Issue 18, 2024
From the journal:

Chemical Communications

Spodium bonding in bis(alkynyl)mecurials†

Chee S. Onn, ORCID logo a   Anthony F. Hill ORCID logo *a  and  Jas S. Ward ORCID logo ab  

* Corresponding authors

a Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, Australia
E-mail: a.hill@anu.edu.au

b Department of Chemistry, University of Jyväskylä, Jyväskylä, Finland

Abstract

The new bis(alkynyl)mercurial Hg{C[triple bond, length as m-dash]CSeC[triple bond, length as m-dash]W(CO)2(Tp*)}2 (Tp* = tris(dimethylpyrazolyl)borate) forms adducts with fluoride and phenathroline, the structures of which are interpreted in the context of two-coordinate mercury presenting a σ-torroid for spodium bonding.

Graphical abstract: Spodium bonding in bis(alkynyl)mecurials

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Article information

DOI
https://doi.org/10.1039/D3CC06027F
Article type
Communication
Submitted
10 Dec 2023
Accepted
22 Jan 2024
First published
24 Jan 2024

Chem. Commun., 2024,60, 2552-2555

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Spodium bonding in bis(alkynyl)mecurials

C. S. Onn, A. F. Hill and J. S. Ward, Chem. Commun., 2024, 60, 2552 DOI: 10.1039/D3CC06027F

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