From the journal:

Dalton Transactions

Emission enhancement in a luminescent polychlorinated diphenylpyridylmethyl radical through coordination to silver(i)†

Takuto Mibu,*ab   Ryota Matsuoka, ORCID logo ab   Masanari Nagasaka ORCID logo a  and  Tetsuro Kusamoto ORCID logo *abcd  

* Corresponding authors

a Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan
E-mail: t-mibu@sagami.or.jp, kusamoto.tetsuro.es@osaka-u.ac.jp

b Division of Frontier Materials Science, Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

c Spintronics Research Network Division, Institute for Open and Transdisciplinary Research Initiatives, Osaka University, Toyonaka, Osaka 560-8531, Japan

d FOREST, JST, Honcho 4-1-8, Kawaguchi, Saitama 332-0012, Japan

Abstract

A luminescent silver(I) complex containing a luminescent radical ligand was prepared for the first time. Coordination to AgI enhanced and red-shifted the radical-centered emission. This study demonstrates similar effects in the luminescence of the radical by complexation with group 11 d10-metal ions.

Graphical abstract: Emission enhancement in a luminescent polychlorinated diphenylpyridylmethyl radical through coordination to silver(i)

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Article information

DOI
https://doi.org/10.1039/D4DT03129F
Article type
Paper
Submitted
08 Nov 2024
Accepted
09 Dec 2024
First published
17 Dec 2024

Dalton Trans., 2025, Advance Article

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Emission enhancement in a luminescent polychlorinated diphenylpyridylmethyl radical through coordination to silver(I)

T. Mibu, R. Matsuoka, M. Nagasaka and T. Kusamoto, Dalton Trans., 2025, Advance Article , DOI: 10.1039/D4DT03129F

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