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Correction: Time-resolved infra-red studies of photo-excited porphyrins in the presence of nucleic acids and in HeLa tumour cells: insights into binding site and electron transfer dynamics

Páraic M. Keane *ab, Clara Zehe c, Fergus E. Poynton ad, Sandra A. Bright ad, Sandra Estayalo-Adrián ad, Stephen J. Devereux c, Paul M. Donaldson e, Igor V. Sazanovich e, Michael Towrie e, Stanley W. Botchway e, Christine J. Cardin b, D. Clive Williams d, Thorfinnur Gunnlaugsson ad, Conor Long *f, John M. Kelly *a and Susan J. Quinn *c
aSchool of Chemistry, Trinity College Dublin, Dublin 2, Ireland. E-mail: keanepa@tcd.ie; jmkelly@tcd.ie
bSchool of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, UK
cSchool of Chemistry, University College Dublin, Dublin 4, Ireland. E-mail: susan.quinn@ucd.ie
dTrinity Biomedical Sciences Institute, The University of Dublin, Pearse St, Dublin 2, Ireland
eSTFC Central Laser Facility, Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot OX11 0QX, UK
fSchool of Chemical Sciences, Dublin City University, Dublin 9, Ireland. E-mail: conor.long@dcu.ie

Received 14th July 2023 , Accepted 14th July 2023

First published on 18th August 2023


Abstract

Correction for ‘Time-resolved infra-red studies of photo-excited porphyrins in the presence of nucleic acids and in HeLa tumour cells: insights into binding site and electron transfer dynamics’ by Páraic M. Keane et al., Phys. Chem. Chem. Phys., 2022, 24, 27524–27531, https://doi.org/10.1039/D2CP04604K.


The TRIR spectrum given in panel b of Fig. 2 in the published version of the manuscript is incorrect. The correct figure is shown below.
image file: d3cp90155f-f2.tif
Fig. 1 TRIR spectra at 3 (red), 10 (blue), 50 ps (black) for 500 μM PtTMPyP4 in the presence of nucleic acids (a) 10 mM GMP, (b) 500 μM {d(GC)5}2, (c) 500 μM {d(CGCAAATTTGCG)}2, (d) c-MYC quadruplex. In buffered (50 mM phosphate pH 7, c-MYC also with 70 mM KCl, D2O). λexc = 400 nm (0.25–1 μJ). Regions of nucleotide absorption are highlighted and spectra are normalised to the 1636 cm−1 transient.

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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