Hung Van
Tran
a,
Hao Anh
Phan
b and
Ha Manh
Bui
*c
aInstitute of Environmental Science, Engineering and Management, Industrial University of Ho Chi Minh, Ho Chi Minh City 700000, Vietnam
bDepartment of Chemical Engineering, National Chung Hsing University, Taichung 40227, Taiwan
cFaculty of Environment, Saigon University, Ho Chi Minh City 700000, Vietnam. E-mail: manhhakg@sgu.edu.vn
First published on 28th December 2024
This study employs Life Cycle Assessment (LCA) to evaluate the environmental impacts of wastewater treatment systems in industrial zones of Vietnam. Focusing on two treatment technologies—Anoxic–Oxic (OA) and Sequencing Batch Reactor (SBR)—as well as different electricity production methods and sludge management strategies, the research aims to identify opportunities for enhancing sustainability and reducing environmental footprints. Utilizing the ReCiPe v1.13 method and SimaPro 9.6.0.1 software, the study assesses key impact categories: climate change, freshwater eutrophication, human toxicity and freshwater ecotoxicity. The results showed that the OA system resulted in 30% lower climate change impacts than the SBR system (0.61 vs. 0.87 kgCO2 eq) but 24% higher freshwater eutrophication (6.17 × 10−4vs. 4.69 × 10−4 kgP eq). Utilizing electricity produced from natural gas resulted in an 8.4% reduction in climate change impacts compared to using electricity from the local grid (0.6 vs. 0.66 kgCO2 eq) and an 81% reduction in freshwater ecotoxicity (1.29 × 10−3vs. 2.18 × 10−5 kg1,4-DB eq). Additionally, endpoint analysis of Scenario 0 highlights that the AAO biological and coagulation tanks are the main contributors to Human Health and Resource impacts, with respective scores of 13.8 mPt and 11.5 mPt, demonstrating areas for targeted improvement. The utilization of sewage sludge as fertilizer reduces the impact on climate change by 80% (0.036 vs. 0.3 kgCO2 eq) and nearly eliminates freshwater eutrophication (5.01 × 10−6vs. 1.77 × 10−4 kgP eq) compared to landfill. These findings provide detailed insights into different treatment processes and resource utilization strategies, offering a robust framework for enhancing sustainability in developing countries.
Sustainability spotlightIndustrial wastewater treatment in Vietnam is crucial due to its significant environmental impact and the need for effective management practices. Our study advances sustainability by employing Life Cycle Assessment (LCA) to compare the environmental performance of Anoxic–Oxic (OA) and Sequencing Batch Reactor (SBR) technologies. This approach provides insights into energy use, emissions and sludge management, promoting more sustainable practices in wastewater treatment. By identifying more efficient technologies and practices, our work contributes to reducing environmental burdens and supports the UN Sustainable Development Goals (SDGs), particularly SDG 6 (Clean Water and Sanitation) and SDG 12 (Responsible Consumption and Production), by improving the sustainability of industrial wastewater management. |
Industrial zones, with their concentration of manufacturing activities, are essential to the economy but are also significant sources of environmental pollution. If wastewater treatment systems in these zones are not effectively designed and managed, they can contribute to water, air and soil pollution, as well as increase greenhouse gas emissions.2,3 Therefore, enhancing the efficiency and sustainability of these systems is crucial.
Life Cycle Assessment (LCA) is a critical tool for evaluating the environmental impacts of products and processes. It has gained traction in recent years as a method for assessing wastewater treatment systems. LCA examines emissions and resource use throughout a system's life cycle, identifying opportunities to enhance efficiency and reduce environmental impact.4 In developing countries, where wastewater infrastructure often lags behind, LCA can provide a structured approach to improve wastewater treatment processes, optimize resource allocation and reduce energy consumption.5 For instance, studies have shown that improvements in biogas recovery and sludge management through LCA can significantly reduce greenhouse gas emissions and overall environmental footprint.6
As demonstrated in multiple studies, the global application of LCA in industrial wastewater treatment has been expanding. A significant number of studies have applied LCA to industrial wastewater, particularly in countries like China, India and Brazil, where industrial activities are booming.5 However, even though many developing countries have shown interest in LCA, the application of LCA in Vietnam's wastewater treatment sector, particularly in industrial wastewater systems, remains limited.7 This limitation represents a gap in the broader effort to mitigate environmental damage and improve sustainability in this region.
Applying LCA to industrial wastewater treatment systems could provide several significant benefits. First, LCA can identify the stages or processes with the most considerable environmental impacts, enabling targeted improvements.8 Second, it offers a scientific basis for comparing and selecting treatment technologies that optimize both performance and environmental impact.9 Lastly, by supporting the net-zero emissions goal, LCA can help businesses and policymakers better understand the primary sources of emissions and develop appropriate mitigation strategies.10,11
This study investigates the potential benefits of applying LCA to industrial wastewater treatment systems in Vietnam, where its use has been limited. By focusing on specific case studies within actual wastewater treatment systems, the research aims to demonstrate how LCA can help minimize harmful environmental impacts. The study also highlights the use of clean energy and sludge recovery for fertilizer, offering a comprehensive perspective on waste reuse and natural gas utilization in the context of a developing country where environmental concerns are still emerging.
A cradle-to-gate approach was adopted for this study, focusing on the operational phase due to limited data on the construction and demolition stages. This approach encompasses all chemical, energy and transport consumption related to wastewater treatment processes. The system boundary, illustrated in Fig. 1, includes wastewater inflow, treatment processes, energy inputs, sludge handling and treated water outputs but excludes upstream impacts such as infrastructure development and transportation of end products like fertilizer to users.
Industrial wastewater from factories within the park is channeled into the centralized treatment plant. In the regulation tank, the flow and concentration of the wastewater are balanced for optimal processing. Next, in the coagulation–flocculation stage, pollutants are removed. Biological treatment then follows, utilizing OA technology during the first construction phase and SBR technology during the second. Once biologically treated, the wastewater undergoes disinfection to eliminate harmful bacteria before being discharged into the nearby river. Sludge produced during treatment is dewatered and either buried in a landfill or reused as fertilizer, depending on the operational scenario.
To evaluate and compare the environmental impacts, four operational scenarios were analyzed based on experimental data:
✓ Scenario 0 (baseline – green): the plant operates with OA as the primary treatment technology and dewatered sludge is buried in a landfill.
✓ Scenario 1 (red): a comparison of the two treatment technologies—OA and SBR—to assess environmental performance differences.
✓ Scenario 2 (blue): the plant operates entirely on energy sourced from natural gas instead of the local power grid.
✓ Scenario 3 (orange): biological sludge is either reused as DAP (diammonium phosphate) fertilizer or buried in a sanitary landfill.
Parameters | Unit | Influent | Effluent |
---|---|---|---|
pH | 6–6.5 | 7.5–8 | |
BOD | mg L−1 | 410–453 | 25–27 |
COD | mg L−1 | 800–885 | 52–58 |
Total suspended solids | mg L−1 | 384–424 | 43–47 |
Residual chlorine | mg L−1 | 2–2.1 | 0.4–0.42 |
Total nitrogen | mg L−1 | 55–61 | 2.5–3 |
Total phosphorous | mg L−1 | 5.3–6 | 0.45–0.52 |
Direct N2O emissions from wastewater treatment were calculated according to Bao et al., 2016 (ref. 14) and Liu et al., 2014.15 Operational data provided by plant managers and data collected in January 2024 were used as baseline inventory data. The life cycle inventory (LCI) is presented in Table 2.
Processes | Influent | Value | Unit | Effluent | Value | Unit |
---|---|---|---|---|---|---|
Equalization | Wastewater | 1500 | m3 | Wastewater | 1499.93 | m3 |
Electricity | 21 | kW h | Waste (solids, grease, sand) | 70 | kg | |
Coagulation and flocculation tank | Wastewater | 1499.93 | m3 | Wastewater | 1497.93 | m3 |
Electricity | 32.016 | kW h | Sludge | 514.2 | kg | |
PAC | 75 | kg | ||||
NaOH | 5 | kg | ||||
PAM | 8.2 | kg | ||||
Transports, chemicals | 3.969 | tkm | ||||
OA | Wastewater | 1497.93 | m3 | Wastewater | 1496.93 | m3 |
Electricity | 95.874 | kW h | Sludge | 360 | kg | |
NaOH | 5.625 | kg | N2O (emission) | 1.392 | kg | |
Molasses | 5 | kg | ||||
Transports, chemicals | 0.47813 | tkm | ||||
Disinfection tank | Wastewater | 1496.93 | m3 | Wastewater | 1496.93 | m3 |
Electricity | 12.7 | kW h | ||||
NaOCl | 49.89 | kg | ||||
Transports, chemicals | 2.24505 | tkm | ||||
Sludge storage and dewatering tank | Electricity | 12.41 | kW h | Sludge | 874.2 | kg |
PAM | 16.3 | kg | ||||
Transports, sludge | 17.484 | tkm | ||||
Transports, chemicals | 0.7335 | tkm | ||||
SBR | Wastewater | 1497.93 | m3 | Wastewater | 1496.93 | m3 |
Electricity | 60.69 | kW h | Sludge | 403 | kg | |
Molasses | 13.76 | kg | N2O (emission) | 2.82495 | kg | |
Transports, chemicals | 0.6192 | tkm |
The DAP fertilizer recovered from the sludge in the bioreactor is based on the assumption that the fertilizer production efficiency is 80% of the total phosphorus content in the sludge (assuming all treated phosphorus is converted into sludge). The baseline data is derived from the ecoinvent v3.10 database, as detailed below:
• Electricity production in Vietnam (Hydro electricity 36.6%, thermal power 44.1%, electricity from oil 2.2%, electricity from gas 13.1%, electricity from renewable energy 4.1%).16
• Chemical production: data on chemical production (PAC, PAM, molasses, NaOH, DAP, etc.).
• Lorry with a capacity of 3.5–7.5 tons (Euro 5) are selected as means of transporting chemicals.
• Lorry with a capacity of 7.5–16 tons (Euro 5) are selected as means of transporting sludge.
• Electricity production using natural gas.
As mentioned, the utilization of sludge for DAP fertilizer production is considered a recovered product. Therefore, it is considered as an avoided product of equivalent production processes.18 Since they represent an environmental benefit in the total impact of the system, they are subtracted from the system and shown as a negative value in the interpretation of the results.
Impact category | Unit | Total | Equalization tank | Coagulation and flocculation tank | OA | Disinfection tank | Sludge storage and dewatering tank |
---|---|---|---|---|---|---|---|
CC | kg CO2 eq | 6.06 × 10−1 | 9.20 × 10−3 | 1.31 × 10−1 | 3.24 × 10−1 | 9.02 × 10−2 | 5.11 × 10−2 |
OD | kg CFC-11 eq | 6.46 × 10−9 | 3.94 × 10−11 | 4.10 × 10−9 | 7.38 × 10−10 | 8.32 × 10−10 | 7.47 × 10−10 |
TA | kg SO2 eq | 1.72 × 10−3 | 6.63 × 10−5 | 7.12 × 10−4 | 3.31 × 10−4 | 3.87 × 10−4 | 2.24 × 10−4 |
FE | kg P eq | 6.17 × 10−4 | 3.50 × 10−6 | 4.77 × 10−5 | 1.83 × 10−5 | 5.37 × 10−4 | 1.13 × 10−5 |
HT | kg 1,4-DB eq | 1.34 × 10−1 | 2.90 × 10−3 | 6.57 × 10−2 | 1.57 × 10−2 | 3.70 × 10−2 | 1.27 × 10−2 |
PCOF | kg NMVOC | 1.19 × 10−3 | 3.55 × 10−5 | 4.99 × 10−4 | 1.83 × 10−4 | 2.95 × 10−4 | 1.75 × 10−4 |
PMF | kg PM10 eq | 7.09 × 10−4 | 2.04 × 10−5 | 2.91 × 10−4 | 1.07 × 10−4 | 2.13 × 10−4 | 7.66 × 10−5 |
TET | kg 1,4-DB eq | 4.61 × 10−5 | 3.05 × 10−7 | 2.52 × 10−5 | 2.31 × 10−6 | 1.04 × 10−5 | 7.82 × 10−6 |
FET | kg 1,4-DB eq | 7.79 × 10−3 | 9.68 × 10−5 | 3.55 × 10−3 | 6.09 × 10−4 | 2.58 × 10−3 | 9.57 × 10−4 |
IR | kBq U235 eq | 1.62 × 10−2 | 3.39 × 10−5 | 6.58 × 10−3 | 6.77 × 10−4 | 7.42 × 10−3 | 1.48 × 10−3 |
To gain a deeper understanding of the scale of the impact indicators, the indicator results were normalized using the ReCiPe/World H v1.13 reference method (Fig. 2). The scale of the indicators is highlighted here. Scenario 0 has the highest environmental impact on FE (0.0021) followed by FET and HT at 0.0018 and 0.0004, respectively. The results show that although climate change has the largest impact on WWTP, its total impact on global climate change is negligible. Therefore, the impact categories associated with Scenario 0 are FE, FET and HT.
The results presented in Fig. 3 show that the FE indicator was assessed over the entire life cycle, including direct nutrient emissions from the wastewater treatment system to the receiving environment, as well as indirect emissions from energy production, supply and chemical inputs used in various treatment processes. For the OA treatment technology, the influent water quality is detailed in Table 1. Fig. 4 highlights that nutrient emissions from the treatment system constitute the majority of the FE indicator, accounting for up to 81%, while indirect impacts from the system contribute approximately 19%. This finding aligns with other studies, which indicate that WWTPs often retain nutrients, particularly nitrogen and phosphorus in the water.8,19,20 These results suggest that FE can be reduced by implementing more effective treatment methods to thoroughly remove nitrogen and phosphorus from the water.21 This would not only enhance the quality of fertilizer production but also help reduce eutrophication at the receiving water bodies.
The FET indicator, which reflects the potential release of harmful chemicals into the environment during the life cycle of a product or process,22 highlights the significant impact of chemical-intensive stages such as coagulation, flocculation, disinfection and sludge dewatering. Specifically, these stages contribute 45.4%, 33.1% and 12.3% to the FET index, respectively. Of these, polyaluminum chloride (PAC), used for coagulation, contributes about 36% to the total FET index, while sodium hypochlorite (NaOCl), a disinfectant, accounts for approximately 32.2%. Additionally, polyacrylamide (PAM), used in dewatering and sludge flocculation, contributes around 17%. These figures underscore the importance of managing chemical use in water treatment processes to minimize environmental impacts.
Each process within a treatment plant has the potential to cause toxicity and affect human health. The HT indicator must be carefully considered, especially in relation to the benefits of reducing other indicators such as CC, FE and FET. Notably, toxic impacts often do not arise directly from emissions into the air or wastewater but rather from indirect activities such as mining, chemical production and energy generation. Fig. 4 clearly demonstrates that chemical processes involving PAC, NaOCl, PAM and electricity contribute significantly to toxicity.17
In the LCA analysis, the OA treatment process contributes the largest share to the CC indicator, accounting for 53.5%. Other treatment processes, such as coagulation and flocculation, disinfection, sludge storage and dewatering and equalization, contribute 21.7%, 14.9%, 8.42% and 1.52%, respectively. Nitrous oxide (N2O), a potent greenhouse gas with a global warming potential 300 times greater than that of carbon dioxide (CO2),23 is produced during nitrogen conversion in WWTPs and accounts for 45.6% of emissions from biological treatment systems.24 Additionally, the use of electricity and various chemicals in wastewater treatment also significantly impacts the CC indicator, contributing between 10% and 15%. The total impact on the CC indicator in this study is 0.6 kgCO2 eq m−3. Similar results were also shown in the study of Pasqualino et al. (2011) with the traditional 3 step treatment system with CC index of about 0.8 kgCO2 eq m−3 (ref. 25) and fluctuating around 0.4–0.86 kgCO2 eq m−3 with the study of Bao et al. (2016).14 In contrast, factors such as transportation, nutrients and sodium hydroxide (NaOH) during the treatment stages have a negligible impact on the CC indicator. This finding contrasts with studies by previous studies,6,20,26 which identified energy consumption as the largest contributor to the CC indicator. This difference may be due to the relatively low energy consumption of the WWTP in this study, which is approximately 0.116 kW h m−3, a small figure compared to the range reported by Li et al. (2021)19 of 0.036 to 2.17 kW h m−3, corresponding to 0.055 to 5.3 kgCO2 eq m−3.
Fig. 4 illustrates the endpoint analysis for the treatment system, showing a trend consistent with the midpoint assessment, with impacts expressed in a common unit, mPt. The total impact score is 37.9 mPt, distributed across Human Health (24.8 mPt), Resources (10.9 mPt) and Ecosystems (2.22 mPt). The AAO biological tank and coagulation tank are the most impactful stages, contributing 13.8 mPt and 11.5 mPt, respectively. Notably, the AAO tank accounts for 10.8 mPt in the Human Health category, the largest contributor to this impact, while the coagulation tank significantly affects Resource consumption, contributing 4.26 mPt. Table 4 compares the endpoint results with other wastewater treatment technologies, including UASB, activated sludge and MBBR. In the Human Health category, this system (24.8 mPt) performs better than activated sludge (35.22 mPt) and MBBR (28.6 mPt) but exhibits higher impacts than UASB (15.67 mPt). For Ecosystems, the impact of this system (2.22 mPt) is comparable to MBBR (2.6 mPt) and lower than activated sludge (4.82 mPt), showcasing its reduced ecological footprint. In Resource consumption, the system (10.9 mPt) demonstrates a balanced performance, with impacts lower than MBBR (15.9 mPt)27 but higher than UASB (8.03 mPt) and activated sludge (8.08 mPt).28 These findings underline the competitive advantages of the treatment system in this WWTP, particularly its lower ecological and resource-related impacts compared to activated sludge and MBBR systems. The integration of the AAO biological and coagulation tanks effectively addresses key environmental categories, making this system a promising alternative for achieving balanced sustainability in wastewater treatment.
Each LCA methodology reveals different impact points. For example, electricity generation in Vietnam emits approximately 0.66 kgCO2 eq kW−1 h−1 from the grid and 1.06 kgCO2 eq kW−1 h−1 from gas. In comparison, electricity generation from coal power in Indonesia also emits about 1.06 kgCO2 eq kW−1 h−1, while Singapore emits approximately 0.45 kgCO2 eq kW−1 h−1, Japan 0.4 kgCO2 eq kW−1 h−1, Korea 0.49 kgCO2 eq kW−1 h−1, Malaysia 0.69 kgCO2 eq kW−1 h−1 and Thailand 0.63 kgCO2 eq kW−1 h−1.32,33
However, the indicators in this study do not show negative emissions as reported by Pintilie et al. (2016),8 possibly due to the limited amount of sludge recovered for fertilizer production and technical constraints. Nevertheless, the use of sludge as fertilizer is still an important step towards the goal of resource utilization. In addition, other sludge management methods, such as incineration, wet oxidation, pyrolysis and recycling with cementitious materials, have been explored in the literature.34,35
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