Isolation of single crystals of a homoleptic UO22+-diglycolamide complex from a room temperature ionic liquid: X-ray crystallography and complexation studies

Seraj A. Ansari; Amey P. Wadawale; Willem Verboom; Prasanta K. Mohapatra

doi:10.1039/D1NJ05760J

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Isolation of single crystals of a homoleptic UO₂²⁺-diglycolamide complex from a room temperature ionic liquid: X-ray crystallography and complexation studies†

Seraj A. Ansari,

^a Amey P. Wadawale,^b Willem Verboom

^c and Prasanta K. Mohapatra

*^a

Author affiliations

* Corresponding authors

^a Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai–400 085, India
E-mail: mpatra@barc.gov.in

^b Chemistry Division, Bhabha Atomic Research Centre, Mumbai–400 085, India

^c Molecular Nanofabrication Group, Department of Molecules & Materials, MESA+Institute for Nanotechnology, University of Twente, P.O. Box 217, Enschede 7500 AE, The Netherlands

Abstract

Complexation and structural investigations of the solid complex of UO₂²⁺ ions and N,N,N′,N′-tetramethyl diglycolamide isolated from a room temperature ionic liquid, for the first time, revealed that the nature and the structural features of the complex are identical to those of the complex isolated from an aqueous medium.

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Article information

DOI: https://doi.org/10.1039/D1NJ05760J
Article type: Communication
Submitted: 21 Oct 2021
Accepted: 07 Dec 2021
First published: 07 Dec 2021

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New J. Chem., 2022,46, 950-954

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Isolation of single crystals of a homoleptic UO₂²⁺-diglycolamide complex from a room temperature ionic liquid: X-ray crystallography and complexation studies

S. A. Ansari, A. P. Wadawale, W. Verboom and P. K. Mohapatra, New J. Chem., 2022, 46, 950 DOI: 10.1039/D1NJ05760J

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