Issue 78, 2024
From the journal:

Chemical Communications

Bismuth-based electrocatalytic scheme enabling efficient and selective electrosynthesis of 4-aminophenol in acidic media†

Fitri Nur Indah Sari,a   Cheng-Yi Su,a   Shih-Ching Huanga  and  Chia-Yu Lin ORCID logo *abc  

* Corresponding authors

a Department of Chemical Engineering, National Cheng Kung University, Tainan 70101, Taiwan

b Hierarchical Green-Energy Materials (Hi-GEM) Research Center, National Cheng Kung University, Tainan 70101, Taiwan

c Program on Key Materials & Program on Smart and Sustainable Manufacturing, Academy of Innovative Semiconductor and Sustainable Manufacturing, National Cheng Kung University, Tainan 70101, Taiwan
E-mail: cyl44@mail.ncku.edu.tw

Abstract

A highly efficient electrocatalytic platform based on in situ formed metallic bismuth submicron crystals (microBi) was developed for 4-aminophenol electrosynthesis via the electrochemical reduction of 4-nitrophenol at acidic pH. The facile formation and high reactivity of microBi enable efficient electrosynthesis of 4-aminophenol with high selectivity (∼100%) at the expense of an ultra-low overpotential.

Graphical abstract: Bismuth-based electrocatalytic scheme enabling efficient and selective electrosynthesis of 4-aminophenol in acidic media

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Article information

DOI
https://doi.org/10.1039/D4CC03493G
Article type
Communication
Submitted
13 Jul 2024
Accepted
05 Sep 2024
First published
05 Sep 2024

Chem. Commun., 2024,60, 10922-10925

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Bismuth-based electrocatalytic scheme enabling efficient and selective electrosynthesis of 4-aminophenol in acidic media

F. N. I. Sari, C. Su, S. Huang and C. Lin, Chem. Commun., 2024, 60, 10922 DOI: 10.1039/D4CC03493G

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