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Correction: Optical property trends in a family of {Mo6I8} aquahydroxo complexes
Margarita V.
Marchuk
a,
Natalya A.
Vorotnikova
a,
Yuri A.
Vorotnikov
*a,
Natalia V.
Kuratieva
a,
Dmitri V.
Stass
bc and
Michael A.
Shestopalov
a
aNikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation. E-mail: vorotnikov@niic.nsc.ru
bVoevodsky Institute of Chemical Kinetics and Combustion SB RAS, 3 Institutskaya Str., Novosibirsk, 630090, Russian Federation
cNovosibirsk State University, 2 Pirogova Str., 630090 Novosibirsk, Russian Federation
First published on 13th October 2023
Abstract
Correction for ‘Optical property trends in a family of {Mo6I8} aquahydroxo complexes’ by Margarita V. Marchuk et al., Dalton Trans., 2021, 50, 8794–8802, https://doi.org/10.1039/D1DT01293B.
The authors regret an error in determining the band gap values of compounds 1-NO3 and 1-OTs. A revised version of Fig. 5 is shown below:
 | ||
| Fig. 1 Solid-state absorption spectra of 1-NO3, 1-OTs, 2-h2, and 2-h12new obtained by conversion of the corresponding diffuse reflectance spectra using the Kubelka–Munk function. Inset: estimation of the energy gaps via Tauc plots. | ||
The obtained values correlate well with the absorption spectra, namely the Eg values increase with the protonation of two OH− groups, ∼1.65 eV (2) vs. ∼1.87 eV (1).
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
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