Crystal structures of sandwich-type potassium cation complexes formed from benzo-15-crown-5-based ligand containing a chloromaleimide moiety

Abstract

We developed a novel benzo-15-crown-5 (B15C5)-based organic ligand containing an N-phenylchloromaleimide moiety. Two geometrically different potassium cation (K+) complexes with a B15C5/K+/B15C5 sandwich structure were prepared and characterised via single-crystal X-ray diffraction.

Graphical abstract: Crystal structures of sandwich-type potassium cation complexes formed from benzo-15-crown-5-based ligand containing a chloromaleimide moiety

Supplementary files

Article information

Article type
Communication
Submitted
09 Mar 2025
Accepted
01 May 2025
First published
01 May 2025

CrystEngComm, 2025, Advance Article

Crystal structures of sandwich-type potassium cation complexes formed from benzo-15-crown-5-based ligand containing a chloromaleimide moiety

Y. Hirayama, A. Ito and R. Ochi, CrystEngComm, 2025, Advance Article , DOI: 10.1039/D5CE00252D

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