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Correction: Is the single-ion conductor cubic Li7La3Zr2O12 a binary ionic electrolyte?

Peng Bai abc
aDepartment of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, St. Louis, Missouri 63130, USA. E-mail: pbai@wustl.edu
bInstitute of Materials Science and Engineering, Washington University in St. Louis, St. Louis, Missouri 63130, USA
cDepartment of Materials Science and Engineering, Stanford University, Stanford, California 94305, USA

Received 19th May 2025 , Accepted 19th May 2025

First published on 16th June 2025


Abstract

Correction for ‘Is the single-ion conductor cubic Li7La3Zr2O12 a binary ionic electrolyte?’ by Peng Bai, Mater. Horiz., 2025, https://doi.org/10.1039/d5mh00069f.


The author regrets the presence of typos in Fig. 2a of the published article, where “Neutral” is spelled incorrectly as “Neural” in four locations. The corrected version of Fig. 2 is shown in this notice.
image file: d5mh90065d-f2.tif
Fig. 2 Schematic of the defects chemistry and mobile charge carriers along the Li transport pathway in c-LLZO. (a) In equilibrium, Li ions are distributed homogeneously in the 24d and 96h sites, forming 4 types of neutral species: Li+ ion on 24d Li-site image file: d5mh90065d-t1.tif and Li+ ion on 96h Li-site image file: d5mh90065d-t2.tif are shown as solid blue spheres; vacant 24d Li-site image file: d5mh90065d-t3.tif and vacant 96h Li-site image file: d5mh90065d-t4.tif are shown as open blue circles. (b) When the electrochemical driving force is applied, external Li+ ions from the positive electrode are pushed into the crystal structure near the positive interface to form image file: d5mh90065d-t5.tif (solid pink spheres), while Li+ ions on a image file: d5mh90065d-t6.tif are stripped out of the 24d or 96h site near the negative interface to generate image file: d5mh90065d-t7.tif (pink open circles). Native defects are shown in blue. Electrochemically generated defects are in pink. Structural ions La, Zr, Ta, and O are omitted for clarity.

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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