Structural transition and chemical reactivity of atomic carbon chains†
Abstract
The sp-hybridized carbon chain (carbyne) is a representative 1D atomic material, whose bonding structure and chemical reactivity have remained a mystery for a century. Here, we report the unexpected alternating bond orders of 1.4 and 2.6 for the most stable carbon chain and the in situ diffuse reflectance infrared Fourier-transform spectroscopy (DRIFTS) detection of the temperature-dependent reversible change of the bond order alternation. Moreover, we revealed its reactivities with O2, H2, and CO2 at temperatures up to 600 °C and created an end-group-protection strategy to stabilize it. These observations open a new door to the chemistry of atomic materials.
- This article is part of the themed collection: Chemical Communications HOT Articles 2023