Dihydroxyacetone production by glycerol oxidation under moderate condition using Pt loaded on La1−xBixOF solids

Naoyoshi Nunotani; Masanari Takashima; Yeon-Bin Choi; Yuta Uetake; Hidehiro Sakurai; Nobuhito Imanaka

doi:10.1039/D3CC01734F

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Dihydroxyacetone production by glycerol oxidation under moderate condition using Pt loaded on La_1−xBi_xOF solids†

Naoyoshi Nunotani,

^a Masanari Takashima,^a Yeon-Bin Choi,^a Yuta Uetake,

^ab Hidehiro Sakurai

^ab and Nobuhito Imanaka

*^a

Author affiliations

* Corresponding authors

^a Department of Applied Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: imanaka@chem.eng.osaka-u.ac.jp

^b Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

Pt/La_1−xBi_xOF/SBA-16 (SBA-16: Santa Barbara Amorphous no. 16) catalysts were prepared to produce dihydroxyacetone (DHA) from glycerol under moderate conditions. By using 7 wt% Pt/16 wt% La_0.95Bi_0.05OF/SBA-16, the DHA yield reached up to 78.4% (glycerol conversion: 100%) after reacting for 6 h at 30 °C in an atmospheric open-air system.

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Article information

DOI: https://doi.org/10.1039/D3CC01734F
Article type: Communication
Submitted: 08 Apr 2023
Accepted: 10 Jul 2023
First published: 10 Jul 2023

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Chem. Commun., 2023,59, 9533-9536

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Dihydroxyacetone production by glycerol oxidation under moderate condition using Pt loaded on La_1−xBi_xOF solids

N. Nunotani, M. Takashima, Y. Choi, Y. Uetake, H. Sakurai and N. Imanaka, Chem. Commun., 2023, 59, 9533 DOI: 10.1039/D3CC01734F

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Chemical Communications