Issue 15, 2022

Progress on transition metal catalyzed asymmetric hydroesterification, hydrocarboxylation, and hydroamidation reactions of olefins

Abstract

Hydrocarboxylation, hydroesterification, and hydroamidation of olefins are fundamental transformations in organic synthesis. Asymmetric processes for these transformations provide an effective and straightforward approach to optically active carboxylic acids and their derivatives, which are highly useful compounds in pharmaceuticals, materials, fine chemicals, etc. This review provides a brief summary of the development of asymmetric hydroesterification, hydrocarboxylation, and hydroamidation with CO and its surrogates.

Graphical abstract: Progress on transition metal catalyzed asymmetric hydroesterification, hydrocarboxylation, and hydroamidation reactions of olefins

Article information

Article type
Review Article
Submitted
04 Mar 2022
First published
19 Jul 2022

Chem. Soc. Rev., 2022,51, 6757-6773

Progress on transition metal catalyzed asymmetric hydroesterification, hydrocarboxylation, and hydroamidation reactions of olefins

J. Li and Y. Shi, Chem. Soc. Rev., 2022, 51, 6757 DOI: 10.1039/D2CS00150K

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