Issue 3, 2024

Manipulating the charge transport via incorporating a cobalt bridge into a single-molecule junction

Abstract

Cobalt-bridged organometallic molecular wires (p-Co-p, p-Co-m and m-Co-m) are synthesized, and their charge transport properties are studied. The experimental results show that the quantum interference (QI) effects of cobalt-bridged organometallic wires are determined by the anchoring group. Interestingly, the cobalt-bridge reduces the conductance of the junctions and tunes the QI effect of the wires. These results demonstrate the unique property of metal-bridged organometallic molecular wires and their potential applications in molecular electronics.

Graphical abstract: Manipulating the charge transport via incorporating a cobalt bridge into a single-molecule junction

Supplementary files

Article information

Article type
Communication
Submitted
13 Oct 2023
Accepted
13 Dec 2023
First published
14 Dec 2023

Phys. Chem. Chem. Phys., 2024,26, 1608-1611

Manipulating the charge transport via incorporating a cobalt bridge into a single-molecule junction

C. Ma, Y. Li, A. Tang, R. Wang, Y. Li, Z. Li, J. Yang and H. Li, Phys. Chem. Chem. Phys., 2024, 26, 1608 DOI: 10.1039/D3CP04979E

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