Research progress in fluorescence sensors for the detection of Fe3+, Cr2O72− and nitrobenzene based on MOFs

Abstract

The accelerated progress of industrialization has led to anthropogenic and industrial activities that generate ferric ions (Fe³⁺), dichromate ions (Cr₂O₇²⁻), and nitrobenzene (NB), causing severe environmental pollution and health hazards. Metal–organic frameworks (MOFs) exhibit wide-ranging sensing performance due to their structural diversity, designability, high specific surface area, porosity, and excellent fluorescence properties. In this perspective, we summarize the representative work to date in the field of sensing Fe³⁺, Cr₂O₇²⁻, and NB using transition metal-based, lanthanide-based, and ratiometric bimetallic-based MOFs. Furthermore, the mechanism, current challenges, and prospects of MOF sensors have been elaborated upon.