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Correction: Hidden ordered structure in the archetypical Fe(pyrazine)[Pt(CN)4] spin-crossover porous coordination compound

Ángel Fernández-Blanco ab, Lorenzo A. Mariano b, Lucía Piñeiro-López c, José Antonio Real d, Jose Sanchez Costa c, Roberta Poloni *b and J. Alberto Rodríguez-Velamazán *a
aInstitut Laue Langevin, 71 Avenue des Martyrs, CS 20156-38042, Grenoble, France. E-mail: velamazan@ill.eu
bUniv. Grenoble Alpes, SIMaP, Grenoble-INP, CNRS, F-38042, Grenoble, France. E-mail: roberta.poloni@grenoble-inp.fr
cIMDEA Nanociencia, Faraday 9, Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain
dDepartamento de Química Inorgánica, Insituto de Ciencia Molecular (ICMol), Universidad de Valencia, 46980, Paterna, Spain

Received 26th October 2022 , Accepted 26th October 2022

First published on 3rd November 2022


Abstract

Correction for ‘Hidden ordered structure in the archetypical Fe(pyrazine)[Pt(CN)4] spin-crossover porous coordination compound’ by Ángel Fernández-Blanco et al., CrystEngComm, 2022, 24, 6349–6356, https://doi.org/10.1039/D2CE00895E.


The authors regret that the neutron diffraction pattern shown in Fig. 3C was duplicated in Fig. 3D in the original article. The correct version of Fig. 3 is shown below.
image file: d2ce90151j-f3.tif
Fig. 3 Details of the most relevant part of the powder neutron diffraction patterns (wavelength 1.54 Å) of Fe(d4-pyrazine)[Pt(CN)4] (a and c) and Fe(pyrazine)[Pt(CN)4] (d): experimental patterns (red), calculated patterns (black), difference patterns (blue lines), and position of the Bragg reflections for the disordered configuration (green marks) and the ordered arrangement of the pyrazine bridges in perpendicular configuration (black marks). The arrows indicate the observed superstructure reflections related to the ordering of the pyrazine bridges in the perpendicular configuration. Panel a) Fe(d4-pyrazine)[Pt(CN)4] in the low-spin state (100 K). Panel b) neutron thermodiffractograms collected upon cooling from 320 K to 245 K (cooling rate ca. 1.5 K min−1, acquisition every 5 minutes) for Fe(d4-pyrazine)[Pt(CN)4]. Panel c) Fe(d4-pyrazine)[Pt(CN)4] in the high-spin state (320 K). Panel d) Fe(pyrazine)[Pt(CN)4] in the low-spin state (130 K).

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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