Double-channel sensor for high precision measurement of methane-based on a dual-path Herriott cell

Abstract

A double-channel methane (CH4) sensor was developed using a dual-pass multipass cell (DP-MPC) and a novel method that combines average dual-channel concentration signals with optimized detector gain configuration. This DP-MPC features two input/output coupling holes, resulting in absorption path lengths of approximately 95.8 meters and 35.8 meters, respectively. By optimizing the photodetector gain configuration and averaging the dual-channel concentration signals, the detection performance of the sensor was further enhanced. Allan deviation analysis indicated that under the 1-s integral time measurement precision of the sensor improved to approximately 20 ppb at a concentration of 2 ppm CH4 after dual-channel averaging and detector gain optimization. Meanwhile, the measurement precision improved by 2-3 times under the 10-s integral time. The sensor demonstrated its stability and reliability through continuous outdoor atmospheric CH4 measurements.

Article information

Article type
Paper
Submitted
16 Aug 2024
Accepted
02 Oct 2024
First published
07 Oct 2024

Analyst, 2024, Accepted Manuscript

Double-channel sensor for high precision measurement of methane-based on a dual-path Herriott cell

H. Ma, S. Wang, G. Wang, Q. Zhang, S. Zha, X. Cai, L. Li, P. Pan, Q. Liu and S. Zhan, Analyst, 2024, Accepted Manuscript , DOI: 10.1039/D4AN01107D

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