Issue 3, 2024
From the journal:

Chemical Communications

Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex†

Rui Wang,ab   Yunling Pan,ac   Sushan Feng,ad   Chenyi Liang,ab   Jianhui Xie, ORCID logo c   Tai-Chu Lau ORCID logo e  and  Yingying Liu ORCID logo *a  

* Corresponding authors

a Institute of Intelligent Machines, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, P. R. China
E-mail: yyliu@iim.ac.cn

b Science Island Branch, Graduate School of USTC, Hefei 230026, P. R. China

c Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China

d Institutes of Physical Science and Information Technology, Anhui University, Hefei 230601, P. R. China

e Department of Chemistry, City University of Hong Kong, Kowloon Tong, Hong Kong, P. R. China

Abstract

The use of metal-acylperoxo complexes as oxidants has been little explored. Herein we report the synthesis and characterization of the first seven-coordinate Ru-acylperoxo complex, [RuIV(bdpm)(pic)2(mCPBA)]+ (H2bdpm = [2,2′-bipyridine]-6,6′-diylbis(diphenylmethanol); pic = 4-picoline; HmCPBA = m-chloroperbenzoic acid). This complex is a highly reactive oxidant for C–H bond activation and O-atom transfer reactions.

Graphical abstract: Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3CC04751B
Article type
Communication
Submitted
25 Sep 2023
Accepted
04 Dec 2023
First published
05 Dec 2023

Chem. Commun., 2024,60, 312-315

Permissions

Request permissions

Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex

R. Wang, Y. Pan, S. Feng, C. Liang, J. Xie, T. Lau and Y. Liu, Chem. Commun., 2024, 60, 312 DOI: 10.1039/D3CC04751B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements