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Abstract | Cited by

Visible-light-promoted hydrocarboxylation of allenes with formate salt and CO2 was developed for the first time using commercially available [Ir(ppy)2(dtbbpy)]PF6 as a photocatalyst. This strategy provides an efficient and practical method to access β,γ-unsaturated linear carboxylic acids in moderate yields with complete regioselectivity.

Graphical abstract: Visible-light-promoted regioselective hydrocarboxylation of allenes with formate salt and CO2

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