A ratiometric luminescence sensing platform based on lanthanide-based silica nanoparticles for selective and sensitive detection of Fe3+ and Cu2+ ions

Abstract

Detection of Fe(III) and Cu(II) in water is highly desirable because their abnormal levels can cause serious harm to human health and environmental safety. In this work, a ratiometric luminescence sensing platform based on lanthanide-based silica nanoparticles was constructed for the detection of Fe³⁺ and Cu²⁺ ions. The terbium-silica nanoparticles (named SiO₂@Tb) with dual-emission signals were successfully prepared by grafting Tb³⁺ ions onto trimellitic anhydride (TMA) functionalized silica nanospheres. It can serve as a ratiometric fluorescent probe for the detection of Fe³⁺ and Cu²⁺ ions in water with the green emission of Tb³⁺ ions as a response signal and the blue emission of silica nanospheres as the reference signal. Significantly, an easy-to-differentiate color change for visual detection was also realized. SiO₂@Tb shows high sensitivity even in very low concentration regions towards the sensing of Fe³⁺ and Cu²⁺ with low detection limits of 0.75 μM and 0.91 μM, respectively. Moreover, the mechanism for the luminescence quenching of SiO₂@Tb was systematically investigated, and was attributed to the synergetic effect of the absorption competition quenching (ACQ) mechanism and cation exchange. This study demonstrates that SiO₂@Tb can be employed as a promising fluorescent probe for the detection of Fe³⁺ and Cu²⁺ ions, and the combination of lanthanide ions with silica nanoparticles is an effective strategy to construct a ratiometric fluorescent sensing platform for the determination of analytes in environmental detection.