Issue 4, 2022

Oxidative evolution of Z/E-diaminotetraphenylethylene

Abstract

We report that Z/E-diaminotetraphenylethylene (Z/E-2NH2-TPE) molecules suffer primarily from oxidative evolution rather than recognized isomerization. The oxide is separated and its structure is deciphered by single crystal X-ray diffraction. The oxidative evolution accompanying the rearrangement is explained through quantum theoretical calculation.

Graphical abstract: Oxidative evolution of Z/E-diaminotetraphenylethylene

Supplementary files

Article information

Article type
Communication
Submitted
19 Nov 2021
Accepted
05 Jan 2022
First published
07 Jan 2022

Phys. Chem. Chem. Phys., 2022,24, 1960-1964

Oxidative evolution of Z/E-diaminotetraphenylethylene

X. Li, Y. Zhuang, Q. Ran and X. Liu, Phys. Chem. Chem. Phys., 2022, 24, 1960 DOI: 10.1039/D1CP05303E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements