Issue 26, 2025

Comparative molecular dynamics simulation studies of simple and polymerized ionic liquids

Abstract

We perform molecular dynamics simulations to compare the structures and dynamics of a simple and a polymerized ionic liquid. The latter comprises [BF4] anions and [(CH2)6–C3H3N2]25 cations and, hence, the charged imidazolium rings are, unlike in most previous studies, embedded in the polymer backbone rather than in side chains. It is found that cation polymerization weakly affects the local structure but leads to a strong slowdown and an enhanced heterogeneity of the dynamics. Despite strongly different diffusion coefficients of the anions and polymerized cations, reflecting single ion conductor behavior, the structural relaxation of the anions remains coupled to the segmental polymer motion. A comparison with literature results indicates that polymerized cations with embedded and pendant imidazolium rings exhibit different anion association and cause different anion transport mechanisms, with prevailing diffusive and hopping motions, respectively. In addition, we observe that the Rouse model reasonably well describes the polymer dynamics in our case of charged chains strongly interacting with counterions. Specifically, it captures the static amplitudes and time constants of the lower Rouse modes, while there are strong deviations from the model predictions for the higher Rouse modes, which are associated with smaller length scales and sensitive to structural and dynamical heterogeneity related to polycation–anion association.

Graphical abstract: Comparative molecular dynamics simulation studies of simple and polymerized ionic liquids

Supplementary files

Article information

Article type
Paper
Submitted
24 Mar 2025
Accepted
23 May 2025
First published
09 Jun 2025

Soft Matter, 2025,21, 5231-5241

Comparative molecular dynamics simulation studies of simple and polymerized ionic liquids

A. Ahmad, R. Köster, S. Kloth and M. Vogel, Soft Matter, 2025, 21, 5231 DOI: 10.1039/D5SM00307E

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