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Correction: Optical property trends in a family of {Mo6I8} aquahydroxo complexes

Margarita V. Marchuk a, Natalya A. Vorotnikova a, Yuri A. Vorotnikov *a, Natalia V. Kuratieva a, Dmitri V. Stass bc and Michael A. Shestopalov a
aNikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation. E-mail: vorotnikov@niic.nsc.ru
bVoevodsky Institute of Chemical Kinetics and Combustion SB RAS, 3 Institutskaya Str., Novosibirsk, 630090, Russian Federation
cNovosibirsk State University, 2 Pirogova Str., 630090 Novosibirsk, Russian Federation

Received 3rd October 2023 , Accepted 3rd October 2023

First published on 13th October 2023


Abstract

Correction for ‘Optical property trends in a family of {Mo6I8} aquahydroxo complexes’ by Margarita V. Marchuk et al., Dalton Trans., 2021, 50, 8794–8802, https://doi.org/10.1039/D1DT01293B.


The authors regret an error in determining the band gap values of compounds 1-NO3 and 1-OTs. A revised version of Fig. 5 is shown below:
image file: d3dt90178e-f5.tif
Fig. 1 Solid-state absorption spectra of 1-NO3, 1-OTs, 2-h2, and 2-h12new obtained by conversion of the corresponding diffuse reflectance spectra using the Kubelka–Munk function. Inset: estimation of the energy gaps via Tauc plots.

The obtained values correlate well with the absorption spectra, namely the Eg values increase with the protonation of two OH groups, ∼1.65 eV (2) vs. ∼1.87 eV (1).

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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