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The visible-light-mediated tandem phosphorylation/cyclization of N-arylacrylamides with H-phosphine oxides has been developed for the synthesis of phosphorylated oxindoles. This efficient and facile process was useful for the construction of a C–P bond and triggered the formation of a C–C bond with good compatibility with functional groups undermild reaction conditions.

Graphical abstract: Visible-light-mediated tandem phosphorylation/cyclization for the synthesis of phosphorylated oxindoles

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