Correction: Luminescent ionic heterobimetallic diphosphine-β-diketiminate complexes

Abstract

Correction for ‘Luminescent ionic heterobimetallic diphosphine-β-diketiminate complexes’ by Steven Kebernik et al., Dalton Trans., 2025, 54, 13192–13199, https://doi.org/10.1039/D5DT00977D.

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The authors regret that the lifetime values in Table 1 and Table S1 were incorrectly labelled as 6 and 7 microseconds. While the incorrect table reflects the actual measured values, due to the experimental setup with a lamp signal lifetime of approximately 6 microseconds, the actual lifetime is likely shorter. Therefore, the lifetime values in the table are now correctly labelled as ‘Lifetimes are below the detection limit of our detector.’:

Table 1 Experimentally determined data of the PLE and PL spectra as well as the lifetimes of compounds 2–5

		λmax,exc [nm]		λmax,em [nm]		ΦPL [%]	τ [µs]
		77 K	298 K	77 K	298 K	298 K	77 K	298 K
a Lifetimes are below the detection limit of our detector.b Lifetimes are at the detection limit of our detector and may be uncertain.
1	Solid	440	460	470	485		—^a	—^a
[PNacZn]				525	535	75
				550	560
				595
2	Solid	385	400	435	445		—^a	–^a
[PNacZnAu]^+				490	480	28	7^b/351	13
	THF sol.	355	405	425	445		—	—^a
				480			6^b/218/724
		400		440			—^a
				500			6^b/8/687
3	Solid	385	400	440	440	41	— ^a	—^a
[PNacZnAg]^+	THF sol.	370	390	430	430
4	Solid	410	420	450	455	6	—^a	—^a
[PNacZnCu]^+				505
	THF sol.	395	405	450	440
5	Solid	445	455	605	590	55	40/103	—^a
[PNacAuCu]^+	THF sol.	430	480	585	605		62/163

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The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.

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