Issue 22, 2025

Ru doping induces phase transition and in-plane S-site electronic modulation in ternary MoS2 heterostructures to enhance hydrogen evolution in water/seawater

Abstract

Optimizing the performance of in-plane S atoms of MoS2 is crucial to extend the breadth of application of MoS2. Herein, using a simple hydrothermal method, we prepared a novel electrocatalyst of Ru incorporated into trinary-MoS2 (Ru-MoS2) nanoflowers. Ru doping could promote preferential transition from the semiconducting (2H) phase to the metallic (1T and 1T′) phase in the basal plane. Density functional theory (DFT) calculations confirmed that Ru incorporated into MoS2 could optimize the electronic structure, improve the conductivity and optimize H* adsorption in interfacial S sites of trinary-MoS2, and facilitate the catalytic hydrogen evolution activity. Moreover, in-plane S sites on the Ru doping 2H/1T′ heterostructure have been shown to be highly active sites for trinary-MoS2. Benefiting from the good conductivity and activated interfacial S sites in trinary-MoS2, the prepared Ru-MoS2 exhibited superior electrocatalytic activity at 10 mA cm−2 and only required overpotentials of 89 mV and 112 mV in alkaline solution and alkaline seawater, respectively. This work provides a fresh insight into the design of highly-efficient trinary-MoS2 electrocatalysts.

Graphical abstract: Ru doping induces phase transition and in-plane S-site electronic modulation in ternary MoS2 heterostructures to enhance hydrogen evolution in water/seawater

Supplementary files

Article information

Article type
Paper
Submitted
23 Mar 2025
Accepted
22 Apr 2025
First published
01 May 2025

Nanoscale, 2025,17, 13842-13849

Ru doping induces phase transition and in-plane S-site electronic modulation in ternary MoS2 heterostructures to enhance hydrogen evolution in water/seawater

J. Sun, J. Rao, S. Qin, X. Li, R. Jia, K. Huang, Y. Zheng and X. Meng, Nanoscale, 2025, 17, 13842 DOI: 10.1039/D5NR01199J

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