High-temperature phase evolution in CuO/Al2O3 oxygen carriers: insights from in situ quick XAS

Abstract

This study investigates phase transitions in CuO/Al2O3 oxygen carriers during chemical looping combustion (CLC), aiming to understand performance and stability over extended redox cycles. In situ quick X-ray assorption spectroscopy (QXAS) was employed to track the transformations of the copper aluminate phase (CuxAlyO4) over 50 redox cycles in various oxidizing (2.5 to 21% O2 in N2) and reducing (H2, CO, CH4) environments. The study reveals that the oxygen carrier undergoes significant phase transitions, reaching a threshold where CuxAlyO4 predominantly converts to copper oxide and α-Al2O3, leading to irreversible structural modifications. Complementary SEM analysis further highlights morphological changes, such as particle growth prior to α-Al2O3 formation. This cycle-dependent phase evolution provides new insights into accelerated ageing mechanism involving the interplay between copper phase transformations and α-Al2O3 formation, which is critical for enhancing the durability of oxygen carriers in CLC applications.

Graphical abstract: High-temperature phase evolution in CuO/Al2O3 oxygen carriers: insights from in situ quick XAS

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Article information

Article type
Paper
Submitted
26 Jan 2025
Accepted
26 Aug 2025
First published
29 Aug 2025

Phys. Chem. Chem. Phys., 2025, Advance Article

High-temperature phase evolution in CuO/Al2O3 oxygen carriers: insights from in situ quick XAS

S. Sharna, V. Rouchon, A. Lambert, V. Briois, D. Chiche, A. Gay, C. Legens and O. Ersen, Phys. Chem. Chem. Phys., 2025, Advance Article , DOI: 10.1039/D5CP00358J

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