From the journal:

Chemical Communications

Continuous photocatalytic C–C coupling achieved using palladium anchored to a covalent organic framework†

Chao Ma,‡a   Zhe Wu,‡a   Yi-Tong Hou,‡a   Shao-Xuan Xiong,a   Li-Hua Ma,*ab   Zhi-Ming Zhang, ORCID logo a   Tong-Bu Lu ORCID logo a  and  Song Guo ORCID logo *a  

* Corresponding authors

a Institute for New Energy Materials and Low Carbon Technologies, School of Material Science & Engineering, Tianjin University of Technology, Tianjin 300384, China
E-mail: guosong@email.tjut.edu.cn

b Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Tianjin 300071, P. R. China
E-mail: malh987@hotmail.com

Abstract

We firstly reported a single-atom palladium photocatalyst, Pd-Ace-COF, for a continuous C–C coupling reaction. Under visible light irradiation, Pd-Ace-COF efficiently drives C–C coupling to form biphenyl with a >99% yield. Impressively, Pd-Ace-COF exhibits good stability and high activity in the continuous-flow reactor, highlighting its great potential for practical applications.

Graphical abstract: Continuous photocatalytic C–C coupling achieved using palladium anchored to a covalent organic framework

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Article information

DOI
https://doi.org/10.1039/D4CC06528J
Article type
Communication
Submitted
12 Dec 2024
Accepted
02 Apr 2025
First published
03 Apr 2025

Chem. Commun., 2025, Advance Article

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Continuous photocatalytic C–C coupling achieved using palladium anchored to a covalent organic framework

C. Ma, Z. Wu, Y. Hou, S. Xiong, L. Ma, Z. Zhang, T. Lu and S. Guo, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D4CC06528J

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