Issue 91, 2023
From the journal:

Chemical Communications

Skeletal rearrangement of a boron-containing annulenic molecule into a macrocycle bridged by an electronically stabilized boron cation†

Yukihiro Murata,ab   Cihan Özen,cd   Satoshi Maeda, ORCID logo *cd   Takanori Fukushima ORCID logo abe  and  Yoshiaki Shoji ORCID logo *ab  

* Corresponding authors

a Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
E-mail: yshoji@res.titech.ac.jp

b Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

c Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo 060-8510, Japan
E-mail: smaeda@eis.hokudai.ac.jp

d Department of Chemistry, Hokkaido University, Sapporo 060-8510, Japan

e Living Systems Materialogy (LiSM) Research Group, International Research Frontiers Initiative (IRFI), Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Abstract

An annulenic molecule containing a three-coordinate chloroborane moiety, which exhibits a borane-olefin proximity effect, undergoes a skeletal rearrangement upon chloride abstraction, to generate a three-dimensional macrocyclic molecule featuring a borocenium (η5-cyclopentadienyl–B+–R) structure.

Graphical abstract: Skeletal rearrangement of a boron-containing annulenic molecule into a macrocycle bridged by an electronically stabilized boron cation

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3CC04830F
Article type
Communication
Submitted
28 Sep 2023
Accepted
23 Oct 2023
First published
24 Oct 2023

Chem. Commun., 2023,59, 13635-13638

Author version available


Download author version (PDF)

Permissions

Request permissions

Skeletal rearrangement of a boron-containing annulenic molecule into a macrocycle bridged by an electronically stabilized boron cation

Y. Murata, C. Özen, S. Maeda, T. Fukushima and Y. Shoji, Chem. Commun., 2023, 59, 13635 DOI: 10.1039/D3CC04830F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements