole), PDPPTBT = poly(diketopyrrolopyrrole thiophene-benzothiadiazole), CNF = cellulose nanofibers, PGS = poly(glycerol sebacate), PU = polyurethane, PEG = polyethylene glycol. | |||||
Device-level | |||||
Circuits | A novel fabrication method and architecture for soft electronics | Toluene, Ag, Ni, Fe, C, GaIn, SIS, Fe3O4 & PVA | Stretchable | Demonstrating recycling and repairability | 47 |
Biosensors | Upcycling of no longer used CDs | CD, tattoo paper, PI, PMMA, PCL, chitosan, SWCNT & Prussian Blue | Stretchable | Degradation in different solvents including PBS@37 °C | 48 |
HBTs, Schottky diodes, MIM capacitors | High performance electronics on CNF substrates with a minimized use of toxic semiconductors | TEMPO-oxidised CNF, bisphenol A-based epoxy resin, GaAs, GaInP, Si, C, Al0.96Ga0.04As, PI, Pd, Ge, Au, PDMS, Cu & TiO2 | Flexible | Quantification of the amount of arsenic and water needed for the device, compared to consumer electronics & fungal biodegradation | 49 |
Battery | Fungal mycelium substrates | Mycelium, Cu, Au, Zn, acetylene carbon black, xanthan powder, MnO2, Cr, shellac, PEDOT:PSS, Ag, ammonium chloride and zinc chloride | Flexible | Aerobic disintegration in soil at 58 °C | 50 |
LED, LEC, circuit bord, strain sensor | A biodegradable & photo-crosslinkable stretchable polymer | Poly(glycerol sebacate) acrylate, galinstan, PEDOT:PSS, Au, cellulose acetate, PDY-132, poly(caprolactone-co-trimethylene carbonate) & poly(caprolactone-co-trimethylene carbonate) | Stretchable | Biodegradability assessment according to ISO standards | 51 |
Electronic component-level | |||||
Large range of devices on biodegradable polymer substrates | Fabrication method that separates the processing of electronic systems & the biodegradable polymer | PLGA, Mg, SiO2, Si, PDMS, rice paper, PLA & PCL | Flexible | Degradation in PBS@37 °C | 53 |
Sensor | Highly deformable temperature sensor | Mg, Si3N4, SiO2, Ecoflex, PMMA & NaCl | Stretchable | Dissolution tests in water–NaCl solution@25 °C & cytotoxicity tests | 54 |
Sensors | Laser-based method to make biodegradable electronics | Mg, Si, PLA, Zn, PLGA, wax, BTP, cellulose acetate, Fe, Mo | Stretchable | Bioresorbability in PBS@95 °C for 10 days & in vivo biocompatibility for 8 weeks | 55 |
Thin-film transistor | A crystalline nanocellulose dielectric ink that is compatible with CNT & graphene inks, allowing for all carbon TFTs | CNC, CNT, graphene, toluene, NaCl, AgNW, paper | Flexible | The inks were recycled 5 times and kept good performance | 56 |
Cardiac jacket, actuator & conductive elastomer | Highly elastic biodegradable elastomer | PLCL, PEDOT:PSS, P14(TFSI), Mo, SiO2, Mg & Si | Elastic | Fungal biodegradability & degradability in PBS@37 °C & cytotoxicity studies | 57 |
Electrocardiogram (ECG) electrodes and pressure sensors | Stretchable, self-healing, and recyclable conductive polymer composites | PEDOT:PSS, PU, PEG | Stretchable | The conducting polymer composites were mechanically cut into small pieces, reheated at 100 °C to facilitate remoulding | 59 |
Thin-film transistor | Biodegradable & stretchable polymeric semiconductor | P(DPP-PPD), E-PCL, Au, SEBS | Stretchable | Degradability in acidic solution (pH ∼ 0.5), in vitro cyto-toxicity studies | 60 |
OFET | Combining the synthesis and processing of high performance organic semiconductors for OFETs in one-pot and in water | SDS, PIDTBT, PDPPTBT, Pd, methanol, toluene | Flexible | Synthesis in 1![]() ![]() ![]() ![]() |
61 |
Energy storage and power source component-level | |||||
Super-capacitor | Fully printed and disposable EDLC | TEMPO-modified CNF, CNC, glycerol, shellac, graphite, carbon-black, activated carbon, NaCl | Flexible | ISO standard 20200 composting until 50% mass loss | 64 |
Battery | Battery with dual electrolyte to get a high performance eco/bioresorbable battery | Mg, polyanhydride, iodine, super P, PLGA, ethyl acetate, chitosan, Mb, choline chloride & urea | Flexible | Dissolution in PBS@37 °C & 85 °C and biocompatibility studies in vivo | 65 |
Battery | Biodegradable redox-diffusion battery | Alizarin red S, lignosulfonate, CNF, PEDOT:PSS, PU, nanographite & PGS | Stretchable | Biodegradability assessed by soaking in PBS at various temperatures | 66 |
Battery | Biodegradable and stretchable battery with high energy and power density | PGS, MoO3, xanthan gum, Mg, calcium alginate & CaCl3 | Stretchable | Battery | 67 |
Battery | Edibility | Quercetin, riboflavin, nori algae, beeswax, NaHSO4, Au, activated charcoal & ethyl cellulose | Rigid | Materials are below the limit of toxicity for human consumptions | 68 |
A “3R Electronics” method of resilient, repairable, and recyclable electronics by Tavakoli et al., enabled mechanical disassembly and recycling of the internal electronic components of a wearable device.47 The concept utilised the non-permanent physical crosslinks of the block-copolymer elastomer binder and substrate via solvent dissolution. However, this came at the cost of hazardous organic solvents and petroleum-based substrates, with no formal environmental assessment of their process. Brown et al. showed upcycled compact discs (CDs) into flexible devices using low-energy fabrication and waste valorisation, but without formal environmental assessment.48 On the other hand, Jung et al. developed biodegradable cellulose nanofibril substrates for flexible GaAs-based electronics, mitigating plastic waste but relying on toxic, rare metals without quantifying their trade-offs.49 Similarly, Danninger et al. proposed “MycelioTronics” using fungal mycelium skins, which biodegrade under composting conditions and enable disassembly, but scalability and full life-cycle impacts remain unassessed.50
More robust environmental assessment examples have been shown. For example, Held et al., who demonstrated stretchable biodegradable electronics with poly(glycerol sebacate acrylate) elastomers and Galinstan liquid metal (Ga, In & Sn) interconnects.51 Biodegradability of the elastomer substrate was rigorously validated following ISO 14855-1 and ISO 14851 standards, ensuring environmental disintegration under composting and aqueous conditions. The mechanical and electrical performance were maintained during use, although safe recovery strategies for Galinstan residues after substrate degradation remain an open challenge. Nair et al.'s “Leaftronics” minimised synthetic processing using natural wood-based lignocellulose leaf scaffolds and included a cradle-to-gate LCA, quantifying reductions in carbon footprint relative to non-bio-based alternatives. However, their lab-scale LCA was limited in scope and lacked prospective modelling.
More recently, Dulal et al.'s SWEET platform (Sustainable, Wearable, and Eco-Friendly Electronic Textiles) integrated biodegradable substrates, low-toxicity inks, and a comprehensive LCA across 17 impact categories, but they excluded use phase and end-of-life impacts.52 Finally, Liu et al. introduced paper-based printed circuit boards (P-PCB) fabricated via additive manufacturing and biodegradable substrates reporting approximately two orders of magnitude lower environmental burdens across multiple categories compared to conventional epoxy-based PCBs. 9 different impact categories were considered. The use of renewable paper substrates and simplified additive fabrication processes were key drivers of the reduced impacts. In the study, they also identified the use of silver flakes as conductive fillers as significant contributors to human toxicity. This case exemplifies how targeted material and process redesigns, even at the component and interconnect level, can notably improve the environmental performance profile of the technology. However, prospective impacts and impacts of the use phase remain to be investigated.
Hwang et al.53 and Salvatore et al.54 demonstrated early examples of biodegradable transistors and sensors using ZnO, Mg, and compostable substrates, achieving full degradation without sacrificing functional integrity. However, both studies lacked formal environmental assessments and relied on materials or fabrication techniques such as vacuum deposition or thick encapsulations that complicates scalability. Similarly, Yang et al. advanced the field with spatially programmable, bioresorbable devices using laser-structured electrodes based on biodegradable metals, such as magnesium and zinc, and elastomer substrates.55 Their work is particularly relevant for transient biomedical implants that are conceptually designed for biodegradation and bioresorption inside the body, or for single use disposable devices that can degrade safely in the environment. The biodegradation test of all materials was demonstrated in vivo under accelerated conditions (phosphate buffered solution (PBS), 95 °C, 8 weeks), but broader environmental life-cycle impacts were not evaluated in detail.
More recent innovations have targeted environmental performance through scalable processing and eco-friendly material sourcing. Williams et al. introduced recyclable, printable carbon-based transistors using the biopolymer, cellulose as the active dielectric layer and substate material which enabled low-temperature recovery of both substrate and conductors.56 However, long-term environmental degradation of residual carbon nanomaterials was not assessed. More recently, Han et al. presented a stretchable and biodegradable elastomer from bio-derived polymer used as a binder for a conductive electrode composite, active actuator component and substrate layer.57 The elastomer exhibited mechanical stability (softness and stretchability) while maintaining electrical performance and exhibited complete biodegradation under simulated composting conditions within a few months.
Self-healing and reprocessable materials at the electronic component level are gaining attention for their ability to extend device lifetimes and reduce waste by enabling components to repair damage or be recycled.58 For example, Kim et al. have recently reported a stretchable, self-healing and fully recyclable conductive polymer blend, which exhibited stable electro-mechanical performance even after being recycled 20 times.59 They assumed that end-of-life devices made from the material could be collected and reprocessed under mild conditions (≈ 100 °C and low pressure) instead of landfilling, thereby saving raw materials and avoiding the impacts of producing new components.
Tran et al. introduced a new class of semiconducting materials that are both fully degradable and stretchable, aiming to meet the requirements of transient and bioresorbable electronics.60 Their approach combined a conjugated donor–acceptor copolymer, designed with hydrolytically cleavable ester side chains, with a biodegradable elastomeric matrix to achieve mechanical compliance and controlled degradation. However, the degradation conditions were achieved under highly acidic (pH ∼ 0.5) conditions.
In another paper on semiconducting polymers, Rahmanudin et al. highlighted the need for making the synthesis purification and processing of the organic semiconductor into flexible organic transistors more environmentally friendly.61 The work focused on reducing the number of fabrication steps from the synthesis and purification of the polymer, right up to the film processing of the semiconducting layer in a transistor. All in one-pot and mainly with water as a solvent media. The authors claimed to minimize the use of toxic and volatile organic solvents such as toluene, which is typically used in polymer synthesis, and avoided chlorinated solvents like chlorobenzene that is commonly used to dissolve the polymer during film processing, as used by Tran et al. However, lab-scale values were used as a basis of comparison between conventional synthesis, purification and processing methods with their synthesis-to-device in water approach. Scale-up synthesis and printing conditions were not considered, and rare metal palladium catalysts were needed for the polymerisation.
These examples illustrate that efforts at improving the environmental performance at the electronic component level spanning transistors, sensors, and active layers. Early work focused on achieving basic biodegradability in rigid devices, while more recent studies extend degradability and recyclability into fully stretchable, functional systems suitable for wearable and transient electronics. However, despite promising demonstrations of material breakdown and functional resilience, comprehensive LCAs remain rare, and future efforts should aim to systematically quantify the environmental benefits of component-level innovations across the full life cycle.
To address the environmental performance of energy storage systems, a new class of biodegradable, edible, and recyclable “transient batteries” has emerged.63 These innovations aim to align device lifetimes with application needs while minimizing environmental burdens at end-of-life. The following examples highlight recent advances towards higher environmental and resource performance in this area.
For example, Aeby et al. developed low-power supercapacitors using biodegradable cellulose substrates and aqueous inks, although their energy density and lifespan restrict broader applicability.64 Similarly, Huang et al. introduced a magnesium–iodine battery with complete dissolution under physiological conditions, achieving coin-cell-level energy density.65 Yet, neither study included formal environmental assessments, leaving their broader environmental trade-offs unquantified.
Biodegradable stretchable batteries are also advancing. Rahmanudin et al. designed a soft battery system with plant-based components and mild degradation pathways.66 While the use of bio-sourced materials and their biodegradability may be justified, the low battery performance and quantification of embodied energy, sourcing impacts, or scalability was not conducted, leaving open questions about broader environmental trade-offs at larger scales. Similarly, Karami-Mosammam et al. used kirigami-structured magnesium and molybdenum electrodes on biodegradable substrates to achieve high mechanical durability and energy density, but again only material degradation under physiological conditions was tested.67
Ilic et al. took a novel approach by developing an entirely edible, rechargeable battery using food-grade components.68 All battery components were proven to be non-toxic and digestible according to food safety standards, offering a safe pathway for disposal through biological metabolism. Environmental performance was considered using biodegradable, renewable, and food-safe materials, although no LCA was conducted. As with other transient technologies, scalability, mass production energy demands, and sourcing impacts remain to be fully considered for broader environmental evaluation.
In contrast, Zhang et al. provides a detailed environmental evaluation of flexible all-organic battery technologies through two complementary studies. In their first study, they performed a cradle-to-gate LCA of laboratory-scale all-organic batteries, identifying major environmental hotspots such as solvent use, catalyst consumption, and energy-intensive synthesis steps.69 In a follow-up study, they extended their analysis to a prospective LCA, modelling the environmental impacts of industrial-scale production and comparing future all-organic batteries to conventional flexible lithium-ion batteries.70
Mittal et al. integrated their innovation with an environmental assessment within a single study.71 They introduced a transient zinc-ion battery specifically designed from the bottom up for high environmental performance. Their battery combined a biodegradable polydopamine-derived organic cathode, a zinc metal anode, and a benign aqueous electrolyte, packaged within biodegradable substrates. The device achieved excellent electrochemical performance with an ultralong operational lifespan of over 10000 cycles while retaining mechanical flexibility suitable for wearable applications. Additionally, they conducted a cradle-to-gate LCA to quantify the environmental impacts of raw material extraction, battery fabrication, and packaging in terms of 18 impact categories. The analysis revealed that the energy consumption, particularly from oven drying, represented the dominant contribution to most environmental categories. Although this could be a lab-scale artefact that would not be there during large-scale manufacturing, while the materials themselves contributed minimally due to their benign and abundant nature. The study highlighted clear improvement strategies for future pilot-scale manufacturing, notably through energy optimization and material substitution.
Expanding beyond batteries, other studies have assessed the sustainability of alternative power sources. Välimäki et al. studied how replacing poly(ethylene terephthalate) (PET) made from virgin raw material with recycled PET (rPET) and bio-based polymers as well as metals and metal oxides with poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) affected the environmental footprint of organic photovoltaics (OPVs).72 The authors also examined the scalability in the manufacturing of these devices by using printing techniques. Both cumulative energy demand and greenhouse-gas emissions were assessed in a life cycle perspective for six different devices and the authors were able to compare the different footprints of both the polymer substrates and the metals with PEDOT:PSS. Still, there are other potentially interesting impact categories, and no attempt to model future impacts of the technology were performed.
Similarly, Ahmed et al. conducted an LCA on two different triboelectric nanogenerators (TENGs) where one was based on an earlier study.73 In addition, the authors also included a techno-economic analysis. In this study, the authors highlighted the environmental hot spots of the TENGs and show the competitiveness of the technology compared to photovoltaics when it comes to energy payback time (EPBT). 11 different impact categories were considered, and a thorough sensitivity analysis covering different design parameters was performed. Even if the two TENGs had different operation modes and efficiencies, the use phase as well as the EoL was excluded from the assessment, and no prospective assessment was performed.
Across the examples surveyed, most studies focused primarily on achieving material-level environmental performance measures, such as biodegradability, bio-sourced or biocompatible materials (Aeby et al., Huang et al., Danninger et al., Rahmanudin et al., Ilic et al.). Environmental performances were typically demonstrated through simplified material degradation tests or qualitative descriptions of benign components, but systematic quantification of life cycle impacts remained rare. Mittal et al. and Zhang et al. stand out for incorporating cradle-to-gate LCAs of their systems.
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Fig. 3 Illustration of the different stages of the technology evolution process at pre-commercialisation and our recommended approach of when and how to integrate environmental assessment. |
Degradability might even be a problem if recycling practices are in place and there is degradation of materials during recycling processes, referred to as “downcycling”.75 Exceptions where degradability might be beneficial also in a life-cycle perspective include applications where recycling and other R strategies are particularly challenging, like for electronic implants inside the human body. In such cases, degradation in the body (or subsequently in the environment) might be a preferable EoL option. However, we dissuade from considering degradability a proxy for environmental performance in general. Instead, we recommend performing LCA studies where different EoL options are considered, thereby revealing the most environmentally preferable option(s). In that context, results from degradability studies can be used as input data for, e.g., landfill options. Degradability results can thus be part of a more holistic environmental assessment, rather than stand-alone proxies for environmental performance.
In addition, we note that several of the reviewed studies consider biodegradation to limited extents (see Table 2). Sometimes, the conditions applied are far from those present in the human body or the environment, e.g., with higher/lower pH or temperature. Also, sometimes only part of the device was subject to biodegradability tests, or the test was run over a too short amount of time only proving partial degradation but claiming that the whole device is biodegradable. Such constraints limit the environmental relevance of biodegradability tests and makes the measured result an even less of a valid proxy for environmental performance. We therefore recommend that degradability tests are performed for the entire device and under relevant conditions for the envisioned EoL scenario.
As evident from several of the reviewed studies, lab-scale LCAs can yield relevant information about environmental performance, not least to experimental researchers engaged in the early-stages of the research process. However, lab-scale LCAs lack a prospective perspective, which introduces some limitations. When technologies mature and production processes are scaled up to match increasing demand, production processes and other activities in the life cycle typically change. For example, magnetic stirrers and manual transfer of liquids are typically replaced by in-tank stirring and pumping at larger scale.81 This means that some hotspots identified at lab scale might change in the future, regardless of whether they are highlighted in a lab-scale LCA or not. For example, extensive use of solvents or placing individual substrates in massive ovens will likely be subject to solvent recirculation and more efficient, continuous ovens, if ever scaled up. In addition, comparing lab-scale to large-scale technologies can often be of questionable relevance, since the lab-scale technology has not had time to develop yet.44 Lab-scale technologies are therefore questionable to assess in LCAs with the aim to make comparative assertions to anything but other lab-scale technologies. Therefore, pointing out such hotspots at the lab scale can be of limited value. By performing upscaling already in the LCA study, likely hotspots at large-scale production can instead be identified. Naturally, such upscaling comes with uncertainties, but it can nevertheless potentially provide more relevant results. The functional units used in the lab-scale LCAs are mainly a certain area of the wearable electronic device (e.g., 1 m2) (see Table 1). For power sources, 1 kWh storage capacity is often used, which is also common in LCAs of non-flexible batteries.82 However, the surface area of a device tells little about its technical performance and does not allow for comparisons to other technologies with different per-area performance. Turning to functional units that more reflect the function of wearable devices might be advisable, particularly for comparative LCAs.
Such functional units that consider the performance and specific properties of materials can allow more meaningful (“apples-to-apples”) comparisons in LCAs, especially for new materials.83 Below, we explore several alternative functional units that were applied at early stages of development.
For energy storage devices, a functional unit of 1 kWh stored, or 1 kWh energy throughput is conventional in LCAs of traction and stationery batteries and might be useful for wearable energy storage devices as well.84 For example, a novel organic battery with low specific energy (Wh kg−1) will need more material per unit of energy stored and will then show higher impacts per kWh.70
Similarly, flexible and stretchable conductors used as interconnects in PCBs often use critical raw materials with metals such as Ag, Au, and Ga, or specialized nanomaterials (CNTs, graphene, etc.). Replacing or reducing certain metals (like using less silver or avoiding scarce indium) is a common strategy to reduce the environmental impact.25 Incorporating material usage efficiency by metrics like specific conductivity (Siemens per meter over gram per cubic centimetre, S m−1 g−1 cm3) considers volumetric density and mass of conductor used.85 A strictly mass-based comparison (impact per kg) would favour carbon or copper over silver since silver's production footprint is much higher. However, silver has a higher conductivity, meaning much less is needed to achieve a given electrical performance. This is where performance-based metrics are essential. Nassajfar et al. introduced a “double-parameter comparison” for printed conductive inks that simultaneously evaluates their environmental impact and electrical conductivity.86 They showed that while replacing silver flakes with copper or graphite significantly reduces impact, the lower conductivity of those alternatives must be accounted for in functional terms.
Sensors in wearables can similarly benefit from more performance- and property-related functional units. Rather than impacts per sensor or per cm2 of sensor area, one can define the unit in terms of sensing performance, such as “per detection event”, “per unit of sensitivity achieved”, or “per measure of signal quality over a device's life”. A recent LCA of printed sensors used the functional unit for monitoring a target gas at a given detection limit for one day.87 This kind of functional unit captures environmental impacts per achieved sensing function.
By using performance- and property-based units, researchers can identify which materials or components contribute the most to environmental burdens per unit of function. This can encourage both environmental impact reduction and improvements in technology performance as the technology develops.
That said, we acknowledge that prospective LCA constitutes an advanced environmental assessment approach, which might sometimes be difficult to apply at the very early stages of the research process and requires certain competences. Furthermore, approaches to change some background system processes over time across the whole life cycle exist (such as electricity and cement production), but these approaches require specific LCA software, and do not yet contain all potential inputs to life cycles (e.g., not yet chemicals).45 While there exists guidance on how to scale up chemical processes,81 other aspects of emerging technologies can be more challenging to scale up.
Early-stage innovations might show great performance in the lab, but their scalability, sustainability and long-term durability in real-world conditions are unproven. They generally lack a mature manufacturing infrastructure and supply chain, meaning there are few existing facilities, suppliers, or trained workers ready to produce them at scale.89 Economically, new technologies do not yet benefit from economies of scale, so unit costs remain high and critical materials or components may be scarce or hard to source, creating supply-chain constraints. Indeed, moving from controlled laboratory prototypes to practical, large-scale deployment is often the hardest step (the infamous “valley of death” where many fail).90 There may also be existing regulatory hurdles, where novel products can fall outside, requiring new testing protocols and approvals before they can enter the market.
In the next section, we provide further recommendations about the timing and integration of different environmental assessment approaches into innovation of wearable electronics.
– Stage 1: idea conception & research phase.
– Stage 2: development of proof-of-concept at the lab scale.
– Stage 3: optimizing and scale up.
To this list, a subsequent step 4 involving commercialization can be added (Fig. 3), at which the product can be subjected to more standardized assessments of environmental performance, such as conventional LCA standardized in environmental product declaration guidelines.92 Some examples of wearable electronics that have already been subject to such assessments were identified in the review.93,94 However, the present perspective mainly concerns the pre-commercialisation steps 1–3 related to the research and innovation process.
• Applying the principles of green chemistry during the conception of the idea and the research phase.96,97
• Selecting starting materials from renewable and abundant sources, as opposed to fossil or other scarce sources. There are several comprehensive review articles that discuss the use and properties of sustainable materials in wearable devices ranging from electronic16,24,98,99 and energy14,63 components, large-area manufacturing13,100 to packaging/encapsulation layers.46,101,102
• Identifying the hazard classification of materials, such as avoiding REACH27 or Classification, Labelling and Packaging (CLP)-listed substances,103 and using chemical databases such as Chemsec's Substitute It Now (SIN) list.104
• Presumed environmentally benign process settings, such as solvent-free or the use of low-toxicity solvents (e.g., aqueous media, biocompatible liquids), mild processing conditions (e.g., low temperature (<100 °C), vacuum-free and ambient environments).
• EoL considerations should depend on the design concept and tuned accordingly, such as recyclability, composability, persistent materials, or bioresorbable systems. Biodegradation can be part of such heuristic evaluations, but as discussed in Section 4.1 should not be seen as the sole proxy for environmental performance.
• Process upscaling using stoichiometric modelling, equipment scaling, and/or proxy industrial data.
• Energy grid projections using tools like the above-mentioned premise to model future electricity mixes.
• Modelling of the use phase, including integration with energy recovery or power management.
• Scenario modelling of different EoL routes, such as reuse, recycling, biodegradation, incineration, and landfilling.
• Limited LCA expertise: many experimental research groups do not have in-house training or experience in performing LCAs, especially not prospective LCA. We recommend that experimentalist collaborate with environmental scientists and LCA practitioners to effectively carry out such analyses, primarily at Stage 2 (Fig. 3). Not only will it help bridge this expertise gap and ensure the assessment is done rigorously, but it will also foster closer interactions between the two disciplines.
• Data availability: as discussed earlier, obtaining reliable life cycle inventory data for novel materials or lab-scale processes under development is difficult at early research stages. Researchers may need to generate primary data or use proxy data for new materials, which adds uncertainty, especially in prospective LCA. Experimentalists may also face resource limitation in accessing inventory data. This emphasizes why data limitations can hinder comprehensive environmental assessments at the early stages (Stage 1 and 2) of the development (Fig. 3).
• Resource and time constraints: performing (especially prospective) LCA requires considerable time, effort, and sometimes specialized software or database access. While it is reasonable that early-stage research projects developing sustainable technologies prioritize funding for material or process development, some allocation of resources to performing LCA is also advisable.
Together, these recommendations underline the need for an approach that enables researchers and developers to embed environmental assessment into the innovation pipeline from the outset. Overcoming the design paradox requires new approaches to sync environmental assessment and wearable material innovation. The recommendations are broadly aligned with more general calls for early consideration of environmental performance during the research process, such as the EU's safe and sustainable by design framework for chemicals and materials,106 the EU Green Electronics working group that discusses the best practices of defining and achieving green electronics in hybrid printed electronics,107 and Sweden's Wallenberg Initiative on Materials Science for Sustainability (WISE).108 Our recommendations focus on wearable electronics by providing clearer guidance regarding which environmental assessment method to apply, and when during the research process they are feasible and most relevant.
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