Open Access Article
This Open Access Article is licensed under a
Creative Commons Attribution 3.0 Unported Licence

Breaking the p-type doping barrier in β-Ga2O3: a GaN-based heterojunction bipolar transistor with high gain, high breakdown, and RF capability

Phuc Hong Than*a, Tho Quang Thanb and Yasushi Takakic
aDuy Tan University (DTU), 3 Quang Trung, Hai Chau, Danang 550000, Vietnam. E-mail: thanhongphuc@duytan.edu.vn
bCentral Power Corporation (EVNCPC), 78A Duy Tan, Hoa Thuan Dong, Hai Chau, Danang 550000, Vietnam
cPower Device Works, Mitsubishi Electric Corporation, 997, Miyoshi, Koushi-shi, Kumamoto 861-1197, Japan

Received 23rd September 2025 , Accepted 30th September 2025

First published on 8th October 2025


Abstract

Despite extensive research on unipolar β-Ga2O3 semiconductor devices, the advancement of bipolar devices, particularly heterojunction bipolar transistors (HBTs), has been significantly hindered by the lack of reliable p-type doping in β-Ga2O3. In this paper, we present the first comprehensive simulation study of a functional HBT based on an n-type β-Ga2O3 emitter, a p-type GaN base, and an n-type GaN collector, aiming to address the critical challenge of p-type doping in β-Ga2O3 for bipolar devices. The proposed Ga2O3/GaN HBT, simulated with full consideration of traps, exhibits a maximum DC current gain (βDC) of 18.3, a high collector current density (JC) of 14.3 kA cm−2, a collector–base breakdown voltage (BVCBO) of 120 V, a power figure of merit (PFOM) of 41.3 MW cm−2, and a low specific on-resistance (Ron,sp) of 0.35 mΩ cm2. The temperature-dependent current–voltage (IV) characteristics from 300 K to 460 K reveal stable operation up to 460 K, albeit with a 31.1% reduction in βDC and a 30.0% decline in PFOM due to carrier mobility degradation and enhanced recombination. Furthermore, device performance was optimized by engineering the base and collector thicknesses. The results indicate that a thin base (0.05 μm) maximizes βDC, while a thick collector (2.0 μm) boosts PFOM to 138 MW cm−2 without compromising gain. In addition, high-frequency simulations show a cutoff frequency (fT) of 30 GHz at 300 K, confirming the device's suitability for RF and power-switching applications. These results indicate that the Ga2O3/GaN HBT is a promising candidate for next-generation power electronics, owing to its unique combination of high breakdown voltage and excellent frequency performance.


1 Introduction

Among wide-bandgap semiconductors such as silicon carbide (SiC), gallium nitride (GaN), and gallium oxide (Ga2O3), beta-gallium oxide (β-Ga2O3) has garnered significant attention due to its ultra-wide bandgap of ∼4.8 eV, high breakdown electric field exceeding 8 MV cm−1, excellent controllability of n-type conductivity through intentional donor doping over a broad carrier concentration range (1015–1020 cm−3), and the availability of large-area, low-defect single-crystal substrates grown by melt-based techniques, which are compatible with various epitaxial growth methods.1–6 Thus, over the past decade, extensive research and development has focused on unipolar devices based on β-Ga2O3 for next-generation high-power and high-frequency applications, such as Schottky barrier diodes (SBDs), metal-oxide-semiconductor field-effect transistors (MOSFETs), and high-electron-mobility transistors (HEMTs).7–20 Prior research at the National Institute of Information and Communications Technology (NICT, Tokyo, Japan), where one of the authors participated, showed that normally-off lateral β-Ga2O3 MOSFETs with nitrogen-doped channels were feasible. The use of nitrogen as a deep acceptor for current-blocking layers in β-Ga2O3-based power devices was validated by the stable performance of these devices at a threshold voltage of +5 V.21,22 However, the lack of reliable p-type doping in β-Ga2O3 has significantly limited the development and investigation of bipolar devices based on this material. As a key technology in high-speed electronics, heterojunction bipolar transistors (HBTs) offer superior frequency response and power-handling capabilities compared to other bipolar devices, making them essential for next-generation RF and power-switching applications. Recently, M. Mehta et al. proposed the use of p-type oxides to realize HBTs based on β-Ga2O3.23 A β-Ga2O3 HBT employing a Cu2O base was simulated to estimate its power figure of merit (PFOM), but its performance was severely constrained by the low bandgap of Cu2O. To address this issue, the authors suggested using alternative p-type oxides with a bandgap of Eg > 3.4 eV and an electron diffusion length >0.4 μm to achieve PFOM values exceeding those of state-of-the-art β-Ga2O3 unipolar transistors. Promising candidates such as NiO and r-GeO2 were identified for their potential to significantly enhance PFOM.23 In this study, we propose a HBT structure based on n-type β-Ga2O3 and p-type GaN. GaN was chosen as the base material due to its wide bandgap of 3.53 eV, greater than the 3.4 eV threshold suggested by Mehta et al., and its high compatibility with β-Ga2O3.24,25 Although Ga2O3/GaN heterostructures for various unipolar and optoelectronic applications have been widely studied and reported, including photodetectors,26–28 light-emitting diodes (LEDs),29–31 gate dielectrics or passivation layers in HEMTs/metal-oxide-semiconductor high-electron-mobility transistors (MOSHEMTs),25,32–38 MOSFETs,39–43 as well as p–n diodes,44–47 their potential in bipolar junction transistors remains entirely unexplored. To the best of our knowledge, no experimental or simulation study on a functional β-Ga2O3/GaN HBT has been reported to date. Here, we report the first comprehensive simulation-based demonstration of an n-β-Ga2O3/p-GaN/n-GaN HBT, incorporating realistic interfacial defects and compensation effects to provide a physically grounded evaluation of its feasibility, performance, thermal reliability, and optimization strategies under practical defect considerations.

2 Structure and mechanism

The schematic of the simulated HBT structure consists of an n-β-Ga2O3 emitter layer with a thickness of 0.15 μm and a doping concentration of ND = 2.0 × 1017 cm−3, a p-GaN base layer with a thickness of 0.05 μm and NA = 2.0 × 1018 cm−3, an n-GaN collector layer with a thickness of 0.55 μm and ND = 5.0 × 1016 cm−3, and an n-GaN subcollector layer with a thickness of 0.15 μm and ND = 2.0 × 1017 cm−3, as illustrated in Fig. 1. Due to the lateral symmetry of the device structure, only half of the HBT was simulated in the TCAD environment with appropriate symmetry boundary conditions. The full cross-sectional structure is shown in Fig. 1 for clarity. The emitter contact is placed on top of the n-Ga2O3 emitter layer to form an ohmic contact, while the base contact is located on the p-GaN base layer. The collector contact is formed on the backside of the n-GaN subcollector layer, also establishing an ohmic contact. The structure, thicknesses, and doping concentrations of the emitter, base, and collector layers in the proposed HBT design are based on those used in InGaP/GaAs heterojunction phototransistors previously fabricated by our group, as reported in ref. 48–50. The key physical models and material parameters used in the simulation, as well as the calibration of model parameters using experimental data, have been described in detail elsewhere.51,52 In this study, a baseline HBT, referred to as the bulk-trap-only HBT (B-HBT), incorporating key defect-related effects such as deep-level electron traps in the Ga2O3 layer, was first established to enhance the accuracy of the simulations. These traps, located at EC −0.6 eV, EC −0.75 eV, and EC −1.05 eV, correspond to the E1, E2, and E3 levels identified in bulk and epitaxial β-Ga2O3 films,53–58 and were included to model carrier trapping and recombination effects more accurately, thereby enhancing the realism of the simulation. To account for experimentally observed non-idealities, a full-trap HBT model, referred to as the F-HBT, was developed. In this case, to simulate the compensation effects induced by oxygen diffusion from the Ga2O3 into the p-GaN base, additional defect mechanisms were incorporated in the p-GaN layer: a shallow donor-like trap representing oxygen substituting nitrogen (ON, EC −0.03 eV)59–62 and the dominant shallow acceptor (EV +0.225 eV) commonly observed in GaN, which is enhanced by oxygen doping and is likely related to a VGa–O–H complex.63,64 At the Ga2O3/GaN interface, an interface trap density (Dit) was introduced to emulate interface defects. A value of Dit ≈ 1.0 × 1012 eV−1 cm−2 was used in our simulation. Although Qian Feng et al. reported even higher Dit values (2.3–5.3 × 1013 eV−1 cm−2) for mechanically exfoliated β-Ga2O3/GaN interfaces,65 using these values resulted in a complete loss of transistor action in our simulations. Therefore, a reduced Dit level was employed to ensure both numerical convergence and preservation of transistor behavior, while still reflecting the experimentally observed interfacial degradation. In addition, polarization-induced charges were enabled with a scaling factor to capture the effect of polarization mismatch and strain relaxation at the monoclinic β-Ga2O3/hexagonal GaN interface.66 This comprehensive trap and interface model (F-HBT) provides a physically grounded description of bulk and interfacial recombination pathways and allows a more rigorous assessment of the degradation mechanisms in Ga2O3/GaN HBTs. The modeling assumptions employed in the F-HBT model are not merely hypothetical but are substantiated by experimental findings reported in the literature.66 In particular, structural and chemical characterizations of β-Ga2O3/GaN heterostructures have consistently revealed interfacial traps, strain-induced dislocations, and oxygen-related defect formation, which provide the experimental basis for the adopted full-trap HBT model. Recent experimental characterizations have revealed that the β-Ga2O3/GaN heterointerface is far from ideal and strongly influences device performance. High-resolution TEM analyses provide clear evidence of non-abrupt junctions and interfacial defects. For example, Zhang et al.67 observed that β-Ga2O3 films grown on GaN substrates form a fuzzy transition layer of 3–4 atomic planes at the interface due to atomic reconfiguration, rather than a sharp boundary. Similarly, Seo et al.68 reported that grain boundaries and defect clusters originating from the Ga2O3/GaN junction propagate into the overgrown β-Ga2O3 layer, confirming the presence of interfacial defect networks. Structural characterizations further highlight the role of lattice mismatch and strain. XRD measurements indicate that GaN grown on β-Ga2O3 experiences a lattice mismatch of ∼4.7%, resulting in a threading dislocation density (TDD) of ∼4.0 × 107 cm−2.69 Complementary Raman spectroscopy analyses demonstrated a red-shift of the E2 (high) phonon mode relative to bulk GaN, corresponding to compressive strain of 0.26 GPa in planar GaN/β-Ga2O3 LEDs and 0.07 GPa in nanorod structures.31 These results confirm that both dislocations and residual strain are inevitable at the heterointerface. Chemical analyses also point to interfacial reactions and defect formation. Pre-annealing of GaN substrates prior to β-Ga2O3 growth has been shown to substitute N atoms with O atoms, producing a GaNxOy interfacial layer.67 This observation directly supports the formation of ON-related defects that compensate acceptors in the GaN base. In addition to ON-related compensation, the use of Mg-doped GaN substrates introduces a further risk associated with oxygen incorporation. Pankove et al.70 demonstrated that Mg and O co-doping leads to the formation of Mg–O complexes (‘molecular doping’), which effectively scavenge oxygen donors and render the material highly insulating. Such complexes would further reduce the effective hole concentration and thereby hinder hole injection at the Ga2O3/GaN interface. These characterizations consistently demonstrate that the β-Ga2O3/GaN heterointerface suffers from non-abrupt transitions, strain-induced dislocations, and oxygen-related defect formation.
image file: d5ra07197f-f1.tif
Fig. 1 Cross-sectional schematic of the Ga2O3/GaN HBT. Only half of the structure was used for simulation due to symmetry, but the full structure is illustrated here.

3 Results and discussion

3.1 Electrical characteristics

Fig. 2 presents the Gummel plots of the simulated Ga2O3/GaN B-HBT and F-HBT, showing the base current (IB) and collector current (IC) as functions of the base–emitter voltage (VBE) on a logarithmic scale, with the base–collector voltage (VBC) fixed at 0 V. A distinct onset of current amplification is observed when VBE exceeds 2.7 V, marking the turn-on of transistor operation. This relatively high turn-on voltage is consistent with the wide bandgap nature of the n-Ga2O3/p-GaN heterojunction and validates the band alignment in the simulation. When bulk traps in Ga2O3 as well as comprehensive interfacial effects at the Ga2O3/GaN junction are included, the Gummel characteristics exhibit noticeable changes compared with the bulk-trap-only case. In particular, IC decreases slightly while IB increases, due to enhanced recombination and carrier capture introduced by defect-related mechanisms at the heterojunction (e.g., interface states, atomic mixing, and non-ideal band profiles). Furthermore, oxygen diffusion from n-Ga2O3 emitter into the p-GaN base can generate compensating defects, lowering the effective hole concentration and injection efficiency. As a result, the DC current gain (βDC = IC/IB) of the F-HBT remains in the approximate range of 12–18. This trend is physically reasonable and consistent with experimental reports that interfacial degradation strongly limits the gain of GaN-based HBTs.71–73 The exponential dependence of IC and IB, the clear separation between collector and base currents, and the persistence of current amplification even in the presence of realistic defect modeling confirm that the proposed Ga2O3/GaN structure exhibits genuine heterojunction bipolar transistor behavior. Our simulations highlight both the intrinsic performance potential and the limitations imposed by non-ideal interfaces and traps, thereby validating the feasibility of the n-type β-Ga2O3 emitter/p-type GaN base/n-type GaN collector structure for future high-power HBT applications.
image file: d5ra07197f-f2.tif
Fig. 2 Room-temperature Gummel plots of the B-HBT and F-HBT with collector–base voltage VCB = 0 V.

The room-temperature common-emitter IV characteristics of the simulated Ga2O3/GaN B-HBT and F-HBT are presented in Fig. 3. The base current (IB) was swept from 5 μA to 25 μA in steps of 5 μA, while the collector–emitter voltage (VCE) was varied from 0 to 10 V for each IB. An offset voltage (VCE,offset) as low as 0.25 V was observed, which is substantially lower than that of typical AlGaN/GaN HBTs (2 V)73–75 and comparable to InGaN/GaN HBTs (0.3 V).76,77 The DC current gain (βDC) was extracted from the output curves in Fig. 3 and plotted as a function of IB in Fig. 4. With increasing IB, the collector current (IC) rises proportionally, indicating effective current modulation and forward-active transistor operation. Each output curve exhibits a steep increase in IC at low VCE, followed by a well-defined saturation region where IC remains nearly constant with further increases in VCE. This behavior reflects efficient carrier injection across the n-Ga2O3/p-GaN emitter–base junction and minimal base-width modulation (Early effect), highlighting excellent device stability and linearity—key requirements for high-frequency and high-power applications. Furthermore, as shown in Fig. 3, the collector current IC of the F-HBT is lower than that of the B-HBT, and the F-HBT also exhibits a slight upward shift in the knee voltage. In addition, the saturation region of the F-HBT becomes flatter, indicating a smaller Early effect. The degradation in the F-HBT is attributed to additional recombination pathways introduced at the Ga2O3/GaN boundary, together with parasitic resistances and oxygen-related compensation in the p-GaN base. These trends are consistent with the Gummel plots shown in Fig. 2, further confirming the physical validity of the defect-inclusive model. Despite the incorporation of all relevant traps, the collector current IC of the F-HBT still increases with VCE and then saturates, confirming effective current modulation and forward-active operation similar to that of the B-HBT.


image file: d5ra07197f-f3.tif
Fig. 3 Room-temperature common-emitter IV characteristics of the B-HBT and F-HBT for base currents varying from 5 μA to 25 μA in steps of 5 μA.

image file: d5ra07197f-f4.tif
Fig. 4 Room-temperature DC current gains of the B-HBT and F-HBT for various base currents.

The specific on-resistance (Ron,sp) of the B-HBT and F-HBT was determined to be 0.19 mΩ cm2 and 0.35 mΩ cm2, respectively, at VCE = 5 V with IB = 25 μA and IC = 815 μA for the B-HBT and IC = 450 μA for the F-HBT. These values were calculated based on a circular emitter region with a radius of 1.0 μm, corresponding to high collector current densities (JC) of 26 kA cm−2 and 14.3 kA cm−2, respectively. As shown in Fig. 4, the DC current gain of the B-HBT remains nearly constant or exhibits a slight decline as IB increases, reflecting an almost idealized response dominated by bulk traps. In contrast, the F-HBT demonstrates a slight increase in βDC with IB, which is consistent with our earlier experimental observations in InGaP/GaAs heterojunction phototransistors (HPTs).48–50 In those devices, βDC also increased with IB because recombination at the emitter perimeter and heterointerface became relatively less significant at higher injection levels, while the diffusion current dominated. A similar mechanism can be used to explain the behavior of the F-HBT: at low IB, interface and compensation defects dominate recombination, suppressing βDC, whereas at higher IB these defects are partially saturated, allowing the diffusion current to prevail, thereby improving injection efficiency and slightly enhancing βDC. Specifically, βDC in the B-HBT decreases modestly from 35.4 at IB = 5 μA to 33.4 at IB = 25 μA (5.7% reduction), whereas in the F-HBT it increases from 16.5 to 18.3 (11% enhancement) over the same bias range at VCE = 8.0 V. This difference clearly demonstrates that the full-trap model more realistically captures the bias-dependent behavior observed in practical heterojunction devices.

As shown in Fig. 4, the DC current gain (βDC) of the F-HBT remains in the range of 16–18 for base currents (IB) between 5 and 25 μA, which is more than twice lower than that of the B-HBT. The reduced βDC is associated with defect-assisted recombination at the Ga2O3/GaN boundary, originating from lattice mismatch, interdiffusion, and associated band-edge distortions. These defects act as strong recombination centers in the depletion region of the emitter–base junction, thereby increasing the base current and reducing the DC current gain. A similar mechanism was also observed in our previous studies on InGaP/GaAs HPTs, where defect generation at the heterointerface and at the emitter perimeter enhanced recombination and degraded both current gain and photoresponse. In the Ga2O3/GaN system, additional parasitic resistances at the heterointerface and compensating defects in the p-GaN base induced by oxygen diffusion further reduce the hole concentration and emitter injection efficiency. These findings are consistent with experimentally observed trends in GaN-based HBTs, providing a credible explanation for the performance limitations and highlighting that interface quality, defect passivation, and device design strategies are crucial to realize high-performance β-Ga2O3/GaN HBTs.

The collector current (IC) as a function of the reverse-biased collector–base voltage (VCB), with both the base and emitter grounded, was simulated to determine the breakdown voltage of the HBT, as shown in Fig. 5. VCB was swept from 0 V to 200 V to evaluate the collector–base breakdown behavior (BVCBO). For both the B-HBT and F-HBT, IC remains nearly zero until a sharp increase occurs at approximately 120 V, which is identified as the collector–base breakdown voltage (BVCBO) of the Ga2O3/GaN HBT structure. However, the collector current of the F-HBT is slightly suppressed beyond breakdown compared to that of the B-HBT, reflecting the additional influence of interface-related defects and compensation effects. The transistor's power figure of merit (PFOM) for the B-HBT and F-HBT, defined as BVCBO2/Ron,sp, was calculated to be 74.8 MW cm−2 and 41.3 MW cm−2, respectively. The high breakdown voltage, primarily governed by the intrinsic wide-bandgap nature of Ga2O3 and GaN together with the engineered heterojunction profile, demonstrates the robust reverse-blocking capability of the proposed HBT structure. Furthermore, the high PFOM confirms a favorable trade-off between breakdown performance and conduction loss, indicating strong potential for high-voltage power switching applications.


image file: d5ra07197f-f5.tif
Fig. 5 Simulated collector current as a function of the reverse-biased collector–base voltage (VCB) at room temperature, with both the base and emitter grounded. The sharp increase in IC at approximately 120 V indicates the collector–base breakdown voltage (BVCBO) of the Ga2O3/GaN HBT.

In addition to their application in high-voltage power switching, HBTs are also widely used in RF and high-speed switching circuits. Therefore, the high-frequency performance of the proposed Ga2O3/GaN HBT was evaluated by extracting the cutoff frequency (fT), defined as the frequency at which the short-circuit current gain drops to unity. As seen in Fig. 6, the AC current gain (βAC) remains nearly constant at 29.6 up to frequencies near 109 Hz and then decreases rapidly, with fT determined to be approximately 35 GHz for the B-HBT. By contrast, the F-HBT exhibits a lower low-frequency βAC (25.1) compared to the B-HBT (29.6), with the roll-off occurring at a lower frequency. The cutoff frequency fT of the F-HBT is reduced to approximately 30 GHz, which is 14.3% lower than that of the B-HBT. The reduction in fT for the F-HBT is attributed to carrier recombination and trapping at the heterojunction, which increase the effective base transit time and parasitic resistances, thereby degrading the high-frequency response. Despite this reduction, both the B-HBT and F-HBT maintain effective operation at high frequencies. The simulated fT values are consistent with the device's structural parameters, including a short base width of 50 nm, moderate emitter and collector doping levels, and optimized GaN/β-Ga2O3 heterojunction alignment. Although β-Ga2O3 has inherently low electron mobility, the relatively thin base region and the high carrier saturation velocity in GaN help reduce the carrier transit time, thereby enhancing fT. Moreover, the combination of GaN and β-Ga2O3, two materials with wide bandgaps and high breakdown fields, enables robust high-frequency operation without premature breakdown. Compared to other wide-bandgap devices, the proposed β-Ga2O3/GaN HBT exhibits competitive high-frequency performance.78,79 The B-HBT achieves an fT of 35 GHz, serving as an upper bound under bulk-trap-only conditions, while the F-HBT maintains an fT of 30 GHz, comparable to reported values for β-Ga2O3 MOSFETs (27 GHz)79 and significantly exceeding that of AlGaN/GaN HBTs (4.05 GHz).78 Our simulations show that even under realistic full-trap conditions, the β-Ga2O3/GaN HBT sustains frequency performance on par with or better than established wide-bandgap technologies, while simultaneously providing superior breakdown capability. Furthermore, to the best of our knowledge, this study presents the first demonstration of a functional HBT based on the Ga2O3/GaN material system, even though Ga2O3/GaN heterojunctions have been extensively investigated for unipolar and optoelectronic devices such as p–n diodes, HEMTs, MOSFETs, and LEDs, as summarized in Table 1. By employing a p-GaN base to circumvent the long-standing challenge of p-type doping in β-Ga2O3, our work not only opens a new avenue for the development of Ga2O3-based bipolar devices but also contributes a novel device architecture to the wide-bandgap semiconductor field.


image file: d5ra07197f-f6.tif
Fig. 6 Simulated AC current gain (βAC) of the B-HBT and F-HBT as a function of frequency. The cutoff frequency (fT) is defined as the frequency at which the current gain drops to unity.
Table 1 Comparison of the current work with previously reported Ga2O3/GaN devices
Device Key material layers Primary function Novelty Reference
p–n diode Ga2O3 (n-type), GaN (p-type) High-performance rectifiers and power diodes with high breakdown voltage, low switching loss, and scalability for high-frequency power electronics (i) β-Ga2O3/GaN Junction Barrier Schottky diode (JBSD) with high breakdown and fast switching; (ii) transfer-printed β-Ga2O3 nanomembranes for large-area devices; (iii) improved termination designs to maximize breakdown 44–47
HEMT Ga2O3 layers integrated with GaN (heterojunction or gate oxide) Fabrication of high-performance, normally-off, reliable HEMTs/MOSHEMTs for high-power and high-frequency applications Using β-Ga2O3 as a gate dielectric/stack to enhance 2DEG density, raise threshold voltage, suppress leakage, and improve thermal/noise performance 25 and 32–38
MOSFET β-Ga2O3 channel (grown by mist chemical vapor deposition (mist-CVD) on GaN substrates) and Ga2O3 gate dielectric (formed by photo-enhanced chemical (PEC) oxidation of GaN nanowires (NWs)) High-power, reliable, low-cost MOSFETs suitable for high-voltage power electronics (i) PEC oxidation for Ga2O3/GaN hybrid NW MOSFETs; (ii) mist-CVD instead of MOCVD/MBE for cost-effective, high-performance β-Ga2O3 MOSFETs; (iii) very high breakdown voltage without complex structures 39–43
Photodetector β-Ga2O3/GaN heterojunctions Dual-mode, deep-UV high-selectivity, and high-resolution narrow-band UV photodetection Bias-controlled dual-mode, dual-band high-responsivity, and ultranarrow spectral response 26–28
LED GaN/InGaN LEDs on β-Ga2O3 substrates or with embedded patterned/nanorod Ga2O3 structures High-efficiency GaN-based LEDs with improved light output, internal quantum efficiency, and photon extraction First green LED on β-Ga2O3; Ga2O3 patterning and nanorods enhance light output power (LOP), internal quantum efficiency (IQE), and light extraction efficiency (LEE), while reducing strain and quantum-confined Stark effect (QCSE) 29–31
This work n-β-Ga2O3 emitter/p-GaN base/n-GaN collector A high-gain, high-frequency, high-breakdown transistor for next-generation power electronics and RF switching First demonstration of a functional Ga2O3/GaN HBT via simulation, overcoming the lack of p-type β-Ga2O3, with realistic trap/interface modeling and structural optimization  


3.2 Temperature-dependent electrical characteristics of Ga2O3/GaN HBTs

For power electronics applications, particularly in power switching environments, the β-Ga2O3/GaN HBT must be capable of operating at elevated temperatures. As previously discussed, the combination of an ultra-wide bandgap β-Ga2O3 emitter with a high-performance p-GaN base and n-GaN collector provides a promising material platform, enabling the proposed β-Ga2O3/GaN HBT to achieve high performance. At room temperature, the B-HBT delivered a high collector current density (JC) of 26 kA cm−2 at a base current of 25 μA, corresponding to a power figure of merit (PFOM) of 74.8 MW cm−2 and a low specific on-resistance (Ron,sp) of 0.19 mΩ cm2. In comparison, the F-HBT exhibited a JC of 14.3 kA cm−2, yielding a PFOM of 41.3 MW cm−2 and a Ron,sp of 0.35 mΩ cm2. These results demonstrate strong competitiveness compared to conventional GaN-based HBTs.76–78 However, to assess the practical applicability of the device, it is essential to investigate the temperature dependence of key parameters such as collector current, current gain, specific on-resistance, and PFOM, in addition to performance under ideal conditions.

The temperature-dependent performance of the Ga2O3/GaN HBT was systematically investigated over the range of 300 K to 460 K, as shown in Fig. 7–11. Fig. 7 compares the common-emitter IV characteristics of the Ga2O3/GaN HBT at 300 K and 460 K with a base current step of 5 μA. A noticeable degradation in collector current is observed at 460 K compared to 300 K, especially at higher base current levels, indicating deteriorated carrier transport at elevated temperatures. However, at both temperatures, the IV characteristics exhibit a distinct forward-active behavior, with a sharp increase in collector current (IC) at low VCE followed by well-defined saturation regions. In addition, an increased offset voltage and reduced flatness in the saturation region at 460 K indicate mild base-width modulation and enhanced thermal effects. The B-HBT delivers higher IC at both temperatures, whereas the F-HBT exhibits lower absolute IC and poorer high-temperature performance, reflecting the impact of heterojunction-related non-idealities and compensation effects in the p-GaN base. Consequently, both devices exhibit reduced DC current gain (βDC) with temperature: the B-HBT decreases from 33.4 at 300 K to 23.1 at 460 K (31% reduction), while the F-HBT falls from 18.3 to 12.6 (31% reduction). Although the fractional degradation with temperature is similar, the F-HBT consistently operates with substantially lower absolute gain across the examined range, emphasizing the critical role of interface quality and defect control for reliable high-temperature Ga2O3/GaN HBT operation. The degradation in βDC with increasing temperature is primarily attributed to enhanced carrier recombination in the base region and reduced carrier mobility at elevated temperatures, which together lower the emitter-to-base injection efficiency. In addition, higher temperatures facilitate hole back-injection across the emitter–base junction, further reducing injection efficiency. Moreover, the minority carrier lifetime decreases with temperature due to thermally activated deep-level traps and enhanced non-radiative recombination in both p-GaN and n-β-Ga2O3. The shortened lifetime accelerates recombination, decreases the base transport factor, and thereby further degrades the overall current gain. Compared with the B-HBT, the F-HBT suffers from stronger degradation because junction imperfections act as recombination centers and increase parasitic resistance, while compensating defects in the p-GaN base lower the effective hole concentration and weaken emitter injection efficiency.


image file: d5ra07197f-f7.tif
Fig. 7 Common-emitter IV characteristics of β-Ga2O3/GaN HBTs at 300 K and 460 K with a base-current step of 5 μA: (a) B-HBT (bulk-trap-only model) and (b) F-HBT (full-trap model).

image file: d5ra07197f-f8.tif
Fig. 8 Temperature dependence of the DC current gain (βDC) of the B-HBT and F-HBT at a fixed base current of 25 μA.

Simultaneously, Fig. 9 and 10 show a consistent thermal response in both devices: as the temperature increases from 300 to 460 K, the specific on-resistance (Ron,sp) rises monotonically, accompanied by a decline in the power figure of merit (PFOM). For the B-HBT, Ron,sp increases from 0.19 to 0.29 mΩ cm2 while PFOM drops from 74.8 to 49.2 MW cm−2. Likewise, the F-HBT shows a rise in Ron,sp from 0.35 to 0.50 mΩ cm2 and a reduction in PFOM from 41.3 to 28.9 MW cm−2. This degradation is attributed to thermally reduced electron mobility in the β-Ga2O3 emitter and drift regions. Importantly, the collector–base breakdown voltage (BVCBO) remains nearly constant at 120 V, confirming that the PFOM loss originates mainly from resistance increases rather than breakdown changes. Elevated resistance in the collector region also produces a larger voltage drop under fixed bias (VC), thereby reducing the effective junction voltage and lowering the collector current (IC). The combined effect of higher Ron,sp and suppressed IC results in substantial PFOM degradation. This trend is corroborated by the output characteristics in Fig. 7, which show significantly higher IC at 300 K compared to 460 K for the same collector–emitter voltage (VCE). The consistency between the IV characteristics and PFOM decline highlights the thermal sensitivity of the device performance. This analysis demonstrates that although the proposed HBT structure maintains stable operation at elevated temperatures, both current gain and power efficiency are subject to significant thermal degradation, which must be carefully addressed in the design of high-temperature power and RF devices.


image file: d5ra07197f-f9.tif
Fig. 9 Temperature dependence of the specific on-resistance (Ron,sp) of the B-HBT and F-HBT at a fixed base current of 25 μA.

image file: d5ra07197f-f10.tif
Fig. 10 Temperature dependence of the power figure of merit (PFOM) of the B-HBT and F-HBT at a fixed base current of 25 μA.

Heterojunction bipolar transistors (HBTs) are commonly used in practical RF and power switching applications, where they often operate under elevated thermal conditions. Therefore, evaluating the temperature dependence of the cutoff frequency (fT) is essential for understanding the high-frequency reliability and performance limits of the proposed Ga2O3/GaN HBT. As seen in Fig. 11, fT decreases monotonically with temperature for both device variants. For the B-HBT, fT falls from 35 to 18 GHz as T increases from 300 to 460 K, whereas the F-HBT decreases from 30 to 17 GHz. The full-trap device consistently exhibits lower fT due to reduced transconductance and higher parasitic resistance/capacitance from interfacial defects; however, the gap between the two devices narrows at elevated temperatures where phonon-limited mobility dominates. This degradation is primarily driven by enhanced phonon scattering in the β-Ga2O3 emitter and GaN collector, which reduces carrier mobility, increases base transit time, and elevates diffusion capacitance and base resistance. Despite this, the proposed HBT maintains a competitive fT across the investigated range. The wide bandgap of n-β-Ga2O3 ensures a high breakdown voltage, while the p-GaN base provides thermal stability along with efficient minority-carrier injection and fast switching. These combined attributes highlight the promise of β-Ga2O3/GaN HBTs for high-temperature, high-frequency power and RF applications.


image file: d5ra07197f-f11.tif
Fig. 11 Temperature dependence of the cutoff frequency (fT) of the B-HBT and F-HBT.

3.3 Effect of base and collector thickness on the electrical performance of Ga2O3/GaN HBTs

The performance of heterojunction bipolar transistors (HBTs) can be enhanced by optimizing the base and collector thicknesses, specifically by balancing the trade-offs between current gain, breakdown voltage, and conduction loss. To clarify these effects, the electrical performance of the proposed β-Ga2O3/GaN HBT was evaluated as a function of base and collector thickness. First, all device parameters were kept constant while the base thickness (tB) was varied from 0.05 μm to 0.15 μm. For each tB, key parameters such as current gain, breakdown voltage, specific on-resistance (Ron,sp), and power figure of merit (PFOM) were extracted and analyzed.

Fig. 12(a) presents the dependence of DC current gain (βDC) and power figure of merit (PFOM) on base thickness (tB). As tB increases from 0.05 μm to 0.15 μm, βDC for both the B-HBT and F-HBT decreases significantly due to enhanced carrier recombination and prolonged transit time through the thicker base region. In contrast, PFOM generally increases with tB, primarily driven by the substantial enhancement in breakdown voltage, which outweighs the concurrent increase in specific on-resistance (Ron,sp), as shown in Fig. 12(b). Across the entire thickness range, the F-HBT exhibits lower βDC and PFOM than the B-HBT, consistent with additional interfacial traps and parasitic resistances at the β-Ga2O3/GaN junction that hinder carrier transport. As seen in Fig. 12(b), the breakdown voltage of both devices increases markedly with tB, since a thicker base broadens the depletion region, thereby improving electric field distribution and enhancing voltage blocking capability. Meanwhile, Ron,sp exhibits a noticeable increase with tB due to the longer transport path and higher series resistance in the base/collector stack. Adjusting the base thickness proves to be an effective strategy for balancing switching efficiency and voltage robustness in Ga2O3/GaN HBTs. The base thickness (tB) critically influences the overall device performance. A thinner base significantly enhances the DC current gain (βDC) by reducing carrier transit time and minimizing recombination within the base region, which are essential factors for high-gain amplification and RF operation. However, a thin base limits the breakdown voltage and PFOM due to a narrower depletion region and weaker electric field control. In contrast, increasing the base thickness substantially improves breakdown voltage and PFOM, although it leads to a degradation in βDC. Therefore, an optimized base thickness offers a favorable trade-off. It provides sufficient current gain for efficient switching while maintaining high power performance and voltage robustness, which are critical for the practical implementation of Ga2O3/GaN HBTs in high-voltage and high-frequency power applications.


image file: d5ra07197f-f12.tif
Fig. 12 Dependence of (a) DC current gain (βDC) and power figure of merit (PFOM), and (b) collector–base breakdown voltage (BVCBO) and specific on-resistance (Ron,sp) on base thickness (tB) for the B-HBT and F-HBT, evaluated at IB = 25 μA and VCE = 5 V.

Next, the effect of collector thickness (tC) on device performance was investigated by varying tC from 0.5 μm to 2.0 μm while keeping all other HBT parameters constant. The dependence of key performance metrics on collector thickness was systematically analyzed, and the corresponding simulation results are presented in Fig. 13. As illustrated in Fig. 13(a), the DC current gain (βDC) of both B-HBT and F-HBT remains nearly constant, at approximately 32 for the B-HBT and 18 for the F-HBT, across the entire range of collector thickness (tC). This suggests that increasing the collector thickness does not significantly influence carrier injection efficiency or recombination within the base, as βDC is primarily determined by the emitter–base junction characteristics. In contrast, the power figure of merit (PFOM) exhibits a substantial enhancement, rising from 62.9 MW cm−2 at tC = 0.5 μm to over 248 MW cm−2 at tC = 2.0 μm for the B-HBT, and from 34.7 MW cm−2 to over 138 MW cm−2 for the F-HBT over the same thickness range. This improvement is mainly due to the increase in breakdown voltage (BVCBO) with thicker collector layers, as shown in Fig. 13(b). A thicker collector enables a wider depletion region and a more uniform electric field distribution, thereby enabling significantly higher breakdown voltage. Specifically, BVCBO increases from approximately 110 V to 220 V for both devices as tC increases. Notably, the specific on-resistance (Ron,sp) shows only minor variation across the same thickness range, indicating that enhanced thickness does not introduce significant resistance penalties. Although both devices benefit from collector thickening, the F-HBT consistently exhibits a lower DC current gain, which can be attributed to defect-related recombination at the Ga2O3/GaN junction arising from interfacial imperfections and structural mismatches. Consequently, the F-HBT also demonstrates a lower PFOM across the entire range, since such interfacial defects raise parasitic resistances. These results demonstrate that optimizing the collector thickness is an effective strategy for enhancing the breakdown strength and power efficiency of Ga2O3/GaN HBTs, without compromising DC current gain or Ron,sp. Furthermore, this approach offers a promising solution for improving the trade-off between high-voltage capability and conduction loss in high-power switching applications.


image file: d5ra07197f-f13.tif
Fig. 13 Dependence of (a) DC current gain (βDC) and power figure of merit (PFOM), and (b) collector–base breakdown voltage (BVCBO) and specific on-resistance (Ron,sp) on collector thickness (tC) for the B-HBT and F-HBT, evaluated at IB = 25 μA and VCE = 5 V.

Our simulations show that both base thickness (tB) and collector thickness (tC) play pivotal roles in determining the overall performance of Ga2O3/GaN HBTs, although their effects manifest in distinct ways. A thinner base is favorable for applications requiring high gain and fast response, but it compromises breakdown voltage and PFOM. In contrast, increasing the collector thickness exhibits a dominant and beneficial impact on key performance metrics; a thicker collector enhances both breakdown voltage and PFOM without causing significant degradation in βDC or Ron,sp. This finding is scientifically significant because it reveals a practical and fabrication-compatible approach to improve voltage endurance and switching efficiency without sacrificing current gain. This trade-off between current gain and breakdown performance has long been a challenge in HBT design. Therefore, a structural configuration with a thin base and a moderately thick collector is recommended to achieve optimized performance. This combination supports a favorable balance among DC current gain, power efficiency, and voltage robustness, making it particularly suitable for high-voltage, high-frequency power switching, compact power ICs, and RF front-end modules.

Table 2 provides a comparative overview of the key performance metrics of the proposed Ga2O3/GaN HBT in relation to previously reported wide-bandgap devices. As shown in Table 2, experimental AlGaN/GaN HBTs78 exhibit very high current gain (up to 129) but suffer from limited cutoff frequencies (<5 GHz), whereas InGaN/GaN HBTs77,81 deliver moderate current gain but relatively low breakdown voltages (∼95–105 V). Simulation results of Cu2O/β-Ga2O3 HBTs23 indicate the potential for high breakdown voltages (>3 kV); however, the narrow bandgap of the p-type base material fundamentally limits their performance. In contrast, the simulated Ga2O3/GaN HBT proposed in this work achieves a well-balanced trade-off among current gain, breakdown voltage, PFOM, and frequency response, thereby positioning it as a promising candidate for next-generation power and RF electronic applications. By comparing the characteristics of the B-HBT and F-HBT, it becomes evident that the Ga2O3/GaN heterointerface is the primary bottleneck for achieving high-performance HBTs. Our simulations further reveal that only a low density of interface trap (Dit ≈ 1.0 × 1012 eV−1 cm−2) is compatible with transistor operation, whereas the higher trap densities reported experimentally (2.3–5.3 × 1013 eV−1 cm−2) would completely suppress device functionality. The feasibility of Ga2O3/GaN HBTs therefore hinges on improving interface quality through optimized growth processes, suppression of oxygen diffusion, and advanced strain engineering. It is concluded that stringent interface control is essential as the critical pathway to translate the promising theoretical performance of Ga2O3/GaN HBTs into practical applications.

Table 2 Comparison of the proposed Ga2O3/GaN HBT with previously reported wide-bandgap devices
Device structure DC current gain (βDC) Breakdown voltage (V) Ron,sp (mΩ cm2) PFOM (MW cm−2) fT (GHz) Year Reference
Ga2O3/GaN HBT (B-HBT) 34.9 120 0.19 74.8 35 2025 This work
Ga2O3/GaN HBT (F-HBT) 18.3 120 0.35 41.3 30 2025 This work
Cu2O/β-Ga2O3 HBT >50 3540–280 34.0 2023 23
AlGaN/GaN HBT 129 160 0.28 91.0 4.05 2022 78
AlGaN/GaN HBT 25 2022 72
AlGaN/GaN HBT 2 2016 80
InGaN/GaN HBT 24 105 0.14 ∼78.7 2013 81
GaN/InGaN HBT >24 >95 > 5 2011 77
AlGaN/GaN HBT 18 >330 2003 73
GaN/AlGaN HBT 10 2000 71
β-Ga2O3 MESFET 150 27 2019 79


4 Conclusions

In this work, a β-Ga2O3/GaN heterojunction bipolar transistor (HBT) featuring an n-type β-Ga2O3 emitter, a p-type GaN base, and an n-type GaN collector was designed and simulated to overcome the limitations of β-Ga2O3 bipolar devices caused by the absence of reliable p-type doping. Our simulation results confirm, for the first time, that the β-Ga2O3/GaN structure can effectively function as a heterojunction bipolar transistor. The proposed device with full consideration of traps achieves a high DC current gain of 18.3 and an ultra-low specific on-resistance (Ron,sp) of 0.35 mΩ cm2, resulting from efficient carrier injection across the n-β-Ga2O3/p-GaN heterojunction and optimized layer thicknesses. The collector–base breakdown voltage (BVCBO) reaches 120 V, yielding a power figure of merit (PFOM) of 41.3 MW cm−2. A cutoff frequency (fT) of 30 GHz demonstrates competitive high-frequency performance. Moreover, the device retains stable operation at elevated temperatures up to 460 K, despite predictable degradation in DC current gain and PFOM, primarily due to reduced carrier mobility and increased recombination. Structural optimization further shows that a thin base preserves high gain, while a thicker collector improves PFOM by enhancing breakdown voltage without degrading Ron,sp or βDC. These findings highlight the strong potential of the Ga2O3/GaN HBT for high-voltage and high-frequency applications, positioning it as a promising candidate to bridge the performance gap between ultra-wide-bandgap oxides and III-nitride semiconductors.

Author contributions

Phuc Hong Than: conceptualization, formal analysis, investigation, methodology, resources, validation, writing – original draft, writing – review & editing; Tho Quang Than: conceptualization, data curation, formal analysis, investigation, methodology, writing – review & editing; and Yasushi Takaki: conceptualization, investigation, formal analysis, resources, writing – review & editing.

Conflicts of interest

The authors declare no conflict of interest.

Data availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgements

The authors sincerely thank Prof. Cong-Kha Pham from the University of Electro-Communications (UEC), Tokyo, Japan, for his valuable technical advice and support.

References

  1. S. J. Pearton, J. Yang, P. H. Cary, F. Ren, J. Kim, M. J. Tadjer and M. A. Mastro, A review of Ga2O3 materials, processing, and devices, Appl. Phys. Rev., 2018, 5(1), 011301 Search PubMed.
  2. C. Wang, J. Zhang, S. Xu, C. Zhang, Q. Feng, Y. Zhang, J. Ning, S. Zhao, H. Zhou and Y. Hao, Progress in state-of-the-art technologies of Ga2O3 devices, J. Phys. D Appl. Phys., 2021, 54(24), 243001 CrossRef CAS.
  3. J. Zhang, J. Shi, D.-C. Qi, L. Chen and K. H. L. Zhang, Recent progress on the electronic structure, defect, and doping properties of Ga2O3, APL Mater., 2020, 8(2), 020906 CrossRef CAS.
  4. J. Montes, C. Kopas, H. Chen, X. Huang, T. H. Yang, K. Fu, C. Yang, J. Zhou, X. Qi, H. Fu and Y. Zhao, Deep level transient spectroscopy investigation of ultra-wide bandgap (−201) and (001) β-Ga2O3, J. Appl. Phys., 2020, 128(20), 205701 CrossRef CAS.
  5. M. Bosi, P. Mazzolini, L. Seravalli and R. Fornari, Ga2O3 polymorphs: Tailoring the epitaxial growth conditions, J. Mater. Chem. C, 2020, 8(32), 10975–10992 RSC.
  6. H. Aida, K. Nishiguchi, H. Takeda, N. Aota, K. Sunakawa and Y. Yaguchi, Growth of β-Ga2O3 Single Crystals by the Edge-Defined, Film Fed Growth Method, Jpn. J. Appl. Phys., 2008, 47, 8506 CrossRef CAS.
  7. R. Singh, T. R. Lenka, D. K. Panda, R. T. Velpula, B. Jain, H. Q. T. Bui and H. P. T. Nguyen, The dawn of Ga2O3 HEMTs for high power electronics - A review, Mater. Sci. Semicond. Process., 2020, 119, 105216 CrossRef CAS.
  8. H. Zhou, J. Zhang, C. Zhang, Q. Feng, S. Zhao, P. Ma and Y. Hao, A review of the most recent progresses of state-of-art gallium oxide power devices, J. Semicond., 2019, 40(1), 011803 CrossRef CAS.
  9. M. Higashiwaki, K. Sasaki, A. Kuramata, T. Masui and S. Yamakoshi, Development of gallium oxide power devices, Phys. Status Solidi A, 2014, 211(1), 21–26 CrossRef CAS.
  10. M. H. Wong and M. Higashiwaki, Vertical β-Ga2O3 power transistors: A review, IEEE Trans. Electron Devices, 2020, 67(10), 3925–3937 CAS.
  11. K. Konishi, K. Goto, H. Murakami, Y. Kumagai, A. Kuramata, S. Yamakoshi and M. Higashiwaki, 1-kV vertical Ga2O3 field-plated Schottky barrier diodes, Appl. Phys. Lett., 2017, 110(10), 103506 CrossRef.
  12. H. Fu, H. Chen, X. Huang, I. Baranowski, J. Montes, T. H. Yang and Y. Zhao, A comparative study on the electrical properties of vertical (−201) and (010) β-Ga2O3 Schottky barrier diodes on EFG single-crystal substrates, IEEE Trans. Electron Devices, 2018, 65(8), 3507–3513 CAS.
  13. M. Higashiwaki, K. Sasaki, T. Kamimura, M. H. Wong, D. Krishnamurthy, A. Kuramata, T. Masui and S. Yamakoshi, Depletion-mode Ga2O3 metal-oxide-semiconductor field-effect transistors on β-Ga2O3 (010) substrates and temperature dependence of their device characteristics, Appl. Phys. Lett., 2013, 103, 123511 CrossRef.
  14. M. H. Wong, K. Sasaki, A. Kuramata, S. Yamakoshi and M. Higashiwaki, Field-Plated Ga2O3 MOSFETs With a Breakdown Voltage of Over 750 V, IEEE Electron Device Lett., 2016, 37(2), 212–215 CAS.
  15. A. J. Green, K. D. Chabak, E. R. Heller, R. C. Fitch, M. Baldini, A. Fiedler, K. Irmscher, G. Wagner, Z. Galazka, S. E. Teltak, A. Crespo, K. Leedy and G. H. Jessen, 3.8-MV/cm Breakdown Strength of MOVPE-Grown Sn-Doped β-Ga2O3 MOSFETs, IEEE Electron Device Lett., 2016, 37(7), 902–905 Search PubMed.
  16. S. Krishnamoorthy, Z. Xia, S. Bajaj, M. Brenner and S. Rajan, Delta-doped β-gallium oxide field-effect transistor, Appl. Phys. Express, 2017, 10, 051102 Search PubMed.
  17. E. Ahmadi, O. S. Koksaldi, X. Zheng, T. Mates, Y. Oshima, U. K. Mishra and J. S. Speck, Demonstration of β-(AlxGa1−x)2O3/β-Ga2O3 modulation doped field-effect transistors with Ge as dopant grown via plasma-assisted molecular beam epitaxy, Appl. Phys. Express, 2017, 10, 071101 CrossRef.
  18. N. Moser, J. McCandless, A. Crespo, K. Leedy, A. Green, A. Neal, S. Mou, E. Ahmadi, J. Speck, K. Chabak, N. Peixoto and G. Jessen, Ge-Doped β-Ga2O3 MOSFETs, IEEE Electron Device Lett., 2017, 38(6), 775–778 CAS.
  19. M. Higashiwaki, K. Sasaki, A. Kuramata, T. Masui and S. Yamakoshi, Gallium oxide (Ga2O3) metal-semiconductor field-effect transistors on single-crystal β-Ga2O3 (010) substrates, Appl. Phys. Lett., 2012, 100, 013504 CrossRef.
  20. K. Wang, Z. Wang, R. Cao, H. Liu, W. Chang, L. Zhao, B. Mei, H. Lv, X. Zeng and Y. Xue, Study of the mechanism of single event burnout in lateral depletion-mode Ga2O3 MOSFET devices via TCAD simulation, J. Appl. Phys., 2024, 135, 145702 CrossRef CAS.
  21. T. Kamimura, Y. Nakata, M. H. Wong, P. H. Than and M. Higashiwaki, Nitrogen-Doped Channel β-Ga2O3 MOSFET with Normally-Off Operation, in Proceedings of 2019 Compound Semiconductor Week (CSW), Nara, Japan, 2019,  DOI:10.1109/ICIPRM.2019.8818991.
  22. Y. Nakata, T. Kamimura, M. H. Wong, P. H. Than, and M. Higashiwaki, Unintentional incorporation of Si and N atoms in Ga2O3 films grown by plasma-assisted molecular beam epitaxy, Presented at: 61st Electronic Materials Conference (EMC 2019), Ann Arbor, MI, USA, 2019 Search PubMed.
  23. M. Mehta and S. Avasthi, The possibility of gallium oxide (β-Ga2O3) heterojunction bipolar transistors, Phys. Scr., 2023, 98, 025013 CrossRef CAS.
  24. E. Hossain, A. A. Rahman, M. Gokhale, R. Kulkarni, R. Mondal, A. Thamizhavel and A. Bhattacharya, Growth of high-quality GaN on (1 0 0) Ga2O3 substrates by facet-controlled MOVPE, J. Cryst. Growth, 2019, 524, 125165 CrossRef CAS.
  25. S. Leone, R. Fornari, M. Bosi, V. Montedoro, L. Kirste, P. Doering, F. Benkhelifa, M. Prescher, C. Manz, V. Polyakov and O. Ambacher, Epitaxial growth of GaN/Ga2O3 and Ga2O3/GaN heterostructures for novel high electron mobility transistors, J. Cryst. Growth, 2020, 534, 125511 CrossRef CAS.
  26. W. Y. Weng, T. J. Hsueh, S. J. Chang, G. J. Huang and H. T. Hsueh, A β-Ga2O3/GaN Schottky-barrier photodetector, IEEE Photon. Technol. Lett., 2011, 23, 444–446 CAS.
  27. S. Nakagomi, T. Sato, Y. Takahashi and Y. Kokubun, Deep ultraviolet photodiodes based on the β- Ga2O3/GaN heterojunction, Sens. Actuators, A, 2015, 232, 208–213 CrossRef CAS.
  28. R. Tang, G. Li, Y. Jiang, N. Gao, J. Li, C. Li, K. Huang, J. Kang, T. Wang and R. Zhang, Ga2O3/GaN heterostructural ultraviolet photodetectors with exciton-dominated ultranarrow response, ACS Appl. Electron. Mater., 2021, 4, 188–196 CrossRef.
  29. Z. L. Xie, R. Zhang, C. T. Xia, X.-Q. Xiu, P. Han, B. Liu, H. Zhao, R.-L. Jiang, Y. Shi and Y.-D. Zheng, Demonstration of GaN/InGaN light emitting diodes on (100) β-Ga2O3 substrates by metalorganic chemical vapour deposition, Chin. Phys. Lett., 2008, 25, 2185 CrossRef CAS.
  30. C.-F. Lin, K.-T. Chen and K.-P. Huang, Blue light-emitting diodes with an embedded native gallium oxide pattern structure, IEEE Electron Device Lett., 2010, 31, 1431–1433 CAS.
  31. J. Zhao, W. Li, L. Wang, X. Wei, J. Wang and T. Wei, The optical properties of InGaN/GaN nanorods fabricated on (-201) β-Ga2O3 substrate for vertical light emitting diodes, Photonics, 2021, 8, 42 CrossRef CAS.
  32. H.-Y. Lee, T.-W. Chang, E. Y. Chang, N. Rorsman and C.-T. Lee, Fabrication and characterization of GaN-based fin-channel array metal-oxide-semiconductor high-electron mobility transistors with recessed-gate and Ga2O3 gate insulator layer, IEEE J. Electron Devices Soc., 2021, 9, 393–399 CAS.
  33. M. Ge, Y. Li, Y. Zhu, D. Chen, Z. Wang and S. Tan, An improved design for e-mode AlGaN/GaN HEMT with gate stack β-Ga2O3/p-GaN structure, J. Appl. Phys., 2021, 130, 035703 CrossRef CAS.
  34. H.-Y. Lee, D.-S. Liu, J.-I. Chyi, E. Y. Chang and C.-T. Lee, Lattice-matched AlInN/GaN/AlGaN/GaN heterostructured-double-channel metal-oxide-semiconductor high-electron mobility transistors with multiple-mesa-fin-channel array, Materials, 2021, 14, 5474 CrossRef CAS PubMed.
  35. J.-J. Jia, C.-C. Lin and C.-T. Lee, Scaling effect in gate-recessed AlGaN/GaN finnanochannel array MOSHEMTs, IEEE Access, 2020, 8, 158941–158946 Search PubMed.
  36. M. Ge, Y. Li, Y. Zhu, D. Chen, Z. Wang and S. Tan, Effects of gate work function on E-mode AlGaN/GaN HEMTs with stack gate β-Ga2O3/p-GaN structure, J. Phys. D Appl. Phys., 2021, 54, 355103 CrossRef CAS.
  37. J. T. Asubar, Y. Kobayashi, K. Yoshitsugu, Z. Yatabe, H. Tokuda, M. Horita, Y. Uraoka, T. Hashizume and M. Kuzuhara, Current collapse reduction in AlGaN/GaN HEMTs by high-pressure water vapor annealing, IEEE Trans. Electron. Dev., 2015, 62, 2423–2428 CAS.
  38. H. Y. Kang, M. J. Yeom, J. Y. Yang, Y. Choi, J. Lee, C. Park, G. Yoo and R. B. K. Chung, Epitaxial κ-Ga2O3/GaN heterostructure for high electron-mobility transistors, Mater. Today Phys., 2023, 31, 101002 CrossRef CAS.
  39. J.-W. Yu, Y.-R. Wu, J.-J. Huang, and L.-H. Peng, 75 GHz Ga2O3/GaN single nanowire metal-oxide-semiconductor field-effect transistors, in 2010 IEEE Compound Semiconductor Integrated Circuit Symposium (CSICS), Monterey, California, USA, 2010, pp. 1–4 Search PubMed.
  40. J.-W. Yu, Y.-R. Wu and L.-H. Peng, “Scaling of GaN single nanowire MOSFET with cutoff frequency 150 GHz, in Gallium Nitride Materials and Devices VII, San Francisco, California, United States, 2012, pp. 82620 Search PubMed.
  41. Y. Xu, C. Zhang, P. Yan, Z. Li, Z. Feng, Y. Zhang, D. Chen, W. Zhu, Q. Feng, S. Xu, J. Zhang and Y. Hao, Depletion-mode β-Ga2O3 MOSFETs grown by nonvacuum, cost-effective mist-CVD method on Fe-doped GaN substrates, IEEE Trans. Electron. Dev., 2022, 69, 1196–1199 CAS.
  42. S. Hasan, M. U. Jewel, S. R. Crittenden, D. Lee, V. Avrutin, Ü. Özgür, H. Morkoç and I. Ahmad, MOCVD-grown β-Ga2O3 as a Gate Dielectric on AlGaN/GaN-Based Heterojunction Field Effect Transistor, Crystals, 2023, 13(2), 231 CrossRef CAS.
  43. M. U. Jewel, S. Hasan, S. R. Crittenden, V. Avrutin, Ü. Özgür, H. Morkoç and I. Ahma, Phase stabilized MOCVD growth of β-Ga2O3 using SiOx on c-plane sapphire and AlN/sapphire template, Phys. Status Solidi A, 2023, 220, 2300036 CrossRef CAS.
  44. A. Nandi, K. S. Rana and A. Bag, Design and analysis of P-GaN/N-Ga2O3 based junction barrier Schottky diodes, IEEE Trans. Electron. Dev., 2021, 68, 6052–6058 CAS.
  45. D. H. Mudiyanselage, D. Wang and H. Fu, Wide bandgap vertical kV-class β-Ga2O3/GaN heterojunction p–n power diodes with mesa edge termination, IEEE J. Electron Devices Soc., 2022, 10, 89–97 CAS.
  46. J. Montes, C. Yang, H. Fu, T.-H. Yang, K. Fu, H. Chen, J. Zhou, X. Huang and Y. Zhao, Demonstration of mechanically exfoliated β-Ga2O3/GaN p–n heterojunction, Appl. Phys. Lett., 2019, 114, 162103 CrossRef.
  47. Y. Liu, L. Wang, Y. Zhang, X. Dong, X. Sun, Z. Hao, Y. Luo, C. Sun, Y. Han, B. Xiong, J. Wang and H. Li, Demonstration of n-Ga2O3/p-GaN diodes by wet etching lift-off and transfer-print technique, IEEE Electron Device Lett., 2021, 42, 509–512 CAS.
  48. P. H. Than, K. Uchida and S. Nozaki, Effects of electrical stress on the InGaP/GaAs heterojunction phototransistor, IEEE Trans. Device Mater. Reliab., 2015, 15(4), 604–609 CAS.
  49. P. H. Than, K. Uchida, T. Makino, T. Ohshima and S. Nozaki, InGaP/GaAs heterojunction photosensor powered by an on-chip GaAs solar cell for energy harvesting, Jpn. J. Appl. Phys., 2016, 55, 04ES09 CrossRef.
  50. P. H. Than, K. Uchida, T. Makino, T. Ohshima and S. Nozaki, Effects of Electrical Stress and High-Energy Electron Irradiation on the InGaP/GaAs Heterojunction Phototransistor, MRS Online Proc. Libr., 2015, 1792, 479,  DOI:10.1557/opl.2015.403.
  51. P. H. Than, T. Q. Than and Y. Takaki, Vertical p-GaN/n-Ga2O3 heterojunction diode with high switching performance, Mater. Adv., 2025, 6, 3139–3148 RSC.
  52. P. H. Than, T. Q. Than and Y. Takaki, Breakdown voltage enhancement in p-GaAs/n-Ga2O3 heterojunction diodes with advanced termination designs, Phys. Scr., 2025, 100, 075022 CrossRef CAS.
  53. A. Y. Polyakov, N. B. Smirnov, I. V. Shchemerov, E. B. Yakimov, J. Yang, F. Ren, G. Yang, J. Kim, A. Kuramata and S. J. Pearton, Point defect induced degradation of electrical properties of Ga2O3 by 10 MeV proton damage, Appl. Phys. Lett., 2018, 112, 032107 CrossRef.
  54. Z. Zhang, E. Farzana, A. R. Arehart and S. A. Ringel, Deep level defects throughout the bandgap of (010) β-Ga2O3 detected by optically and thermally stimulated defect spectroscopy, Appl. Phys. Lett., 2016, 108, 052105 CrossRef.
  55. Y. Nakano, Electrical Characterization of β-Ga2O3 Single Crystal Substrates, ECS J. Solid State Sci. Technol., 2017, 6, 615 CrossRef.
  56. M. E. Ingebrigtsen, J. B. Varley, A. Yu. Kuznetsov, B. G. Svensson, G. Alfieri, A. Mihaila, U. Badstübner and L. Vines, Iron and intrinsic deep level states in Ga2O3, Appl. Phys. Lett., 2018, 112, 042104 CrossRef.
  57. M. Labed, N. Sengouga, C. V. Prasad, M. Henini and Y. S. Rim, On the nature of majority and minority traps in β-Ga2O3: A review, Mater. Today Phys., 2023, 36, 101155 CrossRef CAS.
  58. E. Farzana, E. Ahmadi, J. S. Speck, A. R. Arehart and S. A. Ringel, Deep level defects in Ge-doped (010) β-Ga2O3 layers grown by plasma-assisted molecular beam epitaxy, J. Appl. Phys., 2018, 123, 161410 CrossRef.
  59. G. Pozina, S. Khromov, C. Hemmingsson, L. Hultman and B. Monemar, Effect of silicon and oxygen doping on donor bound excitons in bulk GaN, Phys. Rev. B:Condens. Matter Mater. Phys., 2011, 84, 165213 CrossRef.
  60. G. A. Slack, L. J. Schowalter, M. Donald and J. A. Freitas Jr., Some effects of oxygen impurities on AlN and GaN, J. Cryst. Growth, 2002, 246, 287–298 CrossRef CAS.
  61. A. F. Wright, Substitutional and interstitial oxygen in wurtzite GaN, J. Appl. Phys., 2005, 98, 103531 CrossRef.
  62. C. H. Park and D. J. Chadi, Stability of deep donor and acceptor centers in GaN, AlN, and BN, Phys. Rev. B:Condens. Matter Mater. Phys., 1997, 55, 12995 Search PubMed.
  63. B. Monemar, P. P. Paskov, F. Tuomisto, K. Saarinen, M. Iwaya, S. Kamiyama, H. Amano, I. Akasaki and S. Kimura, Oxygen related shallow acceptor in GaN, MRS Online Proc. Libr., 2004, 831, 522–527 Search PubMed.
  64. B. Monemar, P. P. Paskov, F. Tuomisto, K. Saarinen, M. Iwaya, S. Kamiyama, H. Amano, I. Akasaki and S. Kimura, Dominant shallow acceptor enhanced by oxygen doping in GaN, Phys. Rev. B:Condens. Matter Mater. Phys., 2006, 376–377, 440–443 CrossRef CAS.
  65. Q. Feng, G. Yan, Z. Hu, Z. Feng, X. Tian, D. Jiao, W. Mu, Z. Jia, X. Lian, Z. Lai, C. Zhang, H. Zhou, J. Zhang and Y. Hao, Forward Current Conduction Mechanism of Mechanically Exfoliated β-Ga2O3/GaN pn Heterojunction Diode, ECS J. Solid State Sci. Technol., 2020, 9, 035001 CrossRef.
  66. K. Xu, R. Wang, Y. Wang, J. Wang, T. Zhi, G. Yang, J. Xue, D. Chen and R. Zhang, Advances and prospects in Ga2O3/GaN heterojunctions: From fabrication to high-performance devices, Mater. Sci. Semicond. Process., 2025, 185, 108874 CrossRef CAS.
  67. Y. Zhang, Y. Li, Z. Wang, R. Guo, S. Xu, C. Liu, S. Zhao, J. Zhang and Y. Hao, Investigation of β-Ga2O3 films and β-Ga2O3/GaN heterostructures grown by metal organic chemical vapor deposition, Sci. China Phys. Mech., 2020, 63, 117311 CrossRef CAS.
  68. D. Seo, S. Kim, H.-Y. Kim, D.-W. Jeon, J.-H. Park and W. S. Hwang, Heteroepitaxial growth of single-crystalline β-Ga2O3 on GaN/Al2O3 using MOCVD, Cryst. Growth Des., 2023, 23, 7090–7094 CrossRef CAS.
  69. M. M. Muhammed, M. Peres, Y. Yamashita, Y. Morishima, S. Sato, N. Franco, K. Lorenz, A. Kuramata and I. S. Roqan, High optical and structural quality of GaN epilayers grown on (201) β-Ga2O3, Appl. Phys. Lett., 2014, 105, 042112 CrossRef.
  70. J. I. Pankove, J. T. Torvik and C.-H. Qiu, Molecular doping of gallium nitride, Appl. Phys. Lett., 1999, 74, 416–418 CrossRef CAS.
  71. F. Ren, J. Han, R. Hickman, J. M. Van Hove, P. P. Chow, J. J. Klaassen, J. R. LaRoche, K. B. Jung, H. Cho, X. A. Cao, S. M. Donovan, R. F. Kopf, R. G. Wilson, A. G. Baca, R. J. Shul, L. Zhang, C. G. Willison, C. R. Abernathy and S. J. Pearton, GaN/AlGaN HBT fabrication, Solid-State Electron., 2000, 44, 239 CrossRef CAS.
  72. T. Kumabe, H. Watanabe, Y. Ando, A. Tanaka, S. Nitta, Y. Honda and H. Amano, “Regrowth-free” fabrication of high-current-gain AlGaN/GaN heterojunction bipolar transistor with n-p-n configuration, Appl. Phys. Express, 2022, 15, 046506 CrossRef CAS.
  73. H. Xing, P. M. Chavarkar, S. Keller, S. P. DenBaars and U. K. Mishra, Very high voltage operation (>330 V) with high current gain of AlGaN/GaN HBTs, IEEE Electron Device Lett., 2003, 24(3), 141 CAS.
  74. J. B. Limb, L. McCarthy, P. Kozodoy, H. Xing, J. Ibbetson, Y. Smorchkova, S. P. DenBaars and U. K. Mishra, AlGaN/GaN HBTs using regrown emitter, Electron. Lett., 1999, 35(19), 1671 CrossRef CAS.
  75. L. S. McCarthy, P. Kozodoy, M. J. W. Rodwell, S. P. DenBaars and U. K. Mishra, AlGaN/GaN heterojunction bipolar transistor, IEEE Electron Device Lett., 1999, 20(6), 277 CAS.
  76. Z. Lochner, H. J. Kim, Y.-C. Lee, Y. Zhang, S. Choi, S.-C. Shen, P. D. Yoder, J.-H. Ryou and R. D. Dupuis, NPN-GaN/InxGa1-xN/GaN heterojunction bipolar transistor on free-standing GaN substrate, Appl. Phys. Lett., 2011, 99, 193501 CrossRef.
  77. S.-C. Shen, R. D. Dupuis, Y.-C. Lee, H.-J. Kim, Y. Zhang, Z. Lochner, P. D. Yoder and J.-H. Ryou, GaN/InGaN Heterojunction Bipolar Transistors With fT>5 GHz, IEEE Electron Device Lett., 2011, 32(8), 1065 CAS.
  78. L. Zhang, X. Wang, J. Zeng, L. Jia, Z. Cheng, Y. Ai, Z. Liu, W. Tan and Y. Zhang, AlGaN/GaN Heterojunction Bipolar Transistors With High Current Gain and Low Specific ON-Resistance, IEEE Trans. Electron Devices, 2022, 69(12), 6633 CAS.
  79. Z. Xia, H. Xue, C. Joishi, J. McGlone, N. K. Kalarickal, S. H. Sohel, M. Brenner, A. Arehart, S. Ringel, S. Lodha, W. Lu and S. Rajan, β-Ga2O3 Delta-Doped Field-Effect Transistors With Current Gain Cutoff Frequency of 27 GHz, IEEE Electron Device Lett., 2019, 40(7), 1052 CAS.
  80. Y. T. Tseng, C. W. Lin, W. C. Yang, K. Y. Chen and K. Y. Cheng, Influence of Al/Si Codiffusion on Current Gain Deterioration in AlGaN/GaN Single Heterojunction Bipolar Transistors, IEEE Trans. Electron Devices, 2016, 63(11), 4262 CAS.
  81. R. D. Dupuis, J. Kim, T.-T. Kao, Y.-C. Lee, Z. Lochner, M.-H. Ji, J.-H. Ryou, T. Detchphrom, and S.-C. Shen, Bipolar III-N high-power electronic devices, in Proceedings Wide Bandgap Power Devices Application (WiPDA), Columbus, OH, USA, 2013, pp. 96–99,  DOI:10.1109/WIPDA.2013.6695571.

This journal is © The Royal Society of Chemistry 2025
Click here to see how this site uses Cookies. View our privacy policy here.