Issue 78, 2023

Circularly polarized chemiluminescence from planar chiral bis(adamantylidene-1,2-dioxetane)s

Abstract

Bis(adamantylidene-1,2-dioxetane), upon conjugation to a planar chiral scaffold of [2.2]paracyclophane, gave chemical-triggerable circularly polarized chemiluminescence with a dissymmetry factor of 1.1 × 10−3 scale, to which exciton chirality upon chemiexcitation was assigned as the origin.

Graphical abstract: Circularly polarized chemiluminescence from planar chiral bis(adamantylidene-1,2-dioxetane)s

Supplementary files

Article information

Article type
Communication
Submitted
13 Jul 2023
Accepted
15 Aug 2023
First published
16 Aug 2023

Chem. Commun., 2023,59, 11652-11655

Circularly polarized chemiluminescence from planar chiral bis(adamantylidene-1,2-dioxetane)s

M. Shi, M. Xie, S. Wan, C. Zou, Y. Liu, X. Zhou, P. Yang, X. Chang and W. Lu, Chem. Commun., 2023, 59, 11652 DOI: 10.1039/D3CC03389A

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