Issue 20, 2025

Dendrite-free, interfacially compatible Na2ZrCl6 composite halide solid-state electrolyte for solid-state sodium-ion batteries

Abstract

Low ionic conductivity and poor interfacial stability restrict the practical application of all-solid-state sodium-ion batteries (ASSSIBs). To solve these issues, a facile strategy involving the use of an inorganic–organic composite solid electrolyte (SE) composed of Na2ZrCl6 and polyacrylonitrile (PAN) is proposed. The introduction of Na2ZrCl6 results in a reduction in the crystallinity of PAN, which creates numerous pathways for Na+ ions migration and significantly enhances the ionic conductivity of SE. When utilized in a Na‖Na symmetric cell, the Na2ZrCl6–PAN SE exhibited good interfacial stability, with no Na dendrite formation even after 5000 h of Na electroplating/stripping. In addition, non-in situ X-ray diffraction, X-ray photoelectron spectroscopy, and in situ AC impedance tests confirmed the favorable interfacial stability of the Na2ZrCl6–PAN SE in contact with Na metal and Na3V2(PO4)3 (NVP). Furthermore, Na|Na2ZrCl6–PAN|NVP ASSSIBs exhibit outstanding electrochemical performance. The battery achieves an initial discharge capacity of 80.7 mA h g−1 at 1 C, which remains at 69.2 mA h g−1 after 500 cycles. Additionally, all-solid-state SIBs with a hard carbon (HC)|Na2ZrCl6–PAN|NVP ASSSIB configuration demonstrate excellent electrochemical cycling stability.

Graphical abstract: Dendrite-free, interfacially compatible Na2ZrCl6 composite halide solid-state electrolyte for solid-state sodium-ion batteries

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Article information

Article type
Paper
Submitted
08 Nov 2024
Accepted
08 Apr 2025
First published
10 Apr 2025

J. Mater. Chem. A, 2025,13, 15178-15188

Dendrite-free, interfacially compatible Na2ZrCl6 composite halide solid-state electrolyte for solid-state sodium-ion batteries

H. Tian, J. Li, Y. Cai, X. Yao and Z. Su, J. Mater. Chem. A, 2025, 13, 15178 DOI: 10.1039/D4TA07957D

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