Issue 20, 2025

Efficient synergistic photocatalysis of supported Ir/Pd dual metal catalysts based on flexible polymeric brushes

Abstract

Dual metal complexes, Pd(PPh3)4 and Ir(ppy)2(dtbbpy)PF6, are simultaneously anchored onto SiO2-grafted poly(4-vinyl benzyl chloride) (PVBC) brushes via Friedel–Crafts alkylation in one pot, affording supported dual Pd/Ir complexes which gave good yields in photocatalytic α-allylation.

Graphical abstract: Efficient synergistic photocatalysis of supported Ir/Pd dual metal catalysts based on flexible polymeric brushes

Supplementary files

Article information

Article type
Communication
Submitted
12 Mar 2025
Accepted
01 May 2025
First published
06 May 2025

Dalton Trans., 2025,54, 8055-8060

Efficient synergistic photocatalysis of supported Ir/Pd dual metal catalysts based on flexible polymeric brushes

W. Tian, Y. Luo, S. Zhu, Y. Zhou, C. He and X. Ma, Dalton Trans., 2025, 54, 8055 DOI: 10.1039/D5DT00593K

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