A bioinspired solar evaporator with a horizontal channel-like framework for efficient and stable high-salinity brine desalination

Abstract

In recent years, solar steam generation has been one of the most promising and sustainable techniques for water desalination. However, the heat loss to bulk water dramatically decreases the evaporation rate. Besides, salt deposition on the evaporation surface during brine treatment limits the long-term operation of evaporators. Herein, solar evaporators with a horizontal channel-like framework are reported and high efficiency and outstanding salt resistance are achieved. Firstly, eggplants with a hollow fiber alignment structure were carbonized as CEP evaporators. The CEP-H evaporator with a horizontal fiber growth direction shows a high evaporation efficiency of 90.6% and excellent salt resistance when treating high-salinity brine (20 wt%). The low thermal conductivity perpendicular to the fiber growth direction impedes the conductive heat transfer into bulk water, and fast water transport along the fiber growth direction is beneficial for salt resistance. In addition, a proof-of-concept evaporator polypyrrole-coated polypropylene hollow fiber membrane with a horizontal channel-like framework (PPy/PP-H) has also been developed. This hollow fiber membrane shows a high evaporation rate of 1.64 kg m⁻² h⁻¹ due to multiangle evaporation and also demonstrates excellent salt-resisting performance for high-salinity brine treatment (20 wt%). The study demonstrates the effect of the horizontal channel-like framework for high evaporation performance and salt resistance, providing new insights into the solar evaporator design for seawater desalination and wastewater treatment.