Issue 26, 2025

Selenoamides with two reactive sites: synthesis, structures, and dual reactivity of (selenocarbamoyl)phosphines

Abstract

Selenoamides stabilized by a phosphino group, i.e., (selenocarbonyl)phosphines, were synthesized and their solid-state structures were crystallographically determined for the first time. These (selenocarbamoyl)phosphines exhibit dual reactivity on two principal sites in reactions with electrophiles, i.e., on the phosphorus and selenium atoms, whereby the site where the reaction occurs depends on the nature of the reagent.

Graphical abstract: Selenoamides with two reactive sites: synthesis, structures, and dual reactivity of (selenocarbamoyl)phosphines

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2025
Accepted
04 Mar 2025
First published
10 Mar 2025

Chem. Commun., 2025,61, 4955-4958

Selenoamides with two reactive sites: synthesis, structures, and dual reactivity of (selenocarbamoyl)phosphines

R. Masuda, T. Yano and H. Kusama, Chem. Commun., 2025, 61, 4955 DOI: 10.1039/D5CC00607D

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